• Title/Summary/Keyword: benzotriazole

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The Influence of the BTA on Electrical Properties of Synthetic Fluids (합성절연유의 전기적 특성에 미치는 BTA의 영향)

  • Shin, Jong-Yeol;Shin, Hyun-Teak;Hong, Jin-Woong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.2
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    • pp.162-166
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    • 1998
  • Synthetic fluid, class 7 group 2, as an insulating and cooling material is selected as. specimen, arid it is studied for the physical and electrical properties. Also, Benzotriazole(following as BT A) known as a suppressant of streaming electrification is added to it, and the change of physical and electrical properties by addition of BT A is investigated. From the spectrum of FT-IR, it is confirmed that the absorption peak in wavenumbers $3400{\sim}3450[cm^{-1}]$ is small or disappears when BTA is added. AC breakdown strength and volume resistivity of each specimen are investigated. It is considered that the effective content of BTA is about 10[ppm] for the suppression of electrification in this experiment.

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The Electrical Conduction Characteristics of Transformer Oils added the Anti-static Agent for Streaming Electrification (유동대전 억제제가 첨가된 변압기유의 전기전도 특성)

  • Lee, Yong-Woo;Lee, Tae-Hoon;Oh, Se-Young;Lee, Jong-Pil;Cha, Kwang-Hoon;Hong, Jin-Woong
    • Proceedings of the KIEE Conference
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    • 1997.07d
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    • pp.1213-1215
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    • 1997
  • In order to investigate the electrical characteristics due to the BTA(Benzotriazole) additive in the transformer, the electrical characteristics of the transformer oils contained benzotriazole as an anti-static agent for streaming electrification is studied by measuring the electric conduction. As a result of the electrical conduction characteristics, it is confirmed that the conduction current of virgin specimen is more higher than that of specimen contained the BT A 10[ppm] over 35[$^{\circ}C$], but that of specimen contained the BT A 10[ppm] over 50[$^{\circ}C$] is increased.

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Synthesis and Biological Activities of Novel Arylazopyrazolones Substituted with Thiazolyhydrazone

  • Shah, Purvesh J.
    • Journal of the Korean Chemical Society
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    • v.58 no.1
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    • pp.57-61
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    • 2014
  • The 4-(1H)-benzotriazoyl methyl amino benzoate 3 was prepared by Mannich reaction of benzotriazole 1, ethyl-paminobenzoate 2 and formaldehyde. The prepared compound 3 then react with hydrazine hydrate results in the 4-(1H)-benzotriazoyl methyl amino benzoyl hydrazide 4. This compound on condensation with pre-prepared different ethyl 2-(2-(4-(4-substituted phenyl)thiazol-2-yl)hydrazono)-3-oxobutanoates 6a-d, furnished 1-(4-((1H-benzo[d] [1,2,3] triazol-1-yl)methyl amino) benzoyl)-4-(2-(4-(4-substituted phenyl)thiazol-2-yl) hydrazono)-3-methyl-1H-pyrazol-5(4H)-one 7a-d. All the compounds 7a-d was characterized by spectral studies. The compounds showed significant antimicrobial activity against various bacteria and fungi.

Influence of Temperature and Benzotriazole on the Flow Electrification by aging Mineral, Vegetable Oil (열화된 광유와 식물성절연유에서 온도, 벤조트리아졸의 유동대전 영향)

  • Choi, Sun-Ho;Jeong, Jung-Il;Huh, Chang-Su
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.60 no.2
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    • pp.338-343
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    • 2011
  • In this paper, the FT-IR, conductivity and flow electrification phenomena of Vegetable oils were discussed. Vegetable oil has high flash point and eco-friendly properties compared to conventional mineral oil. Accelerated aging transformer oil samples produced in the oven at 140[$^{\circ}C$] for 500 hours, 1000 hours, 1500 hours, 2000 hours. Serial device to measure the flow electrification phenomena was designed and fabricated. Pico ammeter and the Labview data measurements were utilized. The effects of Temperature and antistatic agent on fluid flow electrification were investigated. Both Mineral and vegetable oil showed similar trends for temperature change. The polarity reversal occurred in mineral oil with antistatic agent above 10 ~ 30[ppm] and in vegetable oil with antistatic agent above 5[ppm].

