• Title/Summary/Keyword: bentonite

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A Correlation to Predict the Thermal Conductivity of Buffer and Backfill Material for a High-Level Waste Repository (고준위폐기물처분장 완충재 및 뒷채움재의 열전도도 예측을 위한 관계식)

  • Cho, Won-Jin;Lee, Jae-Owan;Kwon, Sang-Ki
    • Tunnel and Underground Space
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    • v.20 no.4
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    • pp.284-291
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    • 2010
  • In the present design concept of a high-level waste repository, the bentonite and bentonite-sand mixture are considered as the buffer and backfill material. For the Kyungju bentonite which is a candidate material, the thermal conductivities of compacted bentonite and bentonite-sand mixture were measured. A correlation has been proposed to predict the thermal conductivity of the Kyungju bentonite and the bentonite-sand mixture as a function of the dry density, the water content and the sand fraction. The proposed correlation can predict the thermal conductivity with a difference less than 10% under the experimental conditions.

An Experimental Study on the Pozzolan Reaction of discarded Bentonite by the Cooling Method after Heat Treatment (소성가공한 폐 벤토나이트 분말의 냉각방법에 따른 포졸란 반응성에 관한 실험적 연구)

  • Kim, Hyo-Yeul;Kang, Byeung-Hee
    • Journal of the Korea Institute of Building Construction
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    • v.2 no.3
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    • pp.139-146
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    • 2002
  • As the bentonite is main material to prevent from collapse of drilling hole at underground excavation works, it is increased using quantity on construction industry day by day. But, the discarded bentonite that is over using at underground excavation works is caused various environmental trouble as soil and water pollution est. This study aims to propose a foundamental report for pozzolan reaction of discarded Bentonite powder by heat-treatment and cooling as concrete mineral admixture. To find out pozzolan reaction ability of discarded Bentonite powder by indirect cooling & cooling using of water after heat-treatment, the experiments are excuted Phenolphtalein test, setting test, pH test and the analysis by X-ray diffractor. As a result of this study, discarded Bentonite powder can be utilized as concrete mineral admixture by heat-treatment and especially, pozzolan reaction ability of discarded Bentonite powder is superior to the situation of 50$0^{\circ}C$~$700^{\circ}C$, 60min.

Effect of Exchangeable Cation on Radionuclide Diffusion In Compacted Bentonite

  • Park, Jong-Won;Park, Hyun-Soo;Dennis W. Oscarson
    • Nuclear Engineering and Technology
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    • v.28 no.3
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    • pp.274-279
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    • 1996
  • Diffusion coefficient is a critical parameter for predicting radiological source term(migration rate and flux of radionuclide) through given near field conditions in spent fuel or high level waste repository. The effect of exchangeable cation-$Na^+$ and $Ca^{2+} - on the diffusion of $I^- \;and^3H$ (as HTO) in compacted bentonite was examined using a through-diffusion method. Bentonite material used here was compacted to a density of 1.3 Mg/m$^3$, and Na-bentonite was saturated with a solution of 100 mol NaCl/m$^3$ and Ca-bentonite with 50 $mol\;CaCl_2$/m$^3$. The results show that effective diffusion coefficients are generally higher by a factor of two to five in Ca-than Na-clay. This is attributed to the larger particle size of Ca-compared to Na-bentonite; hence, Ca-bentonite has a greater proportion of relatively large pores, which make a greater contribution to mass transport than small pores. Although the nature of the exchangeable cation affects mass diffusion in compacted bentonite, the effect is small and not likely to influence performance assessment modeling of compacted bentonite-based barriers.

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Utilization of Mineral Oxides to Attenuate Mn-EDTA and Fluoride (산화광물을 이용한 수중의 망간-EDTA, 불소 제거)

  • 현재혁;남인영
    • Journal of Korea Soil Environment Society
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    • v.1 no.2
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    • pp.51-60
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    • 1996
  • Removal of Mn-EDTA complex and fluoride by use of hematite and ferrite, which are the by-product to be disposed of as industrial wastes, was investigated. For the comparison of removal rate, Na-bentonite known as excellent absorbent of inorganic contaminants was included in the experiments. As the results of batch mode experiments, for manganese, ferrite-A revealed 48∼65% of removal capacity, ferrite-B 46∼57%, hematite 17∼26%, while Na-bentonite showed 10∼23% of removal, depending on the initial concentration. Meanwhile, in case of fluoride : hematite revealed 53 ∼63% of removal : ferrite-A 54∼63 %, while ferrite-B did 20∼38 %. From the results, it can be postulated that the capacity of hematite and ferrite to attenuate inorganic pollutants, especially when they form complex ions, is superior to that of Na-bentonite. Consequently, the mixing of such oxide minerals with Na-bentonite will reinforce the function of Na-bentonite, especially in the undergroud liner aspect.

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Eco-Friendly and Thermal Conductivity Properties of Magnesium oxide Matrix Utilizing Bentonite (벤토나이트를 활용한 산화마그네슘 경화체의 친환경성 및 열저항 특성)

  • Gwon, Oh-Han;Lim, Hyun-Ung;Lee, Dong-Hoon;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2016.10a
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    • pp.64-65
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    • 2016
  • This study that prevent cancer using absorbent to inflow Radon gas in the room existing soil and rock is making board to absorb the Radon gas as a fundamental study. So, we use bentonite as a absorbent. So, we use bentonite as a absorbent. Bentonite is a 'clay mineral' composed to montmorillonite of main component that volcanic ash denatured to a clay mineral. Bentonite has fine microparticle of nano level, abundant mineral 66 of kinds, adsorbability, swelling, a positive ion(heavy metal adsorption reaction) as a bentonite's property. Using magnesia cement for oxide of magnesiuma and magnesium chloride as a main binder, we measure Radon gas absorbent efficiency and thermal conductivity.

