• Title/Summary/Keyword: bismuth oxide

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A facile spray coating of bismuth oxide on TiO2 nanotube arrays for lithium ion battery anode materials (스프레이 코팅법을 이용한 산화비스무트-타이타니아 나노튜브 제조와 리튬이차전지 음극으로의 적용)

  • Kim, Nam-Yeol;Jeong, Min-Gyeong;Choe, Jin-Seop
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.146-146
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    • 2017
  • 산화비스무트는 리튬이온과의 반응에서 현재 상용화된 그래파이트보다 높은 이론용량을 가지고 있으나, 리튬이온과의 반응에서 비교적 큰 부피팽창 특성을 가져 리튬이차전지의 음극재로서 상용화가 어려운 단점이 있다. 본 연구에서는, 이러한 문제점을 개선하기 위하여 양극산화법을 통해 충 방전시 부피팽창 변화가 매우 적은 타이타니아 나노튜브를 제조한 후, 그 위에 스프레이 방법으로 산화비스무트를 코팅하여 두 물질의 복함체를 만듦으로써 용량과 구조적 안정성을 향상시키는 방법을 소개한다. 음극재의 구조적 특성은 고분해능 주사전자현미경 (HR-SEM), 고분해능 엑스선 회절분석기(XRD)를 통해 조사하였으며, 전기화학 임피던스 분광법 (EIS), 순환전류법 (CV), 충 방전 싸이클 분석을 통해 리튬이차전지의 작동원리와 보다 향상된 성능을 규명하였다.

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A study on single body design of optical current sensor and optical voltage sensor (광전류/광전압 센서의 일체화 설계에 관한 연구)

  • 김영수;김요희
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.21 no.6
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    • pp.1596-1603
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    • 1996
  • A single body type of fiber-optic current and voltae sensor using a rare earth doped YIG and a bismuth silicon oxide single crystsl is proposed, which is used for simultaneous measurement of the AC electric current and AC electric voltage over the trasmission lines. Experimental results showed that the fiber-optic current sensor has the maximum 7.5% error within the current range of 0A to 400A, and the fiber-optic voltage sensor has the maximum 0.87% error within the current range of 0V to 400V. The output waveforms of proposed fiber-optic sensor system has a good agreement with output waveforms of conductor current and voltage. Experimental results proved that the output of fiber-optic current sensor is not affected by the electric voltage applied to the fiber-optic voltage sensor, and also, that the output of fiber-optic voltage sensor is not affected by the electric current applied to the fiber-optic current sensor.

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Corrosion Characteristics of HT-9 in 500℃ and 650℃ Pb-Bi Liquid Metal

  • Song, T.Y.;Cho, C.H.
    • Corrosion Science and Technology
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    • v.5 no.3
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    • pp.94-98
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    • 2006
  • The next generation nuclear power reactor will use Pb-Bi as the cooling material. The steel structure materials such as HT-9 used in the reactor suffer from corrosion when they are exposed to high temperature Pb-Bi. Therefore corrosion should be prevented to use Pb-Bi as the coolant material without any safety problem. One method is to control the oxygen content in Pb-Bi. An appropriate amount of oxygen in Pb-Bi can produce a thin oxide layer on steel, and this layer protects the steel from corrosion attack. Since the required oxygen content in Pb-Bi is in the range of $10^{-5}$ to $10^{-7}$ wt%, this small oxygen content can be controlled by flowing a mixture of hydrogen gas and water vapor. The stagnant corrosion test of HT-9 samples was performed by controlling the oxygen content up to 2,000 hours. The corrosion behavior of HT-9 was analyzed at the temperatures of $500^{\circ}C$ and $650^{\circ}C$ with a reduced condition and a oxygen content of $10^{-6}$ wt%.

Enhanced sticking coefficient in the BSCCO single crystal grown by the sputtering method (스퍼터링 법에 의한 BSCCO 단결정 성장의 부착 계수 향상)

  • Cheon, Min-Woo;Yang, Sung-Ho;Park, Yong-Pil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.585-586
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    • 2005
  • BSCCO thin films were fabricated by an ion beam sputtering method with an ultra-low growth rate, and sticking coefficients of the respective elements are evaluated. The sticking coefficient of Bi element in BSCCO film formation was observed to show a unique temperature dependence; it was almost a constant value of 0.49 below about $730^{\circ}C$ and decreased linearly over about $730^{\circ}C$. In contrast, Sr and Ca, displayed no such remarkable temperature dependence. This behavior of the sticking coefficient was explained consistently on the basis of the evaporation and sublimation processes of Bi2O3. It is considered that the liquid phase of the bismuth oxide plays an important role in the Bi 2212 phase formation in the co-deposition process.

