• Title/Summary/Keyword: binding material

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Correlation Between Arrhenius Equation and Binding Energy by X-ray Photoelectron Spectroscopy

  • Oh, Teresa
    • Transactions on Electrical and Electronic Materials
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    • v.14 no.6
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    • pp.329-333
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    • 2013
  • SiOC films were prepared by capacitively coupled plasma chemical vapor deposition, and the correlation between the binding energy by X-ray photoelectron spectroscopy and Arrhenius equation for ionization energy was studied. The ionization energy decreased with increase of the potential barrier, and then the dielectric constant also decreased. The binding energy decreased with increase of the potential barrier. The dielectric constant and electrical characteristic of SiOC film was obtained by Arrhenius equation. The dielectric constant of SiOC film was decreased by lowering the polarization, which was made from the recombination between opposite polar sites, and the dissociation energy during the deposition. The SiOC film with the lowest dielectric constant had a flat surface, which depended on how carbocations recombined with other broken bonds of precursor molecules, and it became a fine cross-linked structure with low ionization energy, which contributed to decreasing the binding energy by Si 2p, C 1s electron orbital spectra and O 1s electron orbital spectra. The dielectric constant after annealing decreased, owing to the extraction of the $H_2O$ group, and lowering of the polarity.

Optimum Design of the Agricultural Support and Binder for Stretching Device (가중치법을 이용한 농작물 지지대 및 결속장치의 최적설계)

  • Lee, Man-Gi;Kim, Jin-Ho;Shin, Ki-Yeol
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.14 no.4
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    • pp.28-33
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    • 2015
  • In this study, the optimal design for the support and the binding device for the protection of crops for the maximum allowable stress of the shape necessary to minimize volume has been proposed. Optimization of the support and the binding device for the crops should be designed to support businesses in terms of profit, in part to reduce the material, and to profit from the ease and speed of working that part of the farmers. We used CATIA for the mechanical design and the ANSYS program for the structural analysis. Additionally, the optimization was performed by PIAnO with seven design variables for the binding device and three parameters for the support. The weight method using a multi-objective function was also determined by the Pareto optimal solution. The volume of the binding device in the optimum design result was found to be reduced by 16%, from $2.278e-005m^3to1.912e-005m^3$. From the result, we confirmed the effectiveness of the design method proposed as a multi-objective function optimization problem.

Effects of Individual Fatty Acids on Receptor-Mediated Binding, Internalization and Degradation of $[^{125}I]LDL$

  • Choue, Ryo-Won;Cho, Byung-Hee Simon
    • BMB Reports
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    • v.30 no.1
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    • pp.1-6
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    • 1997
  • The ability of Hep-G2 cells to process $[^{125}I]LDL$ under basal conditions was investigated. The receptor-binding and internalization of $[^{125}I]LDL$ increased with the time of incubation in a saturable manner. After 4 h of incubation, 31.4 ng of $[^{125}I]LDL$ was cell bound. The cells rapidly internalized $[^{125}I]LDL$ via specific, receptor-mediated endocytosis. The amount of internalized $[^{125}I]LDL$ reached a maximun of 96.7 ng at 2 h of incubation and remained constant for the next 2 h. The rate of degradation of internalized $[^{125}I]LDL$ proceeded in a linear manner over the entire 4 h of incubation after an initial lag period. The effects of individial fatty acids (C18:0. C18:1, C18:2. and C18:3), differing in their degree of unsaturation. on the receptor-binding, internalization and degradation of $[^{125}I]LDL$ were also investigated. Inclusion of 1.0 mM of each fatty acid into the culture medium significantly increased $[^{125}I]LDL$ metabolism in Hep-G2 cells. Among the fatty acids tested, stearic acid had the least effect on the receptor-binding activity. There were no significant differences among the unsaturated fatty acids in LDL-receptor binding. The effect of individual fatty acids on the $[^{125}I]LDL$ uptake was similar to that of the receptor-binding. showing a significantly lower effect with stearic acid. The amount of degraded material of internalized $[^{125}I]LDL$ was the lowest with stearic acid when it was compared with unsaturated fatty acids.

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Study on the Manufacturing of Leather-like Material using Leather and Textile Scrap (피혁 및 섬유 제조공정 폐기물을 활용한 피혁 대체 소재의 제조에 관한 연구)

  • Kim, Won-Ju;Ko, Jae-Yong;Heo, Jong-Soom
    • Journal of the Korea Organic Resources Recycling Association
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    • v.8 no.4
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    • pp.93-99
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    • 2000
  • Treatment of shaving scrap, a chrome containing solid scrap generated by leather manufacturing process, has been so far depended on mainly incineration, soil landfill and ocean dumping, which give bad impact on environment and cause pollution. Shaving scrap generates from the mechanical work for controlling the final thickness of leather and its main components are collagen protein and pan of chromium compound. For the purpose of reusing this leather waste as resources, researches in connection with collagen fiber recovery, gelable protein recovery and liquid fertilizer is being speedily progressed. In the experiment, shaving scrap went through wet pulverizing treatment by physical and chemical methods. Then, making the leather sheet evenly, it is mixed with natural latex and every kind of binding materials in the container, and the mixtures were passed through experimental hydraulic press machine and applied to Fourdrinier machine respectively. Lastly, a test for fading out physical strength and properties of multiple-purpose of leather-like material was performed on a continuous leather sheet prepared by the experiment. In result, the physical strength and properties of leather-like material showed noticeable differences according to mixing ratio of binding materials, beating methods and the Ends of binding materials selected, and generally tear strength was the weakest property among others. Also, by the pilot scale experiment in sequence, it was possible to manufacture recycled goods made of soft and hard types of leather-like material with various performances.

