• 제목/요약/키워드: bioconcentration

검색결과 80건 처리시간 0.025초

유해화학물질의 생태계 모델링 - I. 동경만 Nonylphenol의 환경동태 해석 - (Ecological modeling for toxic substances - I . Numerical simulation of transport and fate of Nonylphenol in Tokyo Bay-)

  • 김동명
    • 한국환경과학회지
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    • 제14권9호
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    • pp.827-835
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    • 2005
  • A three-dimensional ecological model (EMT -3D) was applied to Nonylphenol in Tokyo Bay. EMT -3D was calibrated with data obtained in the study area. The simulated results of dissolved Nonylphenol were in good agreement with the observed values, with a correlation coefficient(R) of 0.7707 and a coefficient of determination (R2) of 0.5940. The results of sensitivity analysis showed that biodegradation rate and bioconcentration factor are most important factors for dissolved Nonylphenol and Nonylphenol in phytoplankton, respectively. In the case of Nonylphenol in particulate organic carbon, biodegradation rate and partition coefficient were important factors. Therefore, the parameters must be carefully considered in the modeling. The mass balance results showed that standing stocks of Nonylphenol in water, in particulate organic carbon and in phytoplankton are $8.60\times 10^5\;g,\;2.19\times 10^2\;g\;and\;3.78\times 10^0\;g$ respectively. With respect to the flux of dissolved Nonylphenol, biodegradation in the water column, effluent to the open sea and partition to particulate organic carbon were $6.02\times10^3\;g/day,\;6.02\times10^2\;g/day\;and\;1.02\times10^1\;g/day$, respectively.

식물을 이용한 대기 중 PCBs의 농도 예측 평가 (Estimation of Bio-Monitoring for PCBs Concentration in Air Using Plant)

  • 여현구;최민규;천만영;김태욱;선우영
    • 한국대기환경학회지
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    • 제18권4호
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    • pp.265-274
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    • 2002
  • The concentrations of polychlorinated biphenyls (PCBs) in air and plant were measured every other week at Hankyong University located in Ansung, Kyoung-ki province from July to November of 1999. The predicted PCB concentrations in air derived from measured Morus allba were compared with ambient measurement data. This was necessary to test the possibility of using the two equations incorporating Riederer's and Bacci's bioconcentration factors (BCFs) based on the octanol-air partition coefficient (Ksub/oa/) to predict the air-plant equilibrium of PCBs. Ratios of calculated to measured PCB concentrations in air were 2.4 (1.24~4.36), 2.7 (0.17~7.96) using Riederer's and Bacci's equations, respectively Regression analysis between PCBs calculated by Riederer's equation and PCBs directly measured in air, showed correlation ($R^2$= 0.90). However, slope of regression between calculated and directly measured PCB concentrations was above 1. The results thus suggest that calculated PCBs were overestimated comparing with direct measurements. Bio-monitoring using Morus allba may have possibilities in predicting PCBs concentration in air with a further extension of air-plant equilibrium research.

담수 및 해양생태계에서 나노물질의 먹이사슬전이 연구추세 (Research Trends of Food Chain Transfer of Nanomaterials in Freshwater and Marine Ecosystems)

  • 채유은;안윤주
    • 한국물환경학회지
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    • 제30권6호
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    • pp.683-690
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    • 2014
  • Nanomaterials are used in a range of fields, including industry, medicine, aerospace, and manufacturing, due to their unique and useful properties. In recent years, nanotechnology has developed rapidly, and the amount of nanomaterials used in various fields has increased consistently. As a result, nanomaterials are released into the aquatic and soil ecosystem, posing potential risks to organisms and environment. These materials can enter the cells and may cause serious damage to organisms. Furthermore, they can be transferred through trophic levels and food web, thereby leading to bioconcentration and biomagnification. In this study, we analyzed the trends in research on food chain transfer of nanomaterials and investigated the techniques used in the research. Although many studies have been underway, there is a need for further advanced studies on higher trophic levels and complex microcosm and mesocosm. Furthermore, study topics should be expanded to include various types of nanomaterials and varied species and trophic levels.

