• Title/Summary/Keyword: bi-layered

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Preparation of dielectric Bi4-xLaxTi3O12 (x~2) from K2La2Ti3O10 via exfoliation and restacking routes (박리화와 재적층법을 통한 K2La2Ti3O10부터 유전성 Bi4-xLaxTi3O12(x~2)의 합성)

  • Jeon, A Young;Ko, Jieun;Kim, Jong-Young
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.23 no.1
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    • pp.14-19
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    • 2013
  • We have successfully synthesized $Bi_{4-x}La_xTi_3O_{12}$ (x~2) having Aurivillius-type layered perovskite structure from exfoliated layered perovskite oxide of $K_2La_2Ti_3O_{10}$ with Ruddlesden-Popper structure. The reaction between the exfoliated lanthanum titanate nanosheets and BiOCl nanocrystal resulted in the formation of polycrystalline $Bi_{4-x}La_xTi_3O_{12}$ (x~2) after heating above $700^{\circ}C$. Colloidal suspension of the nanosheets could be obtained by intercalating ethylamine (EA) into the protonated lanthanum titanate, $H_2La_2Ti_3O_{10}$, derived from $K_2La_2Ti_3O_{10}$. Transmission electron microscopic (TEM) analysis show that the exfoliated lanthanium titanate nanosheets have a thickness of a few nano meters. According to X-ray diffraction (XRD) analysis, the exfoliated lanthanium titanate was found to be transformed into $Bi_{4-x}La_xTi_3O_{12}$ (x~2) after restacking with BiOCl and subsequent thermal treatment at > $700^{\circ}C$.

Structural monitoring of layered FGM distribution ring support: Analysis with and without internal pressure

  • Ghamkhar, Madiha;Harbaoui, Imene;Hussain, Muzamal;Ayed, Hamdi;Khadimallah, Mohamed A.;Alshoaibi, Adil
    • Advances in nano research
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    • v.12 no.3
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    • pp.337-344
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    • 2022
  • In this work, the vibrational frequency of two layered FGM cylindrical shell with and without the effects of internal pressure under ring support are discussed in detailed. The functionally graded materials of a cylindrical shell are designed for specific purpose and studied under various boundary conditions. The Love shell dynamical equations theory is utilized to find the relationship between the curvature displacement and strain displacement. Natural frequency vibrations are analyzed by using volume polynomial for bi-layered FGM shell under ring support both for with and without internal pressures.

Phase Stability and Electronic Properties of $Bi_2BaLnCuO_{6+δ}$ Cuprates with Structure 2201 Type

  • V. E. Fedorov;N. G. Naumov;P. P. Samoilov;N. F. Zakharchuk;N. I. Matskevich;백우현
    • Bulletin of the Korean Chemical Society
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    • v.16 no.6
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    • pp.484-489
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    • 1995
  • The synthesis of new bismuth-barium containing members of layered cuprates with 2201 type structure was reported. By solution calorimetry the formation enthalpies for Bi2MLaCuO6.5 (M=Ba, Ba0.5Sr0.5, Sr) were obtained. Crucial influence of partial oxygen pressure and size of lanthanoid on stability of layered cuprates was shown. Electronic states of variable valence atoms were studied by voltammetry of solids.

Dielectric and Piezoelectric Properties of Nonstoichiometric Sr1±xBi2±yTa2O9 and Sr1±xBi2±yNb2O9 Ceramics (비화학양론 Sr1±xBi2±yTa2O9 과 Sr1±xBi2±yNb2O9 세라믹의 유전 및 압전 특성)

  • Cho, J.A.;Park, S.E.;Song, T.K.;Kim, M.H.;Lee, H.S.
    • Korean Journal of Materials Research
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    • v.13 no.6
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    • pp.360-364
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    • 2003
  • $Sr_{l}$ $\pm$x/$Bi_{2}$ $\pm$y/$Ta_2$ $O_{9}$ and $Sr_{l}$ $\pm$$Bi_{x}$ $2\pm$y$Nb_2$$O_{9}$ ceramics were prepared by a solid state reaction method. X-ray diffraction analysis indicated that single-phase of Bi-layered perovskite was obtained. According to Sr/Bi content ratio, Curie temperature( $T_{c}$), electromechanical factor($K_{p}$ ) and mechanical quality factor($Q_{m}$ ) were measured. The Curie temperature of SBN(SBT) rose from $414^{\circ}C$(314$^{\circ}C$) to $494^{\circ}C$(426$^{\circ}C$) when Sr/Bi content ratio was increased. In the case of Sr/Bi content ratio = 0.55/2.3, the maximum value of the mechanical quality factor $Q_{m}$ of SBT and SBN were obtained 3320 and 1010, respectively.