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A Study on Stress-Strain Characteristics of Compacted Bentonite for High-Level Radioactive Waste Repository (고준위폐기물 차폐용 압축벤토나이트의 응력-변형률 거동 분석)

  • Kim, Do-Hyun;Jeong, Sang-Seom
    • Proceedings of the Korean Geotechical Society Conference
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    • 2009.03a
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    • pp.792-797
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    • 2009
  • The stress-strain characteristics of compacted bentonite are investigated using experimental triaxial compression test by Hoek-cell. Special attention given to various dry density and water absorption ratio. Based on the test results, it is shown that the stress-strain relationship of compacted bentonite is highly influenced by dry density and water absorption ratio. Also, characteristics of Bentonite is similar to the clay rather than sand. Strength of compressed Bentonite increases with higher dry density. It shows maximum strength value, if in a same condition with dry density and constrain pressure. So we determine that value as the optimistic moisture contents for the maximun strength of compressed Bentonite.

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A Study on Thermal Conductivity Properties of Ground Heat Exchangers for GSHP systems (지열냉난방시스템 수직형 지중열교환기 그라우트의 열적 특성에 관한 연구)

  • Baek, Sung-Kwon;Jeon, Joong-Kyu;An, Hyung-Jun
    • Proceedings of the SAREK Conference
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    • 2007.11a
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    • pp.429-433
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    • 2007
  • Cement mortar and concrete can be used as grouts but problems regarding shrinkage and the discord of coefficients of thermal expansion between grouts and HDPE pipes has to be solved. Thermal conductivities of wet condition two times larger than those of dry condition, except for pure cement mortar. The addition of sand into the cement grouts greatly increases the thermal conductivity. The addition of bentonite into the cement grouts reduces thermal conductivity thus reducing the density. Bentonite grouting must be used only below the groundwater table since bentonite grouts possesses high shrinkage property in dry condition. The addition of sand prevents the shrinkage of bentonite grouts. Bentonite manufactured in Korea can be used since they possess similar thermal conductivities with imported products. The addition of sand into the bentonite grouts greatly increases the thermal conductivity.

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A Compilation and Evaluation of Thermal and Mechanical Properties of Bentonite-based Buffer Materials for a High- level Waste Repository

  • Cho, Won-Jin;Lee, Jae-Owan;Kang, Chul-Hyung
    • Nuclear Engineering and Technology
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    • v.34 no.1
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    • pp.90-103
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    • 2002
  • The thermal and mechanical properties of compacted bentonite and bentonite-sand mixture were collected from the literatures and compiled. The thermal conductivity of bentonite is found to increase almost linearly with increasing dry density and water content of the bentonite. The specific heat can also be expressed as a function of water ontent, and the coefficient of thermal expansion is almost independent on the dry density. The logarithm of unconfined compressive strength and Young’s modulus of elasticity increase linearly with increasing dry density, and in the case of constant dry density, it can be fitted to a second order polynomial of water content. Also the unconfined compressive strength and Young’s modulus of elasticity of the bentonite-sand mixture decreases with increasing sand content. The Poisson’s ratio remains constant at the dry density higher than 1.6 Mg/m$_3$, and the shear strength increases with increasing dry density.

Remediation of PCE-contaminated Groundwater Using Permeable Reactive Barrier System with M0M-Bentonite (MOM-Bentonite 투수성반응벽체를 이용한 PCE로 오염된 지하수의 정화)

  • Chung, Sung-Lae;Lee, Dal-Heui
    • Journal of Soil and Groundwater Environment
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    • v.17 no.4
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    • pp.73-80
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    • 2012
  • The objectives of this research were to study the applicability and limitations of permeable reactive barrier (PRB) for the removal of tetrachloroethylene (PCE) from the groundwater. PRB column tests were conducted using reactive material with Moringa Oleifera Mass - Bentonite (Mom-Bentonite). Most of the PCE in the groundwater was degraded and/or captured (sorpted) in the zone containing activated material (MOM-Bentonite). The removal rate of PCE from the groundwater was 90% and 75% after 30 days and 180 days, respectively. The effect of micro-organisms on the long-term permeability and reactivity of the barrier is not well understood. MOM-Bentonite PRB system in this research has the potential to be developed into an environmentally and economically acceptable technology for the in situ remediation of PCE-contaminated groundwater.

The Purification Characteristics of the Reactive Soil-Bentonite Landfill Liner (혼합반응차수재의 오염정화특성 연구)

  • 장경준;황의석;안기봉;김학문
    • Proceedings of the Korean Geotechical Society Conference
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    • 2003.03a
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    • pp.585-592
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    • 2003
  • The purpose of this paper is to investigate purification characteristic of soil-bentonite landfill liner and to develop of desirable liner system. In this study, column tests for soil-bentonite, reactive soil-bentonite and existing bentomat and reactive bentomat were carried out under the high pressure with water and leachate.

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