토양 내 서식하는 공벌레의 중금속 축적에 따른 생태적 연구 (Ecological study on effects of heavy metal accumulation on pillbugs)

  • 이상돈
    • 환경영향평가
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    • 제20권5호
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    • pp.675-684
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    • 2011
  • In nature, the overall effect of heavy metals on the biota can be influenced by a number of environmental factors like soil characteristics and air pollution by elevated $CO_2$. Pillbugs (Isopoda, Armadillium vulgare) take up heavy metals with their food and store them mainly in the vesicles of hepatopancreas. They accumulate certain metals, occur in relatively large numbers, are easily collected and identified, and provide sufficient material for analysis. The species are decomposing litter well and soil impurities into N and P. Therefore, it has been suggested that total body concentration of metals in pillbugs could be positively correlated to the levels of environmental exposure and that pillbugs could be used as biological indicators of metal pollution and global change by $CO_2$. The aim of the study is to determine effects of heavy metal concentrations in soil and elevated $CO_2$ on pillbugs' body accumulation of heavy metal and growth rate. In this study, the concentrations of six metals (Fe, Mg Cu, Zn, Pb, Cd) have been determined. Pillbugs (N=287) were collected at five sites during Jul-Aug, 2006. Cu and Zn concentrations in the body were much higher than in the soils(1.39-41.70 times). This indicated that bioaccumulation of some of the heavy metals were increasing in the food-chain. The high bioconcentration of lead in Sangam may be partly associated with reclaimed land uses.

Di-2-ethylhexyl phthalate의 수서생태계 먹이사슬을 통한 생물축적 및 거동예측 (Fate of Di-2-ethylhexyl Phthalate in Aquatic Food Chain)

  • 김은주
    • 한국환경보건학회지
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    • 제30권3호
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    • pp.264-271
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    • 2004
  • An aquatic food chain was constructed to provide information of bioaccumulation of DEHP as followed: phytoplankton(Scenedesmus subspicatus) ${\rightarrow}$ zooplankton(Daphnia magna) ${\rightarrow}$ fish(Oryzias latipes). After 10 days of exposure to DEHP, the fish and culture water were analyzed for residual concentration of DEHP and BAF(Bioaccumulation Factor) was determined. In addition, BCF(Bioconcentration Factor) was calculated in exposure tank in which fish were only exposed DEHP by culture water. These experiments provide the relative importance between BAF and BCF. In this study, BCF and BAF did not show any significant difference. Another work in this study was model construction and application to investigate the effect of food chain structure to BAF in higher organism (fish). The model constructed in this study considered the biological characteristics of DEHP such as metabolic parameters, as well as the chemical characteristics such as solubility. This model could be used in prediction of bioaccumulation level in dependent of various food chain structures, when the target organisms or chemicals would be changed.

Identification of Transition Characteristics and Bio-concentration Factors of Heavy Metal (loid)s in the Selected Perennial Root Medicinal Plants

  • Kim, Won-Il;Noh, Hyun Myung;Hong, Chang-Oh;Kim, Da-Young;Kim, Kwon-Rae;Oh, Kyeong-Seok;Moon, Byeong-Churl;Kim, Ji-Young
    • 한국토양비료학회지
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    • 제50권4호
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    • pp.251-258
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    • 2017
  • This study was conducted to identify transition characteristics of arsenic (As), cadmium (Cd), and lead (Pb) and to calculate bio-concentration factors (BCF) in the three perennial root medicinal plants, namely Codonopsis lanceolata (Deoduck), Platycodon grandiflorum (Balloon flower) and Panax ginseng (Korean ginseng) grown in major medicinal plant producing districts in Korea. Average BCF values ranged from 0.009~0.029 in As, 0.334~1.453 in Cd, and 0.021~0.023 in Pb in three perennial root medicinal plants. The BCF values increased in the order of ginseng (0.029) > deodeok (0.012) > balloon flower (0.009) for As, balloon flower (1.453) > deodeok (0.685) > ginseng (0.334) for Cd, and ginseng (0.023) > deodeok (0.022) > balloon flower (0.021) for Pb. The BCF values calculated in this study will be useful for predicting the uptake of heavy metal (loid)s. Further study on uptake and accumulation mechanism of toxic metal (loid)s by agricultural products is required to assess the human health risk associated with soil contamination.

EMT-3D 모델을 이용한 진해만 PAHs의 거동 예측 시뮬레이션 (Numerical Simulation for the Prediction of PAHs in Jinhae Bay using EMT-3D Model)

  • 김동명
    • 해양환경안전학회지
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    • 제17권1호
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    • pp.7-13
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    • 2011
  • 진해만을 대상으로 3차원 생태계 모델(EMT-3D)을 사용하여 PAHs 거동예측에 대한 적용성을 검토하였다. 계산치와 실측치를 비교한 결과, 모델의 재현성은 비교적 양호한 것으로 나타났다. 민감도 분석을 시행하여 영향인자를 파악한 결과, 용존 PAHs의 경우 광분해 계수의 영향이, 입자성 유기물질 내 PAHs의 경우는 입자성 유기탄소에 대한 분배계수의 영향이 중요한 요소였다. 식물플랑크톤 체내의 PAHs의 경우, 생물농축계수의 영향이 가장 큰 것으로 나타났다. 하천, 대기와 하천 및 대기의 오염부하에 대하여 저감에 따른 응답성 평가를 시행하였다.

