• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.14 no.2
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• pp.91-100
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• 2016

The neutron activation inventories in reactor vessel and its internals, and bio-shield of a PWR nuclear power plant were calculated to evaluate the effect of impurity elements contained in the structural materials on the activation inventory. Carbon steel is, in this work, used as the reactor vessel material, stainless steel as the reactor vessel internals, and ordinary concrete as the bio-shield. For stainless steel and carbon steel, one kind of impurity concentration was employed, and for ordinary concrete five kinds were employed in this study using MCNP5 and FISPACT for the calculation of neutron flux and activation inventory, respectively. As the results, specific activities for the cases with impurity elements were calculated to be more than twice than those for the cases without impurity elements in stainless and carbon steel. Especially, the specific activity for the concrete material with impurity elements was calculated to be 30 times higher than that without impurity. Neutron induced reactions and activation inventories in each material were also investigated, and it is noted that major radioactive nuclide in steel material is Co-60 from cobalt impurity element, and, in concrete material, Co-60 and Eu-152 from cobalt and europium impurity elements, respectively. The results of this study can be used for nuclear decommissioning plan during activation inventory assessment and regulation, and it is expected to be used as a reference in the design phase of nuclear power plant, considering the decommissioning of nuclear power plants or nuclear facilities.

• Journal of Environmental Science International
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• v.15 no.2
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• pp.133-139
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• 2006

Soil biofiltration is an environmentally-sound technology for elimination of VOCs, odorous and NOx compounds from a low concentration, high volume waste gas streams because of its simplicity and cost-effectiveness. This study was performed to evaluate effect of removal of gaseous NOx using a soil and a yellow soil. Over $60\%\;and\;48\%$ of NOx from a soil and a yellow soil was removed at the inlet NO concentrations of $423\~451$ppb, respectively. The bio-filter using a soil media was capable of purifying NOx with a different natural processes. Although some of the processes are quite complex, they can broadly be summarized as adsorption into soil pore water, and biochemical transformations by soil bacteria. When the filteration bio-reactor was applied to a soil and a yellow soil, effective NOx removal was obtained for several times and months. These results show that a soil biofilter can be of use as an alternative advanced NOx treatment system.

• Journal of Hydrogen and New Energy
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• v.34 no.6
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• pp.581-586
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• 2023

As the development of alternative energy is required due to the depletion of fossil fuels, interest in the use of hydrogen energy is increasing. Hydrogen is a promising clean energy source with high energy density and can lead to the application of environmentally friendly technologies. However, due to difficulties in production, storage, and transportation that prevent the application of hydrogen-based eco-friendly technology, research on reforming reactions using dimethyl ether (DME) is being conducted. Unlike other hydrocarbons, DME is attracting attention as a hydrogen carrier because it has excellent storage stability and transportability, and there is no C-C bond in the molecule. The reaction between DME and steam is one of the reforming processes with the highest hydrogen yield in theory at a temperature lower than that of other hydrocarbons. In this study, a hydrogen reforming device using DME was developed and a catalyst prepared by supporting Cu in alumina was put into a reactor to find optimal hydrogen production conditions for supplying hydrogen to fuel cells while changing reaction temperature (300-500℃), pressure (5-10 bar), and steam/carbon ratio (3:1 to 5:1).

• Journal of Environmental Science International
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• v.13 no.3
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• pp.245-250
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• 2004

The SBR(Sequencing Batch Reactor) process is ideally suited to treat high loading wastewater due to its high dilution rate. SBR operates by a cycle of periods consisting of filling, reacting, settling, decanting and idling. The react phases such as aeration or non-aeration, organic oxidation, nitrification, denitrification and other bio-logical reactions can be achieved in a reactor. Although the whole reactions can be achieved in a SBR with time distributing, it is hard to manage the SBR as a normal condition without recognizing a present state. The present state can be observed with nutrient sensors such as ${NH_{4}}^{+}-N$, ${NO_{2}}^{-}-N$, ${NO_{3}}^{-}-N} and ${PO_{4}}^{ 3-}-P.$ However, there is still a disadvantage to use the nutrient sensors because of their high expense and inconvenience to manage. Therefore, it is very useful to use common on-line sensors such as DO, ORP and pH, which are less expensive and more convient. Moreover, the present states and unexpected changes of SBR might be predicted by using of them. This study was conducted to get basic materials for making an inference of SBR process from ORP(oxidation reduction potential) of synthetic wastewater. The profiles of ORP, DO, and pH were under normal nitrification and denitrification were obtained to compare abnormal condition. And also, nitrite and nitrate accumulation were investigated during reaction of SBR. The bending point on ORP profile was not entirely in the low COD/NOx ratio condition. In this case, NOx was not entirely removed, and minimum ORP value was presented over -300mV. Under suitable COD/NOx ratio which complete denitrification was achieved, ORP bending point was observed and minimum ORP value was under -300m V. Under high COD/NOx ratio, ORP bending point was not detected at the first subcycle because of the fast denitrification and minimum ORP value was under -300mV at the time.

• New & Renewable Energy
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• v.19 no.4
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• pp.20-26
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• 2023

Emitted CO₂ is an attractive material for microbial electrochemical CO₂ reduction. Microbial electrochemical CO₂ reduction (i.e., microbial electrosynthesis, MES) using biocatalysts has advantages compared to conventional CO₂ reduction using electrocatalysts. However, MES has several challenges, including electrode performance, biocatalysts, and reactor optimization. In this study, an MES system was investigated for optimizing reactor types, counter electrode materials, and CO₂-converting microorganisms to achieve effective CO₂ upcycling. In autotrophic cultivation (supplementation of CO₂ and H₂), CO₂ consumption of Rhodobacter sphaeroides was observed to be four times higher than that with heterotrophic cultivation (supplementation of succinic acid). The bacterial growth in an MES reactor with a single-chambered shape was two times higher than that with a double chamber (H-type MES reactor). Moreover, a single-chambered MES reactor equipped with titanium mesh as the counter electrode (anode) showed markedly increased current density in the graphite felt as a working electrode (cathode) compared to that with a graphite felt counter electrode (anode). These results demonstrate that the optimized conditions of a single chamber and titanium mesh for the counter electrode have a positive effect on microbial electrochemical CO₂ reduction.

