• 제목/요약/키워드: beta-C$_2$S

검색결과 1,572건 처리시간 0.031초

$\beta$-$Si_3$$N_4$종자입자 첨가 SiC-$Si_3$$N_4$복합재료의 기계적 특성 (Mechanical Properties of SiC-$Si_3$$N_4$Composites Containing $\beta$-$Si_3$$N_4$Seeds)

  • 이영일;김영욱;최헌진;이준근
    • 한국세라믹학회지
    • /
    • 제38권1호
    • /
    • pp.22-27
    • /
    • 2001
  • $\beta$-Si$_3$N$_4$종자입자 첨가가 소결조제로 Y-Mg-Si-Al-O-N계 oxynitride glass를 사용하여 일축가압 소결을 행한 SiC-Si$_3$N$_4$복합재료의 미세구조와 기계적 특성에 미치는 영향을 고찰하였다. 길게 자란 $\beta$-Si$_3$N$_4$입자들과 등방성의 $\beta$-SiC 입자들이 균일하게 분포된 미세구조를 얻었다. $\beta$-Si$_3$N$_4$종자입자 함량이 증가함에 따라 SiC-Si$_3$N$_4$복합재료의 강도와 파괴인성이 증가하였고, 이는 복합화에 기인하는 결함크기의 감소와 길게 자란 $\beta$-Si$_3$N$_4$입자에 의한 균열가교 및 균열회절 등에 기인하였다. SiC-70 wt% Si$_3$N$_4$복합재료의 대표적인 강도와 파괴인성은 각각 770 MPa과 6.2 MPa.m$^{1}$2/ 이었다.

  • PDF

Ex vivo Digestion of Milk from Red Chittagong Cattle Focusing Proteolysis and Lipolysis

  • Islam, Mohammad Ashiqul;Ekeberg, Dag;Rukke, Elling-Olav;Vegarud, Gerd Elisabeth
    • Asian-Australasian Journal of Animal Sciences
    • /
    • 제28권4호
    • /
    • pp.559-567
    • /
    • 2015
  • Ex vivo digestion of proteins and fat in Red Chittagong Cattle milk from Bangladesh was carried out using human gastrointestinal enzymes. This was done to investigate the protein digestion in this bovine breed's milk with an especial focus on the degradation of the allergenic milk proteins; ${\alpha}_{s1}$-casein and ${\beta}$-lactoglobulin and also to record the generation of peptides. Lipolysis of the milk fat and release of fatty acids were also under consideration. After 40 min of gastric digestion, all the ${\alpha}_s$-caseins were digested completely while ${\beta}$-lactoglobulin remained intact. During 120 min of duodenal digestion ${\beta}$-lactoglobulin was reduced, however, still some intact ${\beta}$-lactoglobulin was observed. The highest number of peptides was identified from ${\beta}$-casein and almost all the peptides from ${\kappa}$-casein and ${\beta}$-lactoglobulin were identified from the gastric and duodenal samples, respectively. No lipolysis was observed in the gastric phase of digestion. After 120 min of duodenal digestion, milk fat showed 48% lipolysis. Medium (C10:0 to C16:0) and long (${\geq}C17:0$) chain fatty acids showed 6% to 19% less lipolysis than the short (C6:0 to C8:0) chain fatty acids. Among the unsaturated fatty acids $C18:1{\sum}others$ showed highest lipolysis (81%) which was more than three times of $C18:2{\sum}all$ and all other unsaturated fatty acids showed lipolysis ranging from 32% to 38%. The overall digestion of Bangladeshi Red Cattle milk was more or less similar to the digestion of Nordic bovine milk (Norwegian Red Cattle).

