• Applied Chemistry for Engineering
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• v.20 no.1
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• pp.80-86
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• 2009

In this study, binderless zeolite BaX granule, an effective adsorbent for the separation of p-xylene was made. This adsorbent which has a sufficient strength, high specific surface area and selectivity to p-xylene was prepared by various steps, such as granulation process, calcination, binderless treatment, ion-exchange, and activation. In the granulation, the concentration of colloidal silica solution was controlled in order to confirm the effect of $SiO_2$ contents after binderless treatment. As a result, we confirmed that the compressive strength of granule after binderless treatment was increasing with increasing proportion of $SiO_2$ in the granule. And then Na-ion in granule was exchanged with Ba-ion by successive batch ion-exchange process. And then prepared adsorbents were tested for p-xylene separation by batch adsorption at $90^{\circ}C$. As a results of batch adsortion test, we confirmed that prepared adsorbents have a high selectivity to p-xylene. Also, it could be conformed that the prepared binderless zeolite BaX has a sufficient compressive strength (0.450 kgf), high specific surface area $(647.57m^2/g)$, high crystallinity (98.5% compared with zeolite NaX powder), and selectivity to p-xylene.

• Journal of Powder Materials
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• v.10 no.3
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• pp.176-180
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• 2003

Pure WC powders which does not include a binder phase were consolidated by spark plasma sintering (SPS) process at 1600~185$0^{\circ}C$ for 0~30 min under 50 MPa. Microstructure alid mechanical properties of binderless WC prepared by SPS were investigated. With increasing sintering temperature, sintered density and Vickers hardness of binderless WC increased. The fracture toughness of binderless WC was 7~15 MPa $m^{1/2}$ depending on the sintered density and decreased with increasing the Vickers hardness. It is found that the binderless WC prepared by SPS at 175$0^{\circ}C$ for 10 min under 50 MPa showed nearly full densification with fine-grained structure and revealed excellent mechanical properties of high hardness (~HV 2400) and considerably high fracture toughness (~7 MPa $m^{1/2}$).

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2001.11a
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• pp.21-21
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• 2001

• Applied Chemistry for Engineering
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• v.21 no.4
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• pp.417-423
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• 2010

In this study, an effective method to prepare granular binderless ZSM-5 which is as efficient p-xylene separatory adsorbent was explored. Colloidal silica sol 30 wt% solution as an inorganic binder and microcrystalline cellulose as an organic additive were added to ZSM-5 powder ($SiO_2/Al_2O_3$ = 50). Adsorbent with enough strength (0.721 kgf), high crystallinity (94.6%) and high BET specific surface area ($379.2m^2$/g) was obtained by calcination, binderless treatment, ${NH_4}^+$ ion exchange, and activation after spherical granulation process. A batch type adsorption experiment was proceeded with solutions comprising 3 xylene isomers by 1 : 1 : 1 weight ratio to evaluate adsorption characteristics of prepared absorbent. As a result, the obtained binderless ZSM-5 granule showed a higher selective adsorption performance for para-xylene than that of commercial adsorbent.

• Korean Journal of Materials Research
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• v.31 no.7
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• pp.392-396
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• 2021

Expensive PCBN or ceramic cutting tools are used for processing of difficult-to-cut materials such as Ti and Ni alloy materials. These tools have the problem of breaking easily due to their high hardness but low fracture toughness. To solve these problems, cutting tools that form various coating layers are used in low-cost WC-Co hard material tools, and research on various tool materials is being conducted. In this study, binderless-WC, WC-6 wt%Co, WC-6 wt%Co-1 wt% Mo₂C, and WC-6 wt%Co-2.5 wt% Mo₂C hard materials are densified using horizontal ball milled WC-Co, WC-Co-Mo₂C powders, and spark plasma sintering process (SPS process). Each SPSed Binderless-WC, WC-6 wt%Co-1 wt% Mo₂C, and WC-6 wt%Co-2.5 wt% Mo₂C hard materials are almost completely dense, with relative density of up to 99.5 % after the simultaneous application of pressure of 60 MPa and almost no significant change in grain size. The average grain sizes of WC for Binderless-WC, WC-6 wt%Co-1 wt% Mo₂C, and WC-6 wt%Co-2.5 wt% Mo₂C hard materials are about 0.37, 0.6, 0.54, and 0.43 ㎛, respectively. Mechanical properties, microstructure, and phase analysis of SPSed Binderless-WC, WC-6 wt%Co-1 wt% Mo₂C, and WC-6 wt%Co-2.5 wt% Mo₂C hard materials are investigated.