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Test of the Conduction Cooling System for HTS SMES (고온 초전도 SMES용 전도냉각시스템 특성시험)

  • Yeom, Han-Kil
    • Progress in Superconductivity and Cryogenics
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    • v.10 no.1
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    • pp.62-66
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    • 2008
  • The characteristic of the superconducting magnetic energy storage(SMES) system is faster response, longer life time, more economical, and environment friendly than other uninterruptible power supply(UPS) using battery. So, the SMES system can be used to develop methods for improving power quality where a short interruption of power could lead to a long and costly shutdown. Recently, cryogen free SMES has developed using BSCCO(Bismuth Strontium Calcium Copper Oxide) wire. We fabricated and tested the conduction cooling system for the 600 kJ class HTS SMES. The experiment was accomplished for the simulation coils. The simulation coils were made of aluminium, it is equivalent to thermal mass of 600 kJ HTS SMES coil. The coil is cooled with two GM coolers through the copper conduction bar. In this paper, we report that the test results of cool-down and heat loads characteristics of the simulation coils. The developed conduction cooling system adapted to 600 kJ HTS SMES system and cope with the unexpected sudden heat impact, too.

Fabrication of $CeO_2$ Buffer Layer Using MOD Process

  • Kim, Young-Kuk;Yoo, Jai-Moo;Chung, Kook-Chae;Ko, Jae-Woong
    • Progress in Superconductivity and Cryogenics
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    • v.8 no.4
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    • pp.19-21
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    • 2006
  • Biaxially textured Ni was fabricated by electrodeposition process and delaminated from the biaxially textured cathode surface for further buffer layer deposition process. Those electrode posited Ni substrates showed well-developed biaxial texture and smooth surface. In order to improve the thermal stability of Ni substrates, Mn was alloyed by adding Mn precursor into the electrodeposition bath. Subsequently, $CeO_2$ buffer layers are deposited by MOD process to prevent interfacial reaction between superconductor and substrates. In particular, Bismuth oxide was added to $CeO_2$ to realize lower temperature processing of buffer layers. The microstructure and texture development of each layers have been investigated. Preliminary results shows that all electro/chemical process can be a candidate for cost effective route to YBCO coated conductor.

Thermoelectric Properties of Bi2Te2.7Se0.3 Powder Synthesized by an Oxide-Reduction Process (산화물 환원공정에 의해 제조된 Bi2Te2.7Se0.3 분말의 열전특성)

  • Park, Bae-Gun;Lee, Gil-Geun;Kim, Woo-Yeol;Ha, Gook-Hyun
    • Journal of Powder Materials
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    • v.18 no.5
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    • pp.437-442
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    • 2011
  • The present study focused on the synthesis of Bi-Te-Se-based powder by an oxide-reduction process, and analysis of the thermoelectric properties of the synthesized powder. The phase structure, chemical composition, and morphology of the synthesized powder were analyzed by XRD, EPMA and SEM. The synthesized powder was sintered by spark plasma sintering. The thermoelectric properties of the sintered body were evaluated by measuring its Seebeck coefficient, electrical resistivity, and thermal conductivity. $Bi_2Te_{2.7}Se_{0.3}$ powder was synthesized from a mixture of $Bi_2O_3$, $TeO_2$, and $SeO_2$ powders by mechanical milling, calcination, and reduction. The sintered body of the synthesized powder exhibited n-type thermoelectric characteristics. The thermoelectric properties of the sintered bodies depend on the reduction temperature. The Seebeck coefficient and electrical resistivity of the sintered body were increased with increasing reduction temperature. The sintered body of the $Bi_2Te_{2.7}Se_{0.3}$ powder synthesized at $360^{\circ}C$ showed about 0.5 of the figure of merit (ZT) at room temperature.

