• Journal of Korean Society for Atmospheric Environment
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• v.22 no.1
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• pp.145-151
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• 2006

As the concerns about indoor air quality (IAQ) increase in recent years, lots of research works are under way to investigate the influence of volatile organic compounds (VOCs) emitted from building products on the IAQ. One of the regulations for the IAQ is the level of total VOCs (TVOCs) from building products, assuming that the TVOCs are suspected to cause many health problems such as skin irritation, asthma, and allergy. However, the presence of biogenic VOCs, or natural VOCs (NVOCs) is believed to be beneficial to human health. Therefore, this study attempted to investigate chemical species and the NVOCs compositions of solid lumbers from different wood species. It was found that major VOC components were monoterpenes such as $\alpha$-pinene, $\beta$-pinene, d-limonene, camphene, $\alpha$-terpinene, $\gamma$-terpinene etc.

• Journal of Korean Society for Atmospheric Environment
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• v.29 no.6
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• pp.757-772
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• 2013

In this study, a combination of sorbent tube (ST)-thermal desorption (TD)-gas chromatography (GC)-mass spectrometry (MS) was used for quantitative analysis of liquid phase standards of 10 BVOC ((1) (+)-${\alpha}$-pinene, (2) (+)-${\beta}$-pinene, (3) ${\alpha}$-phellandrene, (4) (+)-3-carene, (5) ${\alpha}$-terpinene, (6) p-cymene, (7) (R)-(+)-limonene, (8) ${\gamma}$- terpinene, (9) myrcene, and (10) camphene). The results of BVOC calibration yielded comparatively stable pattern with response factor (RF) of 23,560~50,363 and coefficient of determination ($R^2$) of 0.9911~0.9973. The method detection limit (MDL) of BVOC was estimated at 0.03~0.06 ng with the reproducibility of 1.30~5.13% (in terms of relative standard error (RSE)). Emissions of BVOC were measured from four types of fruit samples ((1) tangerine (TO), (2) tangerine peel (TX), (3) strawberry (SO), and (4) sepals of strawberry (SX)). The sum of BVOC flux (${\sum}flux$ (BVOC) in ng/hr/g) for each sample was seen on the descending order of (1) TX=291,614, (2) TO=2,190, (3) SO=1,414, and (4) SX=2,093. If the results are compared between the individual components, the highest flux was seen from (R)-(+)-limonene (265,395 ng/hr/g) from TX sample.

• Journal of Korean Society for Atmospheric Environment
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• v.28 no.5
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• pp.485-494
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• 2012

The purpose of this study is to monitor the flux of $CO_2$ and BVOCs (biogenic volatile organic compounds) between the atmosphere and forest. The main research activities are conducted at Taehwa Research Forest (TRF), managed by the College of Agriculture and Life Sciences at Seoul National University. The TRF site is located 60 km north-east from the center of Seoul Metropolitan Area. The TRF flux tower is in the middle of a Korean Pine (Pinus Koraiensis) plantation ($400m{\times}400m$), surrounded by a mixed forest. Eddy covariance method was used for $CO_2$ flux above the forest and REA (Relaxed eddy accumulation) method applying eddy covariance was used for BVOCs flux. BVOCs flux that was measured in spring (from May 16 to 18) had distribution of 84 to $2917{\mu}g/m^2{\cdot}h$. Especially, it showed that d-limonene being strong reactivity composed the largest fraction of monoterpene. Ambient $CO_2$ concentration measured in Mt. Taehwa was 399 ppm and observed $CO_2$ fluxes between the atmosphere and forest suggested that during the day, $CO_2$ is absorbed by plants through photosynthesis and released during the night.

• Asian Journal of Atmospheric Environment
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• v.9 no.4
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• pp.259-271
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• 2015

This study conducted analyses on biogenic volatile organic compounds (BVOC) emission sources contributing to urban ozone ($O_3$) concentration in Osaka Prefecture, Japan in summer 2010 by using the Weather Research and Forecasting model (WRF) version 3.5.1 and the Community Multiscale Air Quality model (CMAQ) version 5.0.1. This prefecture is characterized by highly urbanized area with small forest area. The contributions of source regions surrounding Osaka were estimated by comparing the baseline case and zero-out cases for BVOC emissions from each source region. The zero-out emission runs showed that the BVOC emissions substantially contributed to urban $O_3$ concentration in Osaka (10.3 ppb: 15.9% of mean daily maximum 1-h $O_3$ concentration) with day-by-day variations of contributing source regions, which were qualitatively explained by backward trajectory analyses. Although $O_3$ concentrations were especially high on 23 July and 2 August 2010, the contribution of BVOC on 23 July (35.4 ppb: 25.6% of daily maximum $O_3$) was much larger than that on 2 August (20.9 ppb: 14.2% of daily maximum $O_3$). To investigate this difference, additional zero-out cases for anthropogenic VOC (AVOC) emissions from Osaka and for VOC emissions on the target days were performed. On 23 July, the urban $O_3$ concentration in Osaka was dominantly increased by the transport from the northwestern region outside Osaka with large contribution of $O_3$ that was produced through BVOC reactions by the day before and was retained over the nocturnal boundary layer. On 2 August, the concentration was dominantly increased by the local photochemical production inside Osaka under weak wind condition with the particularly large contribution of AVOC emitted from Osaka on the day.