• Journal of Powder Materials
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• v.14 no.5
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• pp.315-319
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• 2007

Pure WC or WC with low Co concentration less than 0.5 wt.% is studied to fabricate high density WC/Co cemented carbide using vacuum sintering and post HIP process. Considering the high melting point of WC, it is difficult to consolidate it without the use of Co as binder. In this study, the effect of lower Co addition on the microstructure and mechanical properties evolution of WC/CO was investigated. By HIP process after vacuum sintering, hardness and density was sharply increased. The hardness values was $2,800kgf/mm^2$ using binderless WC.

• Journal of Korea Foundry Society
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• v.29 no.5
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• pp.192-197
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• 2009

The manufacturing and application characteristics of binderless briquette for in-mold melt treatment of ductile cast iron were investigated. The porosity of briquette was decreased with increased magnesium content. The dissolution rate was increased with the latter in the range of 5~10%. The fluxing effect was the best when 5%$CaF_2$ was added. The optimum composition of the binderless briquette was obtained.

• Journal of the Korean Wood Science and Technology
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• v.48 no.1
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• pp.22-31
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• 2020

In this study, rice straw and bagasse are used as raw materials to produce binderless particleboard (BPB). This study aims to evaluate the mechanical and physical properties of BPB. We identify the raw material that would be better for the production of BPB from the viewpoint of their basic properties. The BPBs are made from rice straw, bagasse, and combinations of both in ratios of 50:50 and 40:60, respectively. The modulus of elasticity (MOE), modulus of rupture (MOR), internal bonding (IB) strength, water absorption, and thickness swelling properties of the different BPBs are determined and compared. Results showed that all the properties are significantly influenced by the type of particles or particle combinations in the BPB. BPBs made from bagasse alone have the highest MOR, MOE, and IB mean values, whereas BPBs made from rice straw alone exhibit the lowest MOR, MOE, and IB values. Meanwhile, BPBs made from a combination of rice straw and bagasse at 40:60 ratio by weight have the second highest values for properties such as MOR, MOE, and IB, followed by BPBs made from a combination of rice straw and bagasse at 50:50 ratio by weight.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2006.09a
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• pp.355-356
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• 2006

WC-TiC-TaC binderless cemented carbide was oxidized under low partial pressure of oxygen (50ppm) at 873K for 1 to 20 h. Surface roughness was measured using atomic force microscope, and effect of TiC amount on oxidation behavior of the carbide was investigated. WC phase was oxidized more easily than WC-TiC-TaC solid solution phase. With an increase in TiC amount, WC-TiC-TaC phase increased and the oxidation resistance of the carbide increased.

• Korean Chemical Engineering Research
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• v.53 no.2
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• pp.231-235
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• 2015

The characteristics of binderless briquettes for dried low-rank coal was studied in this work. Two kinds of Indonesian coals were used to briquette after drying them in electric oven. The characteristics of briquettes have been examined by moisture contents, particle size, hydraulic force, and storing period. The optimum moisture contents of briquettes were observed at between 10 wt% and 15 wt%. The strength of coal briquette was stronger as particle size became smaller. The strength of coal briquette was proportional to the hydraulic force under 300 kN, whereas there was little difference among the briquettes made at more than 300 kN of hydraulic force. The strength of briquettes sharply decreased for a week after produced, and then showed the tendency of converging. The results from this work can be a useful guideline of manufacturing and managing upgraded coal briquettes.