• Korean Journal of Mineralogy and Petrology
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• v.35 no.2
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• pp.101-109
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• 2022

The mobility and transport of radioactive cesium are crucial factors to consider for the safety assessment of high-level radioactive waste disposal sites in granite. The retardation of radionuclides in the fractured crystalline rock is mainly controlled by the hydrochemical condition of groundwater and surface reactions with minerals present in the fractures. This paper reports the experimental results of cesium sorption to the Wonju Granite, a typical Mesozoic granite in Korea, performed in an anaerobic chamber that mimics the anoxic environment of a deep disposal site. We measured the rates and amounts of cesium (¹³³Cs) removed by crushed granite samples in different electrolyte (NaCl, KCl, and CaCl₂) solutions and a synthetic groundwater solution, with variations in the initial cesium concentration (10^-5, 5×10^-6, 10^-6, 5×10^-7 M). The cesium sorption kinetic and isotherm data were successfully simulated by the pseudo-second-order kinetic model (r²= 0.99) and the Freundlich isotherm model (r²= 0.99), respectively. The sorption distribution coefficient of granite increased almost linearly with increasing biotite content in granite samples, indicating that biotite is an effective cesium scavenger. The cesium removal was minimal in KCl solution compared to that in NaCl or CaCl₂ solution, regardless of the ionic strength and initial cesium concentration that we examined, showing that K⁺ is the most competitive ion against cesium in sorption to granite. Because it is the main source mineral of K⁺ in fracture fluids, biotite may also hinder the sorption of cesium, which warrants further research.

• The Journal of the Petrological Society of Korea
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• v.23 no.4
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• pp.393-403
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• 2014

U-Pb ages were determined from the Yongyudo biotite granites from western parts of Gyeonggi massif. The results show that the emplacement age of the Yongyudo biotite granite is ca. 227-230 Ma. Such age result that is somewhat older than previous reported ages, suggesting further investigations for the timing and evolution of the Jurassic granites of the western Gyeonggi massif.

• Journal of Conservation Science
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• v.5 no.1 s.5
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• pp.20-40
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• 1996

For obtaining the basic data for establishing plan on the conservation of the Gameunsa 3-story and Naweonri 5-story Pagodas located at the Kyeongju city, the characteristics of the rock and weathering phenomena have been investigated. The former consists of quartz-rlch granite containing small amount of biotite, and the latter of alkali granite with abundant perthite, These rock phases are nearly identical to the marginal phase of medium-grained hornblende-biotite granodiorite and alkali granite respectively, which are distributed around the Kyeongju city. The rock weathering may be governed mainly by chemical weathering of feldspar following physical segregation of quartz grains and pervasive moss. The feldspar easily dissolve In the solution with pH<7 to precipitate clay mineral such as a kaolinite as a secondary phase on the feldspar surface. However, the chemical weathering of feldspar may continue when the surface is washed by the rain according to removal of the reprecipitated phase. On forwarding, the weathering may be greatly Influenced by the acid rain. Exfoliation and weathering along igneous lineation resulting in exfoliating along the structural line are the characteristic weathering phenomena. Also the secondary small cracks are irregularly developed on the rocks due to different strain on places by the overall structural unbalance of the pagodas. Along these cracks, the rain water intrudes deeply into the rocks and weathering occurs intensively compared to other parts. Weathering may be artificially promoted by the grinding or sculpturing when the pagodas were made. Because it may influence on the physical properties of the rocks as well as destruct the surface of the feldspar crystals, the major constituents of the rocks, it results in providing the environment of easy chemical weathering along time. For conservation, the pagodas must be structurally balanced by compacting the soil basement and supplementing rocks on the destroyed part. On the exfoliated part it is better not to be artifically treated as using cementing material. But the cracks may be filled up by cementing material to avoid the intrusion of acidic water. To supplement the rocks on the destroyed part, it may be better to use similar rock phases from identical biotite granite and alkali granite masses around the Kyeongju city.

• The Journal of the Petrological Society of Korea
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• v.3 no.1
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• pp.94-108
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• 1994

The Precambrian granite, and the Yuli group and the Hyeondong gneisss complex are studied to unravel the metamorphic history of the northeastern Sobaeksan massif. The Hongjesa granite, emplaced at 650-$700^{\circ}C$ and $3{\pm}1$ kbar, has been altered at 310-$568^{\circ}C$. Not only the chloritization of biotite but also the sericitization and saussuritization of plagioclase occur at the subsolidus stage. Biotites of the Hongjesa granite vary in their Al, Fe and Mg contents through dioctahedral and tschermakitic substitutions during the subsolidus stage. Secondary muscovites from biotite and feldspars are enriched in their Si and Mg+Fe contents through tschermakitic and trictahedral substitutuions. The metamorphic pressures and temperatures estimated from the Hyeondong gneiss complex are 3.6-6.6 kbar and 593-$718^{\circ}C$, respectively. Local migmatization producing the cordierite-bearing assemblage occurs in the Hyeondong gneiss complex. The Gibbs' method applied to the assemblage of garnet+biotite+plagioclase+quartz in banded gneiss suggests a complex P-T history of the Hyeondong gneiss complex.