• Environmental Engineering Research
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• v.25 no.1
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• pp.1-17
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• 2020

With benefits to the human health, environment, economy, and energy, anaerobic digestion (AD) systems have attracted remarkable attention within the scientific community. Anaerobic digestion system is created from (bio)reactors to perform a series of bi-metabolism steps including hydrolysis/acidogenesis, acetogenesis, and methanogenesis. By considering the physical separation of the digestion steps above, AD systems can be classified into single-stage (all digestion steps in one reactor) and multi-stage (digestion steps in various reactors). Operation of the AD systems does not only depend on the type of digestion system but also relies on the interaction among growth factors (temperature, pH, and nutrients), the type of reactor, and operating parameters (retention time, organic loading rate). However, these interactions were often reviewed inadequately for the single-stage digestion systems. Therefore, this paper aims to provide a comprehensive review of both single-stage and multi-stage systems as well as the influence of the growth factors, operating conditions, and the type of reactor on them. From those points, the advantages, disadvantages, and application range of each system are well understood.

• Proceedings of the Korean Society for Agricultural Machinery Conference
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• 1996.06c
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• pp.701-710
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• 1996

Composting has gained rapid acceptance as a method of recyling relatively dry organic materials such as leaves and brush and , when alternative disposal costs are high, even moist materials such as grass clippings and dewatered sewage sludges. However, as moisture contents rise above 60% , the need for a dry bulking amendment increase the costs of composting , both by direct purchases of amendment and though increased reactor capacity and materials handling requirements. High moisture materials also present increased risks of anaerobic odor formation through reduced oxygen transport (Miller , 1991) . These costs and operational challengers often constrain the opportunities to compost high moisture materials such as agricultural manures. During the last several decades economies of scale in livestock production have been increasing livestock densities and creating manure management challenges throughout the world. This issue is particularly pressing in Korea, where livestock arms typically manage little or no cropland, and the nutrients and boichemical oxygen demand in manure pose a serious threat to water quality. Composting has recently become popular as a means of recycling manure into products for sale off the farm, but bulking amendments (usually sawdust) are expensive designed to minimize bulking agent requirements by using the energy liberated by decompostion. In this context the composting reactor is used as a biological dryer, allowing the repeated use of bulking amendment with several batches of manure.

• Biotechnology and Bioprocess Engineering:BBE
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• v.8 no.1
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• pp.23-31
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• 2003

A mathematical model was formulated to simulate the long-term performance of an anaerobic bioreactor designed to digest Korean food wastes. The system variables of various decomposition steps were built into the model, which predicts the temporal characters of Solid waste, and volatile fatty acid (VFA) in the reactor, and gas production in response to various input loadings and temperatures. The predicted values of VFA and gas production were found to be in good agreement with experimental observations in batch and repeated-input systems. Finally, long-term reactor performance was simulated with respect to the seasonal temperature changes from 5C in winter to 25C in Summer at different food waste input loadings. The simulation results provided us with information concerning the success or failure of a process during long-term operation .

• Journal of environmental and Sanitary engineering
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• v.16 no.1
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• pp.34-39
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• 2001

Submerged Membrane Bio-Reacter(SMBR) process was used to food wastewater treatment. From laboratory pilot-scale experiment data, it was confirmed that this process was very effective process for organics, suspended solid, and N, P treatment. It was found that BOD and COD removal rate were obtained 90% and 92%, respectively, for 150 days operation. Organics loading rate did not affect to the removal efficiency because MLSS concentration in aerobic tank was highly maintained. IN the case of first reactor operated with anoxic and second reactor operated as aerobic, T-N, T-P removal rate were obtained 93% and 95%, respectively. It was shown that removal efficiency could be maintained stable due to the complete removal of SS and sludge production decreased with increasing of sludge retention time.

• Korean Chemical Engineering Research
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• v.54 no.5
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• pp.687-692
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• 2016

Biomass has been concerned as one of the alternative energy resources because it is renewable, abundant worldwide, eco-friendly, and carbon neutral. Quercus variabilis has been studied to understand pyrolysis reaction characteristics, and to evaluate the efficiency of bio-energy production from fast pyrolysis. Quercus variabilis were fast pyrolyzed in a bubbling fluidized bed reactor at various reaction conditions. The effects of pyrolysis temperature between $400^{\circ}C$ and $550^{\circ}C$ on product yields were investigated. The yield of bio-oil was changed between 36.98 wt% and 39.14 wt%, and those of gas yield was 33.40 and 36.96 wt% with increasing reaction temperature. The higher heating value (HHV) of bio-oil at $500^{\circ}C$ ($3.0{\times}U_{mf}$) was 20.18 MJ/kg. The gas compositions were similar for all reaction conditions such as CO, $CO_2$ and $CH_4$, and $CO_2$ selectivity was the highest (37.16~50.94 mol%). The bio-oil has high selectivities for furfural, phenol and their derivatives such as 1-hydroxy-2-propanone, 2-methoxy-phenol, 1,2-benzendiol, 2,6-dimethoxy-phenol.