• Bulletin of the Korean Chemical Society
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• 제31권2호
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• pp.344-350
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• 2010

The improved photocatalytic performance of a carbon/$TiO_2$ composite was studied for the Bisphenol A (BPA) decomposition. Titanium tetraisopropoxide (TTIP) and a rice husk from Korea were heterogeneously mixed as the titanium and carbon sources, respectively, for 3 h at room temperature, and then thermally treated at $600^{\circ}C$ for 1 h in $H_2$ gas. The transmission electron microscopy (TEM) images revealed that the bulk carbon partially covered the $TiO_2$ particles, and the amount that was covered increased with the addition of the rice husk. The acquired carbon/$TiO_2$ composite exhibited an anatase structure and a novel peak at $2{\theta}=32^{\circ}$, which was assigned to bulk carbon. The specific surface area was significantly enhanced to 123~164 $m^2/g$ in the carbon/$TiO_2$ composite, compared to $32.43m^2/g$ for the pure $TiO_2$. The X-ray photoelectron spectroscopy (XPS) results showed that the Ti-O bond was weaker in the carbon/$TiO_2$ composite than in the pure $TiO_2$, resulting in an easier electron transition from the Ti valence band to the conduction band. The carbon/$TiO_2$ composite absorbed over the whole UV-visible range, whereas the absorption band in the pure$TiO_2$ was only observed in the UV range. These results agreed well with an electrostatic force microscopy (EFM) study that showed that the electrons were rapidly transferred to the surface of the carbon/$TiO_2$ composite compared to the pure $TiO_2$. The photocatalytic performance of the BPA removal was optimized at a Ti:C ratio of 9.5:0.5, and this photocatalytic composite completely decomposed 10.0 ppm BPA after 210 min, whereas the pure $TiO_2$ achieved no more than 50% decomposition under any conditions.

• 한국환경보건학회지
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• 제40권6호
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• pp.435-441
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• 2014

Objectives: Bisphenol A, or BPA, is a chemical component in polycarbonate plastic with which many people come into contact every day. A great deal of controversy has arisen over its safety since this material, which is known to disrupt the human endocrine system and cause neurological difficulties and cancer, is commonplace in beverage containers, food can liners, and receipt paper rolls. In this study, we determined the levels of exposure to BPA of workers in the service industry depending on the number of receipts contacted. Methods: The participants were 16 male and 18 female workers employed in the service industry. Using a questionnaire, we investigated general and job characteristics. Urine samples were collected and analyzed by the LC-MS/MS technique after enzymatic hydrolysis and solid phase extraction (SPE). Results: The geometric mean (GM) concentration of urinary BPA from all subjects was 1.02 ng/ml. Workers were exposed significantly to more BPA according to the number of receipts they contacted, their work experience, and working hours per day. The BPA concentration of those who touched more than 100 receipts per day was 3.09 ng/ml, while that of the other participants was 0.61 ng/ml. It was shown that wearing gloves can protect from BPA exposure. Conclusion: We determined the urinary BPA concentrations of workers in service industry and found that the contact with receipts could increase the BPA exposure of service workers.

• Toxicological Research
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• 제17권3호
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• pp.225-234
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• 2001