SYNTHESIS OF THE GINSENG GLYCOSIDES AND THEIR ANALOGS

  • Elyakov G. B.;Atopkina L. N.;Uvarova N. I.
    • 고려인삼학회:학술대회논문집
    • /
    • 고려인삼학회 1993년도 학술대회지
    • /
    • pp.74-83
    • /
    • 1993
  • In an attempt toward the synthesis of the difficulty accessible ginseng saponins the four dammarane glycosides identical to the natural $ginsenosides-Rh_2,$ - F2, compound K and chikusetsusaponin - LT8 have been prepared from betulafolienetriol(=dammar-24-ene-$3{\alpha},12{\beta}\;20(S)-triol).\;3-O-{\beta}-D-Glucopyranoside$ of 20(S) - protopanaxadiol $(=ginsenoside-Rh_2)$ have been obtained by the regio - and stereoselective glycosylation of the $12-O-acetyldammar-24-ene-3{\beta},\;12{\beta},$ 20(S)-triol. The 12-ketoderivative of 20(S)-protopanaxadiol has been used as aglycon in synthesis of chikusetsusaponin - LT8. Attempted regio - and stereoselective glycosylation of the less reactive tertiary C - 20 - hydroxyl group in order to synthesize the $20-O-{\beta}-D-glucopyranoside$ of 20(S)-protopanaxadiol(=compound K) using 3, 12 - di - O - acetyldammar - 24 - ene - $3{\beta},12{\beta},20(S)$-trial as aglycon was unsuccessful. Glycosylation of 3, 12 - diketone of betulafolienetriol followed by $NaBH_4$ reduction yielded the $20-O-{\beta}-D-glucopyranoside\;of\;dammar-24-ene-3{\beta},12{\alpha},$ 20(S)-triol, the $12{\alpha}-epimer$ of 20(S) - protopanaxadiol. Moreover, a number of semisynthetic ocotillol - type glucosides, analogs of natural pseudoginsenosides, have been prepared.

  • PDF

Cloning and Molecular Characterization of ${\beta}$-1,3-Glucan Synthase from Sparassis crispa

  • Yang, Yun Hui;Kang, Hyeon-Woo;Ro, Hyeon-Su
    • Mycobiology
    • /
    • 제42권2호
    • /
    • pp.167-173
    • /
    • 2014
  • A ${\beta}$-glucan synthase gene was isolated from the genomic DNA of polypore mushroom Sparassis crispa, which reportedly produces unusually high amount of soluble ${\beta}$-1,3-glucan (${\beta}$-glucan). Sequencing and subsequent open reading frame analysis of the isolated gene revealed that the gene (5,502 bp) consisted of 10 exons separated by nine introns. The predicted mRNA encoded a ${\beta}$-glucan synthase protein, consisting of 1,576 amino acid residues. Comparison of the predicted protein sequence with multiple fungal ${\beta}$-glucan synthases estimated that the isolated gene contained a complete N-terminus but was lacking approximately 70 amino acid residues in the C-terminus. Fungal ${\beta}$-glucan synthases are integral membrane proteins, containing the two catalytic and two transmembrane domains. The lacking C-terminal part of S. crispa ${\beta}$-glucan synthase was estimated to include catalytically insignificant transmembrane ${\alpha}$-helices and loops. Sequence analysis of 101 fungal ${\beta}$-glucan synthases, obtained from public databases, revealed that the ${\beta}$-glucan synthases with various fungal origins were categorized into corresponding fungal groups in the classification system. Interestingly, mushrooms belonging to the class Agaricomycetes were found to contain two distinct types (Type I and II) of ${\beta}$-glucan synthases with the type-specific sequence signatures in the loop regions. S. crispa ${\beta}$-glucan synthase in this study belonged to Type II family, meaning Type I ${\beta}$-glucan synthase is expected to be discovered in S. crispa. The high productivity of soluble ${\beta}$-glucan was not explained but detailed biochemical studies on the catalytic loop domain in the S. crispa ${\beta}$-glucan synthase will provide better explanations.

라드를 이용한 열처리 온도 변화에 따른 ${\beta}-carotene$의 산화 안정성에 대한 연구

  • 원혜경;정상희;황미자;김진희;이지영;박남영;이치호
    • 한국축산식품학회:학술대회논문집
    • /
    • 한국축산식품학회 2005년도 정기총회 및 제35차 춘계 학술 발표대회
    • /
    • pp.358-362
    • /
    • 2005
  • 0%, 0.0012%, 0.004%의 ${\beta}-carotene$을 lard를 첨가한후 $80^{\circ}C$, $130^{\circ}C$, $180^{\circ}C$의 온도처리로 2분간 열처리를 하고 $50^{\circ}C$에서 보관시키면서 각 기간별로 총 균수검사, 과산화물가(Peroxide Value), TBArs를 측정하여 비교하였다. 1) 미생물 총 균수 실험에서 ${\beta}-carotene$의 첨가량이 0%, 0.0012%, 0.004%로 증가함에 따라 균의 증식이 둔화되었다. 2) Peroxide Value의 측정 실험에 ${\beta}-carotene$의 첨가량이 0.004%일 때가 0%, 0.0012%에서 보다 항산화 능력이 더 높은 것으로 나타났다. 3) TBA가 측정실험에서 control과 Sample과의 비교에서 온도가 증가함에 따라 그 증가폭 커지므로 ${\beta}-carotene$의 항산화 능력이 있다는 것을 알 수 있다.