Design of Double Layer Shielding Structure using Eco-friendly Shielding Materials (친환경 차폐물질을 이용한 이중구조 차폐체의 설계)

  • Park, Ji Koon;Choi, Il Hong;Park, Hyung Hoo;Yang, Sung Woo;Kim, Kyo Tae;Kang, Sang Sik
    • Journal of the Korean Society of Radiology
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    • v.10 no.8
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    • pp.559-563
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    • 2016
  • Recently, a barium(Ba) and an iodine(I) being studied as a conventional lead(Pb) alternatives of shielding material has excellent shieding rate, but the characteristic x-ray photons in the energy range near 30 keV line is released. In this study, with bismuth oxide(BiO) coupled barium sulfate($BaSO_4$) double layer, transmitted spectra, shieding rates and relative weighting rates were evaluated to validate the applicability of eco-friendly double layer shieding structure using monte carlo simulations as a prior study. From the evaluation results, in 0.4mm and 0.5mm thickness of BiO layers coupled with top 0.1mm-$BaSO_4$ layer, the shieding rate showed 1.9% and 3.9% higher than 0.6mm thickness of Pb single layer, respectively. In addition, the relative weight also 28% and 34.5% lower than 0.6mm-Pb in 0.4mm and 0.5mm thickness of BiO layers coupled with top 0.1mm-$BaSO_4$ layer.

CLINICAL APPLICATION OF MTA(MINERAL TRIOXIDE AGGREGATE) FOR APEXIFICATION (치근단 형성술(Apexification)에 있어서 MTA(Mineral Trioxide Aggregate)의 적용)

  • Baik, Byeoung-Ju;Jeon, So-Hee;Kim, Young-Sin;Kim, Jae-Gon
    • Journal of the korean academy of Pediatric Dentistry
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    • v.28 no.4
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    • pp.700-708
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    • 2001
  • Traumatic injuries in young patients can result in the interruption of the development of the incompletely formed roots. In teeth with incomplete root-end formation and necrotic pulps, the root canals must be completely debrided. Because of a lack of an apical stop and the presence of thin and fragile walls in these teeth, it is imperative to perform apexification to obtain an adequate apical seal. Calcium hydroxide has become the material of choice for apexification. Despite its popularity for the apexification procedure, calcium hydroxide therapy has some inherent disadvantages that include variablility of treatment time, unpredictability of apical closure, difficulty in patient follow-up, and delayed treatment. An alternative treatment to long-term apexification procedure is the use of an artificial apical barrier that allows immediate obturation of the canal. MTA(Mineral Trioxide Aggregate) is a powder consisting of fine hydrophilic particles of tricalcium silicate, tricalcium aluminate, tricalcium oxide and silicate oxide. MTA has a pH of 12.5 after setting, similar to calcium hydroxide. This may impart some antimicrobial properties. MTA has low solubility and a radiopacity slightly eater than that of dentin. Also, MTA leaked significantly less than other materials and induced hard-tissue formation more than other materials.

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Ferroelectric Properties of Bi4Ti3O12 Thin Films Deposited on Si and SrTiO3 Substrates According to Crystal Structure and Orientation (Si 및 SrTiO3 기판 위에 증착된 Bi4Ti3O12 박막의 결정구조 및 배향에 따른 강유전 특성)

  • Lee, Myung-Bok
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.67 no.4
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    • pp.543-548
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    • 2018
  • Ferroelectric $Bi_4Ti_3O_{12}$ films were deposited on $SrTiO_3(100)$ and Si(100) substrate by using conductive $SrRuO_3$ films as underlayer, and their ferroelectric and electrical properties were investigated depending on crystal structure and orientation. C-axis oriented $Bi_4Ti_3O_{12}$ films were grown on well lattice-matched pseudo-cubic $SrRuO_3$ films deposited on $SrTiO_3(100)$ substrate, while random-oriented polycrystalline $Bi_4Ti_3O_{12}$ films were grown on $SrRuO_3$ films deposited on Si(100) substrate. The random-oriented polycrystalline film showed a good ferroelectric hysteresis property with remanent polarization ($P_r$) of $9.4{\mu}C/cm^2$ and coercive field ($E_c$) of 84.9 kV/cm, while the c-axis oriented film showed $P_r=0.64{\mu}C/cm^2$ and $E_c=47kV/cm$ in polarizaion vs electric field curve. The c-axis oriented $Bi_4Ti_3O_{12}$ film showed a dielectric constant of about 150 and lower thickness dependence in dielectric constant compared to the random-oriented film. Furthermore, the c-axis oriented $Bi_4Ti_3O_{12}$ film showed leakage current lower than that of the polycrystalline film. The difference of ferroelectric properties in two films was explained from the viewpoint of depolarization effect due to orientation of spontaneous polarization and layered crystal structure of bismuth-base ferroelectric oxide.