• Title/Summary/Keyword: beryl

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A Study of Bulk Modulus of Beryl Using Water as a Pressure-Transmitting Medium (물을 압력 매개체로 이용한 녹주석의 체적탄성률 연구)

  • Hwang, Gil Chan;Kim, Hyunho;Lee, Yongjae
    • Journal of the Mineralogical Society of Korea
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    • v.30 no.3
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    • pp.83-91
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    • 2017
  • In-situ high-pressure and ex-situ high temperature-pressure experiments of natural beryl ($Be_3Al_2Si_6O_{18}$, P6/mcc) from two different localities (beryl-A and beryl-B) were studied using pure water as pressure transmitting medium. Compared to the previous study using a mixture of methanol:ethanol medium in 4 : 1 by volume, pressure- and temperature-induced chemical and structural changes under water medium are expected to be different. The derived bulk moduli are 111(7) GPa, $K{_0}^{\prime}=73(7)$; 110(9) GPa, $K{_0}^{\prime}=65(8)$ for beryl-A and beryl-B, respectively. We observe densifications in volume compression, which appear to be attributed to the phase transitions of water to ICE VI and ICE VII around 1.0 GPa and 2.5 GPa, respectively.

Breeding of Vivid Pink Standard Carnation 'Pink Beryl' with Round Petals for Cut Flower (둥근 꽃잎에 화색이 선명한 분홍색 스탠다드 카네이션 'Pink Beryl' 육성)

  • Joung, Hyang Young;Lee, Young Ran;Choi, Seong Roul;Kim, Hyoung Deug;Kim, Tae Il
    • FLOWER RESEARCH JOURNAL
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    • v.17 no.3
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    • pp.194-196
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    • 2009
  • A new standard carnation Dianthus caryophyllus 'Pink Beryl' was bred from a cross of red standard cultivar 'Francesco' and purple standard cultivar 'Saturn' in 1996 at the National Institute of Horticultural & Herbal Science. After investigation of the characteristics for 4 years from 1997 to 2000 and registered to the official breeding variety of Rural Development Administration in 2000. 'Pink Beryl' is pink standard cultivar with round edge of petal for cut flower. It has medium resistance to Fusarium wilt. To avoid calyx splitting caused by high temperature, this cultivar is recommended to grow over $8^{\circ}C$ at night and under $25^{\circ}C$ at days during flower bud differentiation period.

Natural Beryl as a Thermoluminescent Dosimeter

  • Moon, P.S.
    • Nuclear Engineering and Technology
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    • v.6 no.3
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    • pp.151-154
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    • 1974
  • The possibility of using natural beryl thermoluminesence for gamma-ray dose measurement was investigated through the analysis of glow curves obtained with Co-60 gamma-ray irrediation. The natural beryl powder of 80-200 mesh has a good gamma-ray thermoluminescent response and stability at room temperature. The thermoluminescent response is linear from 10mR to 10$^3$R and can be measured up to 10$^{6}$ R.

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Optimal Annealing of Natural Beryl for Thermoluminescent Dosimetry

  • Moon, Philip S.
    • Nuclear Engineering and Technology
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    • v.6 no.1
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    • pp.3-8
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    • 1974
  • The annealing of natural beryl powder used for the thermoluminescent dosimetry was investigated in order to eliminate effect of previous exposure. Through the glow curve analysis, the optimal annealing treatment was found to be one hour annealing at 145$0^{\circ}C$, but annealing for one hour at 55$0^{\circ}C$ was sufficient for reuse of natural beryl powder. There are two distinguished glow peaks at $65^{\circ}C$ and 20$0^{\circ}C$ of heating temperature during readout process. The $65^{\circ}C$ glow peak fades away rapidly, but the 20$0^{\circ}C$ glow peak remains very stable. It is, therefore, quite feasible to use the 20$0^{\circ}C$ glow peak for thermoluminescent dosimetry.

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Single crystal growth of syntheric emerald by reflux method of temperatute gradient using natural beryl (천연베릴을 이용한 온도구배 환류법에 의한 합성 Emerald 단결정 육성)