Effect of Ti Buffer Layer Thickness on the Electrical and Optical Properties of In2O3/Ti bi-layered Films (Ti 완충층 두께에 따른 In2O3/Ti 적층박막의 전기적, 광학적 특성 변화)

  • Moon, Hyun-Joo;Jeon, Jae-Hyun;Gong, Tae-Kyung;Kim, Daeil
    • Journal of the Korean Society for Heat Treatment
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    • v.28 no.6
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    • pp.296-299
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    • 2015
  • $In_2O_3/Ti$ bi-layered films were deposited on glass substrate at room temperature with radio frequency (RF) and direct current (DC) magnetron sputtering to consider the effect of Ti buffer layer on the electrical and optical properties. In a comparison of figure of merit, $In_2O_3$ 90 nm/Ti 10 nm thin films show the higher opto-electrical performance of $3.0{\times}10^{-4}{\Omega}^{-1}$ than that of the $In_2O_3$ single layer films ($2.6{\times}10^{-4}{\Omega}^{-1}$). From the observed results, it is supposed that the $In_2O_3\;90nm/TiO_2$ 10 nm bi-layered films may be an alternative candidate for transparent electrode in a transparent thin film transistor device.

Torsional wave dispersion in a bi-layered hollow cylinder with inhomogeneous initial stresses caused by internal and external radial pressures

  • Akbarov, Surkay D.;Bagirov, Emin T.
    • Structural Engineering and Mechanics
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    • v.77 no.5
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    • pp.571-586
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    • 2021
  • The present paper studies the influence of the inhomogeneous initial stresses in the bi-layered hollow cylinder and it is assumed that these stresses are caused by the hydrostatic pressures acting on the interior and outer free surfaces of the cylinder. The study is made by utilizing the version of the three-dimensional linearized theory of elastic waves in bodies with initial stresses for which the initial stress-strain state in bodies is determined within the scope of the classical linear theory of elasticity. For the solution to the corresponding eigenvalue problem, the discrete-analytical method is employed. Numerical results are presented and analyzed for concrete selected pairs of materials. According to these results and their analyses, it is established that, unlike homogeneous initial stresses, the influence of the inhomogeneous initial stresses on the torsional wave dispersion has not only quantitative but also qualitative character. For instance, in particular, it is established that as a result of the initial stresses caused by the hydrostatic pressure acting in the interior free surface of the cylinder, the cut-off frequency appears for the fundamental dispersive mode and the values of this frequency increase with the intensity of this pressure.

Thermoelectric properties of multi-layered Bi-Te/In-Se/Bi-Te thin film deposited by RF magnetron sputter

  • Kim, Hyo-Jung;Kim, Kwang-Chon;Choi, Won-Chel;Jung, Kyoo-Ho;Kim, Hyun-Jae;Park, Chan;Kim, Jin-Sang
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.231-231
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    • 2010
  • Thermoelectric properties of a multi-layered thin film, which was composed with indium selenide and bismuth telluride, were investigated. The structure of the layered thin film is Bi-Te /In-Se/Bi-Te and it was prepared on sapphire substrate by RF magnetron sputter using stoichiometric $Bi_2Te_3$ (99.9%) and $In_2Se_3$(99.99%) target at room temperature. Then, it was annealed at temperature range of 150 - $500^{\circ}C$ in Ar ambient. Structural characterizations were done using X-ray diffraction(XRD, BRUKER, D8, 60kW) and transmission electron microscopy (TEM, FEI, Tecnai, F30 S-Twin), respectively. Cross-section of multi-layer structure was observed by Scanning electron microscopy (SEM). The resistivity and Seebeck coefficient of these samples were also measured by conventional equipment at room temperature. The maximum value of power factor was $1.16\;{\mu}W/k^2m$ at annealing temperature of $400^{\circ}C$.

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Fabrication of simple bi-layered structure red and green PHOLEDs

  • Jeon, Woo-Sik;Park, Tae-Jin;Kwon, Jang-Hyuk;Pode, Ramchandra;Ahn, Jeung-Sun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.34-36
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    • 2008
  • Highly efficient red and green phosphorescent devices comprising a simple bilayer structure are reported. The driving voltage to reach $1000\;cd/m^2$ is 4.5 V in $Bebq_2:\;Ir(piq)_3$ red phosphorescent device. Current and power efficiency values of 9.66 cd/A and 6.90 lm/W in this bi-layered simple structure PHOLEDs are obtained, respectively. While in $Bepp_2:Ir(ppy)_3$ green phosphorescent device, the operating voltage value of 3.3V and current and power efficiencies of 37.89 cd/A and 35.02 lm/W to obtain a luminance of $1000\;cd/m^2$ are noticed, respectively.

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