  • PDF

Bacillus subtilis JW-1 균주가 생산하는 bacilysin의 풋마름병 억제 효과 및 특성 (Isolation and characterization of bacilysin against Ralstonia solanacearum from Bacillus subtilis JW-1)

  • 김신덕
    • 미생물학회지
    • /
    • 제54권2호
    • /
    • pp.136-139
    • /
    • 2018
  • 풋마름병 균에 대해 강한 저해활성을 갖는 활성물질 Compound S와 conversion product인 compound S'이 Bacillus subtilis JW-1 배양액에서 일련의 크로마토그래피 방법으로 분리 정제되었고, $^1H$ NMR, $^{13}C$ NMR, $^1H-^1H$ COSY와 HMBC 등의 spectra 분석에 의해 구조가 alanyl-L-${\beta}$-(2,3-epoxycyclohexyl-4-one)alanine와 alanyl-L-${\beta}$-(2,3-dihydroxycyclohexyl-4-one) alanine로 각각 동정되었다. Compound S는 $G^+$, $G^-$ bacteria, yeast와 Candida albicans 등에 대해 광범위한 antimicrobial activity를 나타내며, conversion product의 활성 상실을 통해 intact oxirane ring이 Compound S의 활성에 필수적임이 밝혀졌다.

폐기물의 용융처리에 의한 시멘트 원료의 합성(II) (Synthesis of Cement Raw Materials by Melting of Industiral Wastes(II))

  • 황연;손용운;정헌생;이홍기;박현서
    • 자원리싸이클링
    • /
    • 제6권1호
    • /
    • pp.29-34
    • /
    • 1997
  • 산업 폐기물의 일종인 석회석 슬러지, 폐주물사, 석탄회 및 폐유리병을 고온에서 용융 슬래그화 하여 시멘트 원료로서의 활용 가능성을 검토하고자 하였다. 각 폐기물을 혼합한 후 용융처리하여 얻은 용융 슬래그는 $\beta$-$C_2$S(2CaO.$SiO_2$) 및 $C_2$AS(2CaO.$Al_2$$O_3$.$SiO_2$)의 2가지 상으로 구성되어 있다. 폐기물의 용융처리시 용융온도, 냉각속도 및 염기도 등을 변화시키면서 이들 요인이 $\beta$-$C_2$S상의 생성율에 미치는 영향을 조사하였다. 시멘트 원료로서 활용이 가능한 $\beta$-$C_2$S상의 함율을 높이기 위해서는 첫째 용융온도를 낮추어 용융슬래그의 제조에 필요한 최소한의 온도에서 용융시키고, 둘째 용융물을 고온에서 급냉시키며, 셋째 낮은 염기도를 갖도록 혼합물의 조성을 조절하는 것이 필요하다.

  • PDF

β-Glucosidase를 생성하는 호염성 Roseivivax roseus 균주의 분리 및 분류동정 (Isolation and identification of β-glucosidase producing halophilic Roseivivax roseus)