  • 최의석;김무경;안영필;서청교;안찬준;이종민
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.4
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    • pp.532-538
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    • 1998
  • Emerald ($3BeO{\cdot}Al_2O_3{\cdot}6SiO_2:Cr^{3+}$) single crystal was grown by temperature gradient reflux method with using Korean natural beryl. The flux of lithium-molibudenium-vanadium oxide system was made by means of mixing the 2 sort of flux which were differently melted $Mo_3-Li_2O$ and $V_2O_5-Li_2O$ each other. The optimum composition of flux was 3 mole ratio of molibudenium. vanadium oxides to lithium oxide ($(MoO_3+V_2O_5)/Li_2O$), flux additives were substituted more less then 0.2 mole% of $K_2O$ or $Na_2O$ to the $Li_2O$ amount. The melting concentration of mixing beryl material was 3~10% content to the flux, that of $Cr_2O_3$ color dopant was 1% to the beryl amount. In the crystal growing apparatus with temperature gradient in the 3 zone furnace which was separated into the block of melt, growth and return, the solution have got to circulate continuously between $1100^{\circ}C$ and $1000^{\circ}C$ in steady state. When thermal fluctuation was treated to during 2 hrs once on a day at 950~$1000^{\circ}C$ in growth zone, the supersaturation solution was maintained, controled and emerald single crystal can be grown large crystal which was prevented from the nucleation of microcrystallite. The preferencial growth direction of hexagonal columnar emerald single crystal was the c(0001) plane of botton side and vertical to the m(1010) plane of post side.

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Single Crystal Growth of Synthetic Emerald by Reflux Method of Temperature Gradient used Natural Beryl (천연베릴을 이용한 온도구배 환류법에 의한 합성 Emerald 단결정 육성)

  • 최의석;김무경;이종민;안영필;서청교;안찬준
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1996.06a
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    • pp.519-521
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    • 1996
  • Emerald (3BeO.Al2O3.6SiO2 : Cr3+) single crystals were crystals were grown by reflux method of temperature gradient in the flux solution of Li2O-MoO3-V2O5 system. The composition of flux materials were 3 mole ratio of MoO3-V2O5/Li2O, subtituted 0.2 mole% of K2O, Na2O, Nb2O5 etc to Li2O content, solved 10-15% of beryl to flux quantity and doped 1% of Cr2O3 to emerald amount. Those of mixing were melted at 110$0^{\circ}C$ in Pt containers of the 3 zone furnace of melt-growth-return to circulate continniously, specially it has been grown large emerald single crystal when thermal fluctuation was treated for 2hrs of once time a day at 1050-95$0^{\circ}C$ in growth zone, substitutional solid solution effect of Cr+3 ion for Al+3 to the growth of emerald single crystal was good. Emerald single crystals were c(0001) hexagonal crystal face of preferencial growth direction and m(1010) post side. When it had been durated for 5 months emerald single crystals of the firet size of 0.6mm thickness of seed crystal were grown 32$\times$65mm(c x m) of maximum size and 6.2mm thickness.

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A Study on the Fluid Inclusions in the Minerals from the Dae Hwa Tungsten-Molybdenum Deposits (대화(大華) 중석휘수연광상산(重石輝水鉛床産) 광물중(鍵物中)의 유체포유물(流體包有物)에 관(關)한 연구(硏究))

  • Park, Hi In;Choi, Suck Won
    • Economic and Environmental Geology
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    • v.7 no.2
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    • pp.63-78
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    • 1974
  • Daehwa tungsten-molybdenum deposits is fissure filled quartz veins occurring in Precambrian granite gneiss adjacent to the contact with Mesozoic biotite granite mass. Essential ore minerals are molybdenum and wolframite accompaning scheelite, cassiterite, chalcopyrite, pyrrhotite, pyrite and bismuthinites. Gangue minerals are quartz and little muscovte, fluorite, beryl and Carbonate minerals. Fluid inclusions in quartz, fluorite, beryl, scheelite and calcite have filling temperature ranges of $170-353^{\circ}C$. According to the studies of mineral paragenesis and filling temperature of fluid inclusion indicate that main tungsten and molybdnum mineralization have taken place with the minerals whose filling temperature ranges 205 to $353^{\circ}C$. Liquid $CO_2$ bearing fluid inclusions are characteristic in the quartz and early fluorite of tungsten and tungsten bearing molybdenum veins but hardly recognized from molybdemun veins. Estimated $CO_2$ concentration according to diagram proposed by the Takenouchi ranges from 10 to 20wt%. These facts suggest that tungsten mineralization may be related to the $CO_2$ content of the hydrothermal solution during the mineralizing period.