• The Journal of the Petrological Society of Korea
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• v.8 no.2
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• pp.71-80
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• 1999

We report zircon morphology of granitoids in the Mt. Keumjeong district, Pusan. There are a series of granitoids in the study area of the late Cretaceous: granodiorite, hornblende granite, adamellite, tonalite, biotite granite, and micrographic granite. Generally, the shapes of zircon crystals are short prismatic to middle prismatic and are dominant in {loo) prism and {101) pyramid in total average morphological data of the granitoids. The crystal forms of zircon in the granitoids can be distinguished by the PPEF diagram and the prism index (PI). The prism index values of zircon crystal forms in granodoirite and hornblende granite are higher than those of tonalite and micrographic granite. The finishing temperature range ($820~800^{\circ}C$) for crystallization of zircon crystals in granodoirite and hornblende granite is higher than the temperature ($790~770^{\circ}C$) at which the zircon crystals are created in tonalite and micrographic granite. The last differentiates (biotite granite and micrographic granite) have mainly intermediate zircon ({110)={100)) crystals, respectively. As differentiation proceeds, the zircons of granitoids become from short prismatic to middle prismatic in the each granitoid types.

• The Journal of the Petrological Society of Korea
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• v.2 no.2
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• pp.74-94
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• 1993

Metabasites and metapelites in the Mungyong area were intruded by Cretaceous granites with radius of 4-8 km. As the distance from granite body increases, the mineral assemblage of metabasite changes from amphibole + plagioclase through amphibole + plagioclase + epidote to amphibole + plagioclase + epidote + chlorite. The compositional variations of amphibole and plagioclase according to the change of metamorphic grade and bulk rock compositions are very complex. Towards the Mungyong Cretaceous granite body, the mineral assemblage of metapelite changes from chlorite+ muscovite(ch1orite zone) through biotite + chlorite + muscovite(biotite zone) to andalusite+biotite + muscovite${\pm}$chlorite or cordierite+ biotite+ muscovite${\pm}$chlorite(cordierite zone). The estimated metamorphic conditions of cordierite zone are 480~$580^{\circ}C$ 1.5-3.3 kb. The theoretical study on the thermal metamorphism caused by the Cretaceous granite with radius longer than 4 km in the Mungyong area suggests the followings: The degree of metamorphism is mainly determined not by the size of granite body but by the temperature of granite intrusion; The country rocks within 2 km from Cretaceous granite have undergone metamorphism with temperature higher than $500^{\circ}C$, which is consistent with the petrological study in the Mungyong area. Mungyong Cretaceous granite caused a low P/T thermal metamorphism to the country rocks; the amphibolite facies metamorphism to the country rocks within 1-2 km from the granite body and the epidote-amphibolite and greenschist facies metamorphism to the country rocks within 2-5 km.

• The Journal of the Petrological Society of Korea
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• v.6 no.3
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• pp.210-225
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• 1997

From their general natures of peraluminous, S-type and ilmenite-series granites, two-mica granites in the Cheongsan, Inje-Hongcheon, Yeongju and Namwon areas were originated from crust-derived granitic magma and solidified under reducing condition. Each two-mica granite in Inje-Hongcheon and Namwon districts was differentiated from the the residual magma of porphyric biotite granite and high Ti/Mg biotite granite, respectively. The genetic relationships between two-mica granite and porphyritic biotite granite in Chenongsan district and between two-mica granite and biotite granodiorite in Yeongju district are ambiguous. In Namwon district granitic magmas were water-saturated and possible water solubilities in magmas were more than 5.8wt.%. In Yeongju district two-mica granitic magma was nearly water-saturated and showed possible water solubilities between 2.4~5.8wt.%. Two-mica granitic magmas in Cheongsan and Inje-Hongcheon districts were water-undersaturated. Pressure-dependent minimum melt compositions (0.5~2kb) and petrographic textures of two-mica granites in Inje-Hongcheon and Yeongju districts represent that the granites intruded and solidified at shallow level, whereas those in Cheongsan and Namwon districts exhibit relatively deeper level of granitic intrusion (2-3kb). The intersection of granite-solidus/muscovite stability indicates that magmatic primary muscovite can be crystallized from the water-saturated magma above 1.6kb (ca. 6km), but below the pressure muscovite can be formed by the subsolidus reaction. On the other hand, more pressure would be necessary for the crystallization of primary muscovite from the water-undersaturated magma. This pressure condition can explain the occurrence of primary and secondary muscovites from the two-mica granites in the areas considered. The experimental muscovite stability must be cautious of the application to examine the origin of muscovite. The muscovite stability can move toward high temperature field with adding of Ti, Fe and Mg components to the octahedral site of pure muscovite end member.