• Journal of Korean Society of Environmental Engineers
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• v.33 no.9
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• pp.644-655
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• 2011

VOCs (Volatile Organic Compounds) have adverse effects on human health and have caused serious global air pollution problems such as ozone depletion and cimate changes. The total of 56 target VOCs were selected to be monitored in this study for 4 years (2006~2009). The VOCs were measured every hour. The concentration of BTEX was higher than the other target compounds. Generally, the levels of VOCs measured in this study were higher than those measured by the other studies because Gamjeon and Jangrim monitering sites are located in industrial areas. The seasonal variations showed that the VOCs were the highest in winter. The temporal variations showed that the VOCs were high during commuting time on weekday. PMF model was used to resolve source types and source contributions of VOCs in this study. Identified sources and quantified contributions resolved by PMF were vehicle exhaust (15.22%), thinning solvent (29.83%), surface coating (17.13%), industries (13.95%), LPG vehicle (15.22%), combustion boiler (7.11%) and biogenic source (6.61%). Thinning solvent and Surface coating were the most contributed sources possibly due to manufactures and automobile garages in Gamjeon and solvent and paint manufactures in Sasang-Gu.

• Journal of Environmental Science International
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• v.24 no.2
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• pp.207-219
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• 2015

The purpose of this study is to show the geographical distribution and the temporal variation of the emission amount of biogenic volatile organic compounds(BVOCs) emanated from forests at Jeju Island. The total emission amount of BVOCs calculated by using the CORINAIR Methodology is $3612ton\;yr^{-1}$ at Jeju Island. More than half of BVOCs emissions is come from coniferous forest, and 45 per cent from broad leaved forest. The others is attributed to grassland. Of total emission of BVOCs, isoprene accounts for 28 per cent, monoterpene for 32 per cent, and other VOCs for about 40 percent, respectively. It can be shown that $3000{\sim}10000kg\;yr^{-1}$ of BVOCs is emitted at the zone with dense forest from an altitude of 500 m to the top of Mt. Halla, and less than $1500kg\;yr^{-1}$ at the zone an altitude of below 500 meters. The monoterpene emission is more than $1500kg\;yr^{-1}$ due to the existence of a colony of Abies koreana at the place with more than 1500 meters and a community of Pinus thunbergii and Cryptomeria japonica at the elevation of 500~700 m. In the case of isoprene emission, there is $1500{\sim}3000kg\;yr^{-1}$ at the zone of an elevation from 700 m to 1500 m due to dense broad leaved forest and very little of its emission at an elevation of more than 1500 meters because there is hardly broad leaved trees grown. In this study, emission of BVOCs according to the altitude above sea level is estimated under the situation of lack of the data for broad leaved tree. More detailed data and information for the distribution of broad leaved trees are needed in order to calculate more realistic BVOC emission.

• Journal of Korean Society for Atmospheric Environment
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• v.30 no.6
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• pp.531-537
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• 2014

Terrestrial vegetation has been known as a main source of biogenic volatile organic compounds (BVOCs). Isoprene and monoterpene among the BVOCs are most abundant species emitted by forests, and have a significant impact on atmospheric chemistry. Abundancy of these species could lead to an increase or decrease in the production of natural tropospheric ozone in forests, depending on the nitric oxide (NO) concentration. Soil is the most significant source of natural NO. Understanding of NO emission from forest soil could be critical in evaluation of air quality in the forest area. Flux-gradient similarity theory (FGST) was applied for practical use to estimate forest soil NO emission at Mt. Taewha where is available micro-meteorological data near surface monitoring from flux tower. NO fluxes calculated by FGST were compared to flux results by flow-through dynamic chamber (FDC) measurement. Surface NO emission trends were shown between two different techniques, however their magnitudes were found to be different. NO emissions measured from FDC technique were relatively higher than those from theoretical results. Daily mean NO emissions resulted from FGST during Aug. 13, 14 and 15 were $0.28{\pm}8.45$, $2.17{\pm}15.55$, and $-3.18{\pm}13.65{\mu}gm^{-2}hr^{-1}$, respectively, while results from FDC were $2.26{\pm}1.44$, $5.11{\pm}3.85$, and $2.23{\pm}6.45{\mu}gm^{-2}hr^{-1}$. Trends of daily means were shown in similar pattern, which NO emissions were increasing during late afternoon ($r^2$=0.04). These emission trends could be because soil temperature and moisture influence importantly soil microbiology.