The present study was conducted to investigate the effects of Korean red ginseng water extract (KRGWE) on developmental toxicity caused by the environmental estrogen bisphenol A (BPA) in Sprague-Dawley rats. fifty males successfully mated were randomly assigned to five experimental groups, 1.e., group I (vehicle control), group II (BPA 1000mg/kg), group III (KRGWE 400mg/kg), group IV (BPA 1000mg/kg & KRGWE 200mg/kg), and group V (BPA 1000mg/kg & KRGWE 400mg/kg). The test articles were administered by gavage to mated females from gestational days (GD) 1 through 20 (sperm vaginal lavage=day O). All females were subjected to caesarean section on GD 21 and their fetuses were examined for external, visceral, and skeletal abnormalities. In the group II, significant maternal toxic effects including suppressed body weight, decreased body weight gain during pregnancy, and reduced food consumption were observed in pregnant rats. The minimal developmental toxicity including fetal ossification delay was also found in fetuses. In addition, a tendency for increased pregnancy failure, increased pre-and postimplantation loss, and decreased fetal body weight was observed. However, no fetal morpho-logical abnormalities were seen in surviving fetuses at a dose level of 1000mg BPA/kg. On the other hand, the maternal toxicity and developmental toxicity found in the groups IV and V were comparable to those of the group II. There were no adverse signs of either maternal toxicity or developmental toxicity in the group III. These results showed that administration of BPA at a dose level of 1000mg/kg to pregnant rats resulted in significant maternal toxicity and minimal developmental toxicity, and that no protective effects on BPA-induced maternal toxicity and developmental toxicity were found by concomitant gavage dosing of KRGWE.

• Environmental Analysis Health and Toxicology
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• 제22권3호
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• pp.203-209
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• 2007

생활하수, 공장폐수, 농경유출수에 의해 수생태계로 유입된 다양한 화학물질들은 수서곤충이나 어류와 같은 수생생물에게 나쁜 영향을 주곤 한다. 비스페놀A와 노닐페놀을 포함하는 많은 화학물질들이 내분비계 장애물질(EDCs)로 의심되고 있고, 그들은 환경속에서 서로 다른 혼합형태로 공존하기도 한다. 따라서 비스페놀A와 노닐페놀의 혼합물이 독성과 생식학적 반응에 미치는 영향을 살펴보기 위해 일본산 송사리의 수정란 치사율, 부화율 및 부화시간, 치어의 성장율 및 비텔로제닌 농도 등이 측정되었다. 수정된 지 24시간 이내의 수정란을 대조군, 양성대조군($17{\beta}-estradiol$), 그리고 서로 다른 농도의 비스페놀A와 노닐페놀의 혼합물에 부화 후 60일까지 유수식 조건하에 노출시켰다. 수정란${\sim}$치자어 단계에서는 대조군과 비교하여 실험군의 치사율 및 부화율, 부화시간에 차이가 나타나지 않았으며, 부화 후 60일간의 노출 후 성장(길이, 무게)에 있어서도 비록 양성대조군에서 낮은 성장상태를 보였지만 다른 혼합물의 실험군들과는 차이를 보이지 않았다. 한편 체내 비텔로제닌 농도는 혼합물의 농도증가에 따라 증가하였으며 수컷의 경우 최저농도의 혼합물(Treatment A)을 제외한 실험군에서 농도증가에 따라 증가하였다. 반면 양성대조군의 경우 수컷이 발견되지 않았고 암컷 체내의 비텔로제닌 농도는 최고농도의 혼합물(Treatment D) 실험군과 비슷한 경향을 보였다. 위 실험을 통해 각각의 내분비계 장애물질이 개별적으론 생식발달 및 비텔로제닌 유도에 무영향농도(NOEC)라 하더라도 혼합된 경우 영향이 나타날 수 있다는 것을 보여주었으며, 이는 수환경 내 다양한 화학물들의 혼합효과(combination effect)가 생태위해성평가를 좀더 면밀하게 하기 위해서 주의 깊게 고려되어야 한다고 제안한다.