A Study on the Polymer Nanocomposite for Corrosion Protection (내식 방지용 고분자 나노복합재료에 관한 연구)

  • Lyu, Sung Gyu;Park, Se Hyeong;Park, Chan Sup;Cha, Jong Hyun;Sur, Gil Soo
    • Applied Chemistry for Engineering
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    • v.16 no.2
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    • pp.212-216
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    • 2005
  • Benzotriazole which is used as a corrosion inhibitor for the zinc coated steel was intercalated into Na-MMT. X-ray diffraction experiments on intercalant/silicate composite samples demonstrated that the intercalation of intercalant leads to an increase in the spacing between silicate layers. Water soluble poly(ethylene-co-acrylic acid) (PEA) nanocomposites, to use as a coating agent, were prepared with these modified MMT. We found that mono-layered silicates were dispersed in PEA matrix and those resultants were exfoliated nanocomposites. From the result of salt spray test, we found that this coating agent prepared with water soluble poly(ethylene-co-acrylic acid) (PEA) nanocomposite provided good corrosion protection. These results were caused by decreasing the rate of oxygen permeation from silicate layers dispersed homogeneously in PEA matrix and the effect of corrosion inhibitor from benzotriazole.

Mechanical Analysis on Uniformity in Copper Chemical Mechanical Planarization (Cu CMP에서의 연마 균일성에 관한 기계적 해석)

  • Lee, Hyun-Seop;Park, Boum-Young;Jeong, Hae-Do;Kim, Hyoung-Jae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.1
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    • pp.74-79
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    • 2007
  • Most studies on copper Chemical Mechanical Planarization (CMP) have focused on material removal and its mechanisms. Although many studies have been conducted on the mechanism of Cu CMP, a study on uniformity in Cu CMP is still unknown. Since the aim of CMP is global and local planarization, the approach to various factors related to uniformity in Cu CMP is essential to elucidate the Cu CMP mechanism as well. The main purpose of the experiment reported here was to investigate and mechanically analyze the roles of slurry components in the formation of the uniformity in Cu CMP. In this paper, Cu CMP was performed using citric acid($C_{6}H_{8}O_{7}$), hydrogen peroxide($H_{2}O_{2}$), colloidal silica, and benzotriazole($BTA,\;C_{6}H_{4}N_{3}H$) as a complexing agent, an oxidizer, an abrasive, and a corrosion inhibitor, respectively. All the results of this study showed that within-wafer non-uniformity(WIWNU) of Cu CMP could be controlled by the contents of slurry components.

Effect of Corrosion inhibitor, Benzotriazole (BTA), on Particle Adhesion in Cu CMP (Cu CMP중 BTA에 의한 Particle의 흡착에 관한 연구)

  • Song, Jae-Hoon;Hong, Yi-Koan;Kim, Tae-Gon;Park, Jin-Goo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.366-367
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    • 2005
  • The effect of benzotriazole (BTA) on the adhesion force of silica and pad particle on Cu/TEOS wafer surfaces was investigated with and without the addition of BTA. Cu-BTA had the isoelectric point (IEP) at around pH 4$\sim$8. Pad particles were more positive zeta potentials than silica. The adhesion force initially decreased of silica and pad particle on Cu surfaces when BTA was added. However, the more BTA was added, the more adhesion force gradually increased with the increase of BTA concentrations. Then the adhesion force of pad particle was higher than silica. And TEOS didn't resulted increasing adhesion force like Cu when BTA was added in DI water.

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Inhibition of Pitting Corrosion Failure of Copper Tubes in Wet Sprinkler Systems (스프링클러 구리배관의 공식 파손 억제)

  • Suh, Sang Hee;Suh, Youngjoon;Lee, Jonghyuk;Kwon, HyukSang
    • Corrosion Science and Technology
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    • v.19 no.2
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    • pp.89-99
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    • 2020
  • The inhibition of pitting corrosion failure of copper sprinkler tubes in wet sprinkler systems was studied. First, an apparatus and technology for removing air in the sprinkler tubes by vacuum pumping and then filling the tubes with water were developed. Using this apparatus and technology, three methods for inhibiting the pitting corrosion of the copper sprinkler tubes installed in several apartment complexes were tested. The first one was filling the sprinkler tubes with water bubbled by high-pressure nitrogen gas to reduce the dissolved oxygen concentration to lower than 2 ppm. In the second method, the dissolved oxygen concentration of water was further reduced to lower than 0.01 ppm by sodium sulfite. In the third method, the sprinkler tubes were filled with benzotriazole (BTAH) dissolved in water. The third method was the most effective, reducing the failure frequency of the sprinkler tubes due to pitting corrosion by more than 80%. X-ray photoelectron spectroscopy analyses confirmed that a Cu-BTA layer was well coated on the inside surface of the corrosion pit, protecting it from corrosion. A potentiodynamic polarization test showed that BTAH should be very effective in reducing the corrosion rate of copper in the acidic environment of the corrosion pit.