  • 조건영;한송이
    • 미생물학회지
    • /
    • 제51권2호
    • /
    • pp.141-147
    • /
    • 2015
  • 소금생산을 위해 25% 이상의 함수를 저장해 놓는 염전의 해주로부터 호염성 세균 4균주를 분리하고 높은 염분농도에서도 ${\beta}$-glucosidase를 생성하는 HJS1과 HJS6 균주를 선발하였다. 이들 ${\beta}$-glucosidase 생성세균은 NaCl 1-10%에서 70-79U/mg의 최적 활성을 나타내었고, NaCl 3%에서 최대 활성을 나타내었으며 NaCl 0-20% 농도에서 최대 효소 활성대비 75%이상의 효소활성을 유지하는 내염성 ${\beta}$-glucosidase를 생성하는 것으로 확인되었다. 내염성 ${\beta}$-glucosidase 생성 HJS1과 HJS6 균주의 16S rRNA 유전자 염기서열을 검토한 결과, Roseivivax roseus $BH87090^T$ (FJ897782)와 99.8%의 상동성을 나타내었고 상기 균주들의 염기서열은 NCBI GenBank에 각각 AB971835와 AB971836로 등록하였다. 계통학적으로 근연종인 Roseivivax roseus $BH87090^T$와의 DNA-DNA 상동성을 비교 검토한 결과, 90.1-90.3%를 나타내었다. 이들 균주의 주요 균체지방산은 $C_{16:0}$, $C_{18:1}$ ${\omega}7c$, $C_{19:0}$ cyclo ${\omega}8c$ 그리고 11-methyl $C_{18:1}$ ${\omega}7c$를 함유하고 Quinone종은 Q-10로 근연종 Roseivivax roseus $BH87090^T$ 균주와 동일한 특징을 나타내어 Roseivivax roseus로 동정되었다. 반면, 비교 균주 Roseivivax roseus $BH87090^T$${\beta}$-glucosidase 생성하지 않는 것으로 나타났다. 본 연구에서 분리된 Roseivivax roseus HJS1과 HJS6 균주는 내염성 ${\beta}$-glucosidase 효소 개발을 위한 유전자원으로 활용 가능하리라 사료된다.

Synthesis of Nuclophilic Adducts of Thiols (Ⅵ). Addition of L-Cystein to $\beta,\;\beta$-Diethoxycarbonylstyrene Derivatives

  • kim, Tae-Rin;Cho, Bong-Rae;Choi, Sung-Yong;Choi, Won-Sik
    • Bulletin of the Korean Chemical Society
    • /
    • 제5권6호
    • /
    • pp.215-218
    • /
    • 1984
  • A series of S-(2,2-diethoxycarbonyl-1-phenylethyl)-L-cysteine derivatives (10a-e) were synthesized from the reaction of $\beta$$\beta$-diethoxycarbonylstyrene with L-cysteine in 1:1 aqueous methanol. Thus, S-(2,2-diethoxycarbonyl-1-phenylethyl)-L-cysteine( 10a), S-[2,2-diethoxycarbonyl-1-(3',4'-methylendioxy)ph enylethyl]-L-cysteine (10b), S-[2,2-diethoxycarbonyl-1-(3',4',5'-trimethoxy)phe nylethyl]-L-cyseine (10c), S-[2,2-diethoxycarbonyl-1-(p-hydroxy)phenylethyl] -L-cysteine (10d), S-[2,2-diethoxycarbonyl-1-(p-methoxy)phenylethyl] -L-cysteine (10e) were obtained in moderate to excellent yields. The structure of the adducts was characterized by analytical and spectral data. The effects of pH upon the product yields were also briefly examined.

C/Si 몰 비가 TEOS와 페놀수지를 출발원료 사용하여 합성된 β-SiC 분말의 특성에 미치는 영향 (Effect of the C/Si Molar Ratio on the Characteristics of β-SiC Powders Synthesized from TEOS and Phenol Resin)

  • 염미래;박상환;김영욱
    • 한국세라믹학회지
    • /
    • 제50권1호
    • /
    • pp.31-36
    • /
    • 2013
  • ${\beta}$-SiC powders were synthesized by a carbothermal reduction process using $SiO_2$-C precursors fabricated by a sol-gel process using phenol resin and TEOS as starting materials for carbon and Si sources, respectively. The C/Si molar ratio was selected as an important parameter for synthesizing SiC powders using a sol-gel process, and the effects of the C/Si molar ratio (1.4-3.0) on the particle size, particle size distribution, and yield of the synthesized ${\beta}$-SiC powders were investigated. It was found that (1) the particle size of the synthesized ${\beta}$-SiC powders decreased with an increase in the C/Si molar ratio in the $SiO_2$-C hybrid precursors, (2) the particle size distribution widened with an increase in the C/Si molar ratio, and (3) the yield of the ${\beta}$-SiC powder production increased with an increase in the C/Si molar ratio.