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Fluid Inclusion Studies on the Wolak Tungsten-Molybdenum Deposits, Korea (월악 중석-몰리브덴 광상의 유체포유물 연구)

  • Lee, In Sung;Park, Hee-In
    • Economic and Environmental Geology
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    • v.15 no.1
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    • pp.17-32
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    • 1982
  • The Wolak tungsten-molybdenum deposits are tungsten-molybdenum bearing quartz veins which filled the fractures in Pre-Cambrian pebble-bearing calcareous hornfels, hornfels and Cretaceous granite. There are two vein groups in this mine, Dongsan vein group in the west and Kwangcheon vein group in the east. The ore minerals are wolframite, scheelite, molybdenite, native bismuth, bismuthinite, pyrite, arsenopyrite, chalcopyrite, cubanite, stannite, pyrrhotite, sphalerite, galena, marcasite, Pb-Bi sulfosalt and ilmenite. Quartz, calcite, beryl, fluorite, muscovite, rhodochrosite and siderite are gangue minerals. Fluid inclusion studies were carried out for the quartz, beryl, scheelite, early and late fluorite. Fluid inclusion studies reveal that liquid-gas inclusions are most common and occur in all of the minerals examined. Filling degree of the inclusions in the late fluorite is much higher than that of the inclusions in quartz and early fluorite. Liquid $CO_2$ bearing liquid-gas inclusions occur in quartz and early fluorite. Liquid, gas and solid phase inclusions occur in quartz, beryl and scheelite. Salinities of inclusions in quartz and beryl from Dongsan vein group range from 3.9 to 8.0, from 5.3 to 7.7 wt.% NaCl equivalent respectively. Salinities in the late fluorite range from 1.5 to 3.2 wt.% NaCl equivalent. In Kwangcheon vein group salinities range from 3.9 to 9.6 wt.% NaCl equivalent in quartz, from 2.8 to 7.3 wt.% NaCl equivalent in early fluorite, from 1.3 to 1.5 wt.% NaCl equivalent in late fluorite. Homogenization temperatures of inclusions range from $239^{\circ}$ to higher than $360^{\circ}C$ in quartz, over $360^{\circ}C$ in scheelite, from $288^{\circ}C$ to higher than $360^{\circ}C$ in beryl, and from $159^{\circ}$ to $202^{\circ}C$ in late fluorite of the Dongsan vein group. In Kwangcheon vein group, homo genization temperatures of inclusions range from $240^{\circ}C$ to higher than $360^{\circ}C$ in quartz and from $240^{\circ}$ to $328^{\circ}C$ in early fluorite. As a whole, in Dongsan and Kwangcheon vein groups it seems that there are no distinct differences in mineralogy, salinities and homogenization temperatures. No distinct variations in homogenization temperatures are revealed through about 300 m vertically in both district. The faint trend of increase in salinities in the lower level can be detected. The salinity, $CO_2$ content and the temperature of ore fluid were much higher in the early vein stage and then dropped off in the late stage of mineralization as represented by the quartz and fluorite inclusion data.

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K - Ar Ages of Mineral Deposits in the Gyeonggi Massif (한반도중부지역(韓半島中部地域)의 광상생성기(鑛床生成期)와 생성구(生成區) -경기육괴내(京畿陸塊內)의 광상생성연령(鑛床生成年齡)-)

  • Park, Hee-In;Chang, Ho Wan;Jin, Myung Shik
    • Economic and Environmental Geology
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    • v.21 no.4
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    • pp.349-358
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    • 1988
  • K-Ar ages were determined on gangue and wall rock alteration minerals from twenty metallic mineral deposits in the Gyeonggi Massif. Beryl deposits give the age of 185 Ma, whereas tungsten - molybdenum deposits reveal two different age groups such as 172~156 Ma and 91~86Ma. Lead - zinc deposits and gold - silver deposits yield the ages of 160 Ma and 71~197 Ma, respectively. Mineralization ages for each genetic type of deposits in the Gyeonggi Massif can be summarized as follows; pegmatite deposits, 185 Ma; skarn deposits, 156~160 Ma; hydrothermal deposits, 71~197 Ma. Present results together with data previously reported reveal that rare earths, tungsten-molybdenum, base and precious metal deposits in the Gyeonggi Massif were formed in Jurassic and Cretaceous time with a genetic relationship to the Daebo and Bulguksa felsic igneous activity.

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Modeling and characterization of beryllium reflector elements under irradiation conditions

  • Ahmed H. Elhefnawy;Mohamed A. Gaheen;Hanaa H. Abou Gabal;Mohamed E. Nagy
    • Nuclear Engineering and Technology
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    • v.55 no.12
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    • pp.4583-4590
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    • 2023
  • This study aims at modeling the beryllium reflector poisoning under neutron irradiation conditions and calculating the impact of beryllium poisoning on the core parameters of ETRR-2 research reactor. The CITVAP code was used to calculate the neutron flux and parameters of ETRR-2 core with beryllium reflector elements. The neutron flux in each reflector element was calculated to solve the modeling equations for the atomic densities of lithium-6 (6Li), tritium-3 (3H), and helium-3 (3He) using the BERYL program. The results are discussed based on CITVAP calculations of the core excess reactivity and cycle length Full Power Days (FPD). Possible solutions to minimize the degradation due to beryllium poisoning are also discussed and compared based on calculations.