• Economic and Environmental Geology
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• v.25 no.4
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• pp.463-477
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• 1992

The study area consists of sedimentary and volcanic rocks of Gyeongsang Supergroup, granitoid intrusives, and hornfelses around the granitoids. Granitoid intrusives occur in small stocks in Nijeon-ri, Uggogri, and Yul-ri area. The masses in Nijeon-ri and Uggog-ri are hornblende-biotite granodiorite, biotite granodiorite respectively, and Yul-ri mass is biotite granite. Surrounding sediments of these masses were thermally metamorphosed and contact aureoles were formed. The studied granitoids are considered to be formed by sequential crystallization-differentiation from calc-alkalic granitoid magma. Metamorphic minerals occurring in contact aureole are chlorite, actinolite, epidote, and biotite. Diopside and hornblende are observed in small amount in some lithology around contact aureole. The lithology of contact aureole is predominantly silty and sandy, and characteristic metamorphic minerals were poorly developed because of low temperature metamorphism. Low temperature in contact aureole could be deduced from the facts that the intrusions were small size, shallow depth, low temperature, and rare movement of volatiles from magma.

• The Journal of the Petrological Society of Korea
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• v.13 no.3
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• pp.142-151
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• 2004

The metamorphic rocks of Yongin-Anseong area in Gyeonggi massif are composed of high-grade gneisses and schists which are considered as Precambrian basement, and Jurassic granite which intruded the metamorphic rocks. In this paper, we discuss the geochemical characteristics of metamorphic rocks and granites in this area based on REE and Nd isotope geochemistry. And we also discuss the petrogenetic relationship between metamorphic rocks and granites in this area. Most of Nd model ages (T$\_$DM/$\^$Nd/) from the metamorphic rocks range ca. 2.6Ga～2.9Ga which are correspond to the main crustal formation stage in Gyeonggi massif by Lee et. al. (2003). And Nd model ages show that the source material of quartzofeldspathic gneiss is slightly older than that of biotite banded gneiss. In chondrite-normalized rare earth element pattern, the range of (La/Yb)$\_$N/ value from biotite banded gneiss is 37～136, which shows sharp gradient and suggests that biotite banded gneiss was originated from a strongly fractionated source material. However, that of amphibolite is 4.65～6.64, which shows nearly flattened pattern. Particularly, the chondrite normalized REE patterns from the high-grade metamorphic rocks show the REE geochemisoy of original source material before metamorphism. In addition, the values of (La/Yb)$\_$N/ and Nd model ages of granite are 32～40 and 1.69Ga～2.08Ga, respectively, which suggest that the source material of granite is different from that of Precambrian basement such as biotite banded gneiss and quartzofeldspthic gneiss in the area.

• Korean Journal of Heritage: History & Science
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• v.56 no.3
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• pp.196-212
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• 2023

This study identifies the origin of stone remains (pavement and banister stones) excavated from the first burial site of King Jeongjo through petro-mineralogical analysis in a quarry and examines the relationship with the stone remains from Geolleung (King Jeongjo's Tomb). The excavated stones from the first burial site of King Jeongjo are all light gray fine-grained biotite granite, and mainly contain quartz, feldspar, and biotite. The magnetic susceptibility of the stones ranges from 5.55 to 12.10 (average 7.00) (SI unit). According to old documents, the quarrying sites of the stones were Mts. Aengbong and Yeogisan (Godeung-dong District, Suwon), and we found a fine-grained biotite granite outcrop behind Mr. Aengbong (currently the site of Yeonggwang Apartment) with a geological survey, and it was petrologically similar to the stone remains from the first burial site. The magnetic susceptibility of the outcrop rocks was 5.15 to 7.24 (SI unit), and their petro-mineral and geochemical characteristics were found to be the same as those of the first buried site and Geolleung Tomb. It was confirmed that most of the stone elements in the first burial site were reused to build Geolleung Tomb while moving the grave. Only the pavement and banister stones seem to have been discarded in the first grave site without being transferred. This is because the size of the new burial mound became larger than the first grave during construction because Queen Hyoui (the consort of King Jeongjo) died and was buried together with the king in the same tomb, and the stone blocks did not fit a grave that size. With these research results, it was possible to compare and examine the old records and scientific analysis data, and they are expected to be used as basic source material in related research.