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Effects of high glucose concentration on IGF-I binding and glucose transporters in renal proximal tubule cells (신장 근위세뇨관세포에서 고포도당이 IGF-I 결합과 포도당운반계에 미치는 영향)

  • Han, Ho-jae;Park, Kwon-moo;Son, Chang-ho;Yoon, Yong-dal
    • Korean Journal of Veterinary Research
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    • v.37 no.2
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    • pp.301-310
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    • 1997
  • Diabetes mellitus is associated with a wide range of pathophysiological in the kidney. This study was designed to examine the effects of high glucose concentration on IGF-I binding and glucose transporters in renal proximal tubule cells. The results were as follows : The binding of $^{125}I-IGF-I$ reached the peak at the 30 minutes and gradually decreased by the time dependent manner. The binding of $^{125}I-IGF-I$ was inhibited by the unlabelled IGF-I($10^{-14}{\sim}10^{-8}M$) in a concentration dependent manner. The relative affinity of IGF-I receptor for IGF-I, IGF-II and insulin exhibited typical type 1 binding(IGF-I > insulin > IGF-II). However IGF-II did not compete for the cultured cell membrane $^{125}I-IGF-I$ binding site at $10^{-14}{\sim}10^{-8}M$. Under optimal conditions, IGF-I binding to the membranes from 5mM and 20mM glucose treated cells was analyzed. It was found that 20mM glucose treated cells exhibited higher binding activity for IGF-I. In order to further substantiate this increase in IGF-I binding sites, we performed affinity-labelling studies. The cross-linked cell membrane subjected to SDS-PAGE; labelled material was detected by autoradiography. 20mM glucose treated cells exhibited higher levels. The initial rate of $methyl-{\alpha}-D-glucopyranoside({\alpha}-MG)$ uptake was significantly lower($74.41{\pm}6.71%$) in monolayers treated with 20mM glucose than those of 5mM glucose. However, 3-O-methyl-D-glucose(3-O-MG) uptake was not affected by glucose concentration in culture media. IGF-I significantly increased ${\alpha}-MG$ uptake in both 5mM and 20mM glucose treated cells. However, 3-O-MG uptake was not affected by IGF-I in both conditions. In conclusion, 20mM glucose increased binding sites of $^{125}I-IGF-I$, inhibited Na/glucose cotransporter activity. But 20mM glucose did not change facilitated glucose transporter.

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The effects on the crystal structure of Polypropylene exposed Radiation and Its dielectric properties (방사선이 폴리프로필렌의 결정구조에 미치는 영향과 유전특성)

  • 강전홍;김한준;유광민;박강식;김종석;한상옥
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.894-896
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    • 2001
  • The Polypropylene films which are made by refinement of its pellet and formed as crystals are exposed to Radiation. As the results, degradation effects were observed in non-crystalline regions. It is thus considered that the effects occur by destroying of lattice binding force by Radiation. The distribution of degradation was increased with irradiation quantities of Radiation and dielectric constant of Polypropylene sheets irradiated Radiation was rapidly increased from above 10 MHz.

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Increase of ICSI Efficacy with Hyaluronic Acid-Binding Sperm for Low Aneuploidy Frequency in Pig

  • Park, Chun-Young;Uhm, Sang-Jun;Song, Sang-Jin;Kim, Kwag-Sung;Hong, Seung-Bum;Chung, Kil-Saeng;Lee, Hoon-Taek
    • Proceedings of the KSAR Conference
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    • 2003.06a
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    • pp.26-26
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    • 2003
  • Hyaluronic acid (HA)-binding sites have been shown the diagnostic potential fur assessment of sperm maturity, which is related to male fertility. This study was designed to evaluate chromosomal patterns in porcine embryos produced by in vitro fertilization (IVF) and intracytoplasmic sperm injection (ICSI) with non- or HA-binding sperm (HABS). For binding of sperm with HA, sperm incubated in 10 ${mu}ell$ drop containing HA (0.8 mg/ml)-agarose (0.8%) mixture for 15 min. IVF and ICSI with non- or HA-bound sperm examined with matured oocytes at 44 hr after in vitro maturation. Embryos were cultured in 50 ${mu}ell$ of NCSU 23 containing 0.5% BSA for 5 days and then in 50 ${mu}ell$ of NCSU 23 containing 10% FBS for 2 days. For the evaluation of chromosomal aneuploidies, chromosome 1 sub-metacentric specific probe was used in sperm and embryos by fluorescence in situ hybridization (FISH). The frequency of aneuploidy sperm for chromosome 1 was 6.25%. The significant differences following IVF and ICSI with non- or HA-bound sperm were not observed in blastocyst formation rates (18.6, 23.5, and 23.8%) and cell number (61.8 $\pm$ 12.5, 55.5 $\pm$ 7.3, and 59.3 $\pm$ 9.6). Moreover, the percentage of diploidy in 4-cell stage embryos was 57.1% (IVF), 68.8% (ICSI), and 76.3% (ICSI-HABS). These results suggest that HA-binding sites may be a material for selection of normal sperm for ICSI. Therefore HA selection of normal sperm may be reduce the loss to embryonic mortality prior to embryo transfer in pig.