• Atmosphere
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• v.29 no.5
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• pp.689-698
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• 2019

Air pollution in urban areas has become a serious problem in the recent years. Especially, high concentrations of particulate matter (PM) cause negative effects on human health. Several studies suggest urban forest as a tool for improving air quality because of the capability of forests in reducing PM concentrations through deposition and adsorption using leaf area. For this reason, the National Institute of Forest Science plans to install in-situ observation stations for PM and biogenic volatile organic compounds (BVOCs) on a national scale to verify the net effect of forests on urban air pollution. To measure the quantitative change of PM concentrations due to the urban forest, stations should be located within and outside the forest area with respect to atmospheric circulation. In this study, we analyze the wind direction at the potential measurement sites to assess suitable locations for detecting the effect of urban forests on air quality in five cities (i.e. Gwangju, Daegu, Busan, Incheon, and Ilsan). This technical note suggests effective locations of in-situ measurements by considering main wind direction in the five cities of this study. A measurement station network created in the future based on the selected locations will allow quantitative measurements of PM concentration and BVOCs emitted from the urban forest and help provide a comprehensive understanding of the forest capabilities of reducing air pollution.

• Journal of Korean Society of Forest Science
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• v.110 no.4
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• pp.543-553
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• 2021

This research focused on the investigation of isoprene and terpene emissions from 30 major urban tree species. We conducted sampling using a specific dynamic enclosure system between August and September 2020. Seedlings less than three years old were enclosed in a chamber consisting of a 400 L transparent Tedlar bag. The air-flows from the chamber's outlet were sampled using Tenax-filled sorbent tubes in the presence of standard conditions (temperature: 30℃, PAR: 1,000 μmol/m²/sec). A thermal desorption GC/MS system was used to analyze 38 BVOC compounds (isoprene, monoterpene, sesquiterpene, oxygenated monoterpene, and sesquiterpene). Isoprene emitters included Phyllostachys bambusoides, Quercus serrata, Daphniphyllum macropodum, and Buxus Koreana. Monoterpene emitters included Pinus rigida, Acer pictum subsp. mono, Larix kaempfer, Magnolia denudata, Metasequoia glyptostroboides, Pinus koraiensis, Pinus densiflora, and Abies holophylla. The monoterpene emission profiles were dominated by α-pinene, myrcene, limonene, β-pinen, and sabinene, while caryophyllene and farnesene were the prominent sesquiterpenes. Predominant oxygenated monoterpene compounds were also discovered as pulegone, borneol, menthol, eucalyptol, and nerol, while caryophyllene oxide were the prominent oxygenated sesquiterpenes. Sesquiterpenes and oxygenated sesquiterpenes had relatively lower contributions for all species.

• Journal of Korean Society for Atmospheric Environment
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• v.32 no.3
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• pp.320-328
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• 2016

Among biogenic volatile organic compounds (BVOCs) in the natural ecosystem, monoterpenes, along with isoprene, play important roles in atmospheric chemistry and make significant impacts on air pollution and climate change, especially due to their contribution to secondary organic aerosol production and photochemical ozone formation. It is essential to measure monoterpene concentrations accurately for understanding their oxidation processes, emission processes and estimation, and interactions between biosphere and atmosphere. Thus, traceable calibration standards are crucial for the accurate measurement of monoterpenes at ambient levels. However, there are limited information about developing calibrations standards for monoterpenes in pressured cylinders. This study describes about developing primary standard gas mixtures (PSMs) for monoterpenes at about 2 nmol/mol, near ambient levels. The micro-gravimetric method was applied to prepare monoterpene (${\alpha}$-pinene, 3-carene, R-(+)-limonene, 1,8-cineole) PSMs at $10{\mu}mol/mol$ and then the PSMs were further diluted to 2 nmol/mol level. To select an optimal cylinder for the development of monoterpene PSMs, three different kinds of cylinders were used for the preparation and were evaluated for uncertainty sources including long-term stability. Results showed that aluminum cylinders with a special internal surface treatment (Experis) had little adsorption loss on the cylinder internal surface and good long-term stability compared to two other cylinder types with no treatment and a special treatment (Aculife). Results from uncertainty estimation suggested that monoterpene PSMs can be prepared in pressured cylinders with a special treatment (Experis) at 2 nmol/mol level with an uncertainty of less than 4%.