진해만의 퇴적물, 해수 및 참굴 내의 중금속 분포 (Distribution of Heavy Metals in Sediments, Seawater and Oysters (Crassostrea gigas) in the Jinhae Bay)

  • 이인숙;김은정
    • The Korean Journal of Ecology
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    • 제23권1호
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    • pp.59-64
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    • 2000
  • 진해만의 중금속 오염도를 평가하기 위해 해저퇴적물, 해수 및 참굴의 중금속 농도를 측정하였다. 해저퇴적물내 카드뮴, 코발트, 구리, 니켈, 납, 아연의 농도범위는 0.1∼2.4, 12.6∼14.4, 25.3∼92.3, 32. 4∼93.5, 24.1∼81.2, 124∼477 ㎍/g 으로 나타났다. 인간의 산업활동과 관련된 카드뮴, 구리, 납, 아연의 농도는 마산 내만에서 높게 나타났다. 해수내의 용존성 카드뮴, 코발트, 구리, 니켈, 납, 아연의 농도범위는 <0.010∼0.043, 0.008∼0.120,0.31∼0.90,0.25∼3.10, 0.010∼0.142,0.27∼9.04 ㎍/L로 나타났다. 해수의 카드뮴, 구리, 납, 아연의 농도도 퇴적물에서처럼 마산 내만에서 높게 나타났으므로 마산만이 진해만의 주오염원임을 알 수 있었다. 참굴의 아연, 구리, 카드뮴, 납, 코발트, 니켈 둥의 생물농축계수(BCF)는 647373, 280861, 145069, 44559, 13524, 2745 순으로 나타났으며, 다른 이매패류에 비해 강한 중금속 축적종으로 나타났다.

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대기 중 $CO_2$ 및 토양 중 Pb 농도 증가가 공벌레의 성장과 공벌레 체내 Pb 축적에 미치는 영향에 관한 연구 (Studies on Effect of $CO_2$ Concentration in Air and Pb Concentration in Soil on Pillbug Growth and Bio-accumulation)

  • 황화연;이상돈
    • 환경영향평가
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    • 제19권6호
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    • pp.539-546
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    • 2010
  • In nature, the overall effect of heavy metals on the biota can be influenced by a number of environmental factors like soil characteristics and air pollution by elevated $CO_2$. Pillbugs(Isopoda, Armadillium vulgare) take up heavy metals with their food and store them mainly in the vesicles of hepatopancreas. They accumulate certain metals, occuring in relatively large numbers, are easily collected and identified. Therefore, it has been suggested that total body concentration of metals in pillbugs could be positively correlated to the levels of environmental exposure and that pillbugs could be used as biological indicators of metal pollution and global change by $CO_2$. The aim of the study is to determine effects of heavy metal concentrations in soil and elevated $CO_2$ on pillbugs'body accumulation of heavy metal and growth rate. In this study, pillbugs were collected at five sites (N=287) May 2006. Cu and Zn concentrations in pillbugs were higher than in soils (1.39-41.70 times) than in control. The high bioconcentration of lead in Sangam may be partly associated with reclaimed land uses. Pillbugs in low $CO_2$ and Pb condition showed higher growth rate than in elevated $CO_2$ and Pb condition.

국내 남해 및 남서해안지역 해양퇴적물과 저서성 유공충 골격내 중금속함량 (Heavy Metal Concentrations of Marine Surface Sediments and Benthic Foraminifera in Southern and Southwestern Coastal Areas of Korea)

  • 김경웅;윤혜수;이성숙;정규귀
    • 자원환경지질
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    • 제30권3호
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    • pp.223-230
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    • 1997
  • The skeletal chemistry of calcareous microfossils may contribute to the classification of various biological processes and be used as an environmental indicator for future pollution. In order to examine the degree of heavy metal pollutions in marine environments, samples of sediment and benthonic foraminifera were taken from 5 study areas from 3 different stations in coastal offshore regions of Korea. After sieving, cleaning and acid digestion, sample were analyzed for heavy metals by ICP-MS, ICP-AES and AAS. Concentrations of Cd, Cu, Pb and Zn in most of marine sediments from 5 study areas are not higher than those in sediments from unpolluted marine environment in the U.K.. However, pollution indices are up to 0.96~0.99 in the Gwangyang and Yulchon areas which are classified as the special control distric along the coast for pollution. The pollution indices decrease in order of Yulchon > Gwangyang > Mokpo > Gamak = Yoja > Yonggwang areas. Concentrations of Mg, Pb, Sr and Zn in Ammonia beccarii Pseudorotalia gaimardii, Quinqueloculina lamarckiana are reduced after pre-treatment of samples. From the result of bioconcentration index, Mg is easily accumulated in microfossils and Quinqueloculina lamarckiana may be used as the best indicator for future pollution.

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