• 한국환경보건학회지
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• 제47권1호
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• pp.87-100
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• 2021

Objectives: The purpose of this study was to analyze the factors affecting Bisphenol A (BPA) exposure in children and adolescents using the results of the Korean National Environmental Health Survey (KoNEHS) cycle 3. Methods: A total of 2,380 subjects (n=571, 887, and 922 for 3-5, 6-11, and 12-17 years of age, respectively) were analyzed using an environmental exposure survey and environmental chemical substances concentration levels. Univariable linear regression analysis was performed to determine associated variables such as sex, age, income level, housing type, secondhand smoke time, cup noodles and canned food consumption, seafood consumption, new furniture (within the previous six months), drinking water type, and consumption of herbal medicines. Variables with p-values of less than 0.2 were extracted from the results and a multivariable linear regression analysis was performed using stepwise selection. Results: Univariable linear regression analysis showed positive associations between BPA concentration levels and variables including sex, age, secondhand smoke time, new furniture (within the previous six months), renovated living space (within the previous six months), fish and shellfish consumption, plastic-bottled drink consumption, and herbal medicine. As a result of performing multivariable linear regression analysis, the lower was the age the higher was the concentration of BPA levels. Additionally, women showed higher BPA levels than those of men. The more frequently fish was consumed, the higher was the BPA concentration. Moreover, higher BPA concentrations were observed when taking herbal medicine. Conclusions: The main factors affecting BPA concentration levels were age, gender, and consumption of fish and herbal medicine.

• Bulletin of the Korean Chemical Society
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• 제27권10호
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• pp.1542-1548
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• 2006

Maleimide modified epoxy compounds were prepared by reacting N-(4-hydroxyphenyl) maleimide (HPM) with diglycidylether of bisphenol-A. Triphenylphosphine was used as catalyst and methylethylketone as solvent. The resulting compound possessed both the oxirane ring and maleimide group. The curing reaction of the maleimide epoxy compound with amine curing agents such as 1-(2-aminoethyl) piperazine (AEP) and 5-amino-1,3,3-trimethylcyclohexane methylamine isophorone diamine, IPDA) were studied. Incorporation of maleimide groups in the epoxy resin provides cyclic imide structure and high cross-linking density to the cured resins. The cured samples were found to have good thermal stability, chemical resistance (acid/alkali/solvent) and water absorption resistance.

• 한국환경성돌연변이발암원학회:학술대회논문집
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• 한국환경성돌연변이발암원학회 2003년도 추계학술대회
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• pp.135-135
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• 2003

• International Journal of Precision Engineering and Manufacturing
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• 제1권1호
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• pp.33-41
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• 2000

Fiber reinforced metal laminates(FRMLs) were new type of hybrid materials. FRMLs consist of high strength metals(Al 5052-H34) and laminated fiber with structural adhesive bond. The effect of resin mixture ratios on the fatigue crack propagation behavior and mechanical properties of aramid fiber reinforced aluminum composites was investigated. The epoxy, diglycidylether of bisphenol A(DGEBA), was cured with methylene dianiline(MDA) with or without an accelerator(K-54). Eight kinds of resin mixture ratio were used for the experiment ; five kinds of FRMLs(1)(mixture of epoxy and curing agent) and three kinds of FRMLs(2)mixture of epoxy, curing agent and accelerator). The characteristic of fatigue crack propagation behavior and mechanical properties FRMLs(2) shows more effecting than that of FRMLs(1).

• 대한예방의학회:학술대회논문집
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• 대한예방의학회 2002년도 제54차 추계 학술대회 연제집
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• pp.290-291
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• 2002

• Environmental Engineering Research
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• 제13권4호
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• pp.197-202
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• 2008

This study evaluated the photocatalytic oxidation of BPA using the RPOD reactor under various conditions. This study found that the RPOD was effective for BPA degradation. It could reduce 1 mg/L of BPA by half within 5 min under the optimum conditions. According to the study results, $TiO_2$ coating was important for the BPA oxidation. As the coating thickness increased, the removal efficiency improved. The light source, the light intensity and the drum rotating speed were important for the oxidation. The UV light was more effective for the BPA degradation than the visible light. The removal efficiency improved with increasing intensity. As the drum speed increased, the removal efficiency improved. The maximum speed was 240 rpm in this study. Addition of air and nitrogen was not beneficial for the BPA degradation in this study probably due to enough oxygen in the water.