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Experimental study on the periodontal regenerative capacity of moldable synthetic peptide domain gel in degree III furcation defect of beagles (성견의 3급 이개부 병변에서 성형성 합성 펩타이드 젤의 치주재생 능력에 관한 실험적 연구)

  • Kim, Jeong-Beom;Park, Yoon-Jeong;Lee, Sang-Cheol;Kim, Tae-Il;Seol, Yang-Jo;Lee, Yong-Moo;Gu, Young;Rhyu, In-Chul;Han, Soo-Boo;Chung, Chong-Pyoung
    • Journal of Periodontal and Implant Science
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    • v.38 no.4
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    • pp.621-628
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    • 2008
  • Purpose: Osteopontin is one of the major non-collagenous protein of hard tissue. Use of peptide domain of biologically active protein has some advantages. The objective of this experimental study is evaluation of periodontal regenerative potency of synthetic peptide gel which containing collagen binding domain of osteopontin in the degree III periodontal defect of beagle dogs. Material and Methods: Experimental degree III furcation defect was made in the mandibular third and fourth premolar of beagles. Regenerative material was applied during flap operation. 8 weeks after regenerative surgery, all animals were sacrificed and histomorphometric measurement was performed to calculate the linear percentage of the new cementum formation and the volume percentage of new bone formation. Result: The linear percent of new cementum formation was 41.6% at control group and 67.1% at test group and there was statistically significant difference. The volume percent of new bone formation was 52.1% at control group and 58.9% at test group. Conclusion: As the results of present experiment, synthetic peptide gel containing collagen binding domain of osteopontin significantly increase new bone and cementum formation in the degree III furcation defect of canine mandible.

A Study on the Mechanical and Flowing Properties of High-strength Mortar Binding Admixture (고강도 모르타르용 결합재의 유동특성 및 역학특성에 관한 연구)

  • Lee, Sang-Soo;Lee, Yun-Seong;Lee, Kang-Pil
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.4
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    • pp.105-110
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    • 2009
  • It's important to study about suitable substitutional material of expensive silica fume because it used widely for silica fume as a high-strength mortar binding agent. The main purpose of this study is to check which is the most efficient binder for the expensive silica fume's alternative material. And this study also present basic data about to make high-strength mortar when we use alternative material instead of silica fume through research outcome. Also writers analzed flow properties respectively, so it was founded out the substitutional goods fare like meta-kaolin, HMBA which are less expensive than silica fume because they are in domestic enough.

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Preparation of NiO/YSZ Ultra-Fine Powder Composites Using Self-Sustaining Combustion Process (Self-Sustaining Combustion Process를 이용한 NiO/YSZ 초미세 복합분말 제조)

  • 김선재;정충환;김경호;김영석;국일현
    • Journal of the Korean Ceramic Society
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    • v.33 no.4
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    • pp.411-417
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    • 1996
  • Ultrafine NiO/YSZ (Yttria Stabilized Zirconia) powders were made by using a glycine nitrate process which is used as anode material for solid oxide fuel cells. The specific surface areas of synthesized NiO/YSZ powders were examined with controlling pH of a precursor solution and the content of glycine. The binding of glycine with metal nitrates occurring in the precursor solution was analyzed by using FTIR. The characteristics of synthesized powders were examined with X-ray diffraction(XRD) Brunauer Emmett Teller with N2 absorption. scanning electron microscopy (SEM). and transmission electron microscopy (TEM). Ultrafine NiO/YSZ powders of 15-18 m2/g were obtained through GNP when the content of glycine was controlled to 1 or 2 times the stoichiometric ratio in the precursor solutions. Strongly acid precursor solution increased the specific surface area of the synthesized powders. This is suggested to be the increased binding of metal nitrates and glycine under a strong acid solution of pH=0.5 that lets glycine consist of mainly the amine group of {{{{ { NH}`_{3 } ^{+ } }}. After sintering and reducing treatment of NiO/YSZ powders synthesized by GNP the Ni/YSZ pellet showed ideal microstructure where very fine Ni particles of 3-5 ${\mu}{\textrm}{m}$ were distributed uniformly and fine pore around Ni metal particles was formed. leading to anincrease of the triple phase boundary among gas Ni and YSZ.

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