• Title/Summary/Keyword: behavior modification

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Surface Treatment of Mg95Zn4.3Y0.7 Alloy Powder Consolidates using Plasma Electrolytic Oxidation (플라즈마 전해산화공정을 이용한 Mg95Zn4.3Y0.7 합금분말 성형체의 표면특성제어)

  • Kim, J.H.;Choi, H.S.;Kim, D.H.;Hwang, D.Y.;Kim, H.S.;Kim, T.S.
    • Journal of Powder Materials
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    • v.15 no.2
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    • pp.95-100
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    • 2008
  • The investigation is to modify the mechanical and chemical properties of Mg alloys using a combination of rapid solidification and surface treatment. As the first approach, $Mg_{95}Zn_{4.3}Y_{0.7}$ was gas atomized and pressure sintered by spark plasma sintering process (SPS), showing much finer microstructure and higher strength than the alloys as cast. Further modification was performed by treating the surface of PM Mg specimen using Plasma electrolytic oxidation (PEO) process. During the PEO processing, MgO layer was initiated to form on the surface of Mg powder compacts, and the thickness and the density of MgO layer were varied with the reaction time. The thickening rate became low with the reaction time due to the limited diffusion rate of Mg ions. The surface morphology, corrosion behavior and wear resistance were also discussed.

Active Materials for Energy Conversion and Storage Applications of ALD

  • Sin, Hyeon-Jeong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.75.2-75.2
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    • 2013
  • Atomic layer deposition (ALD), utilizing self-limiting surface reactions, could offer promising perspectives for future efficient energy conversion devices. The capabilities of ALD for surface/interface modification and construction of novel architectures with sub-nanometer precision and exceptional conformality over high aspect ratio make it more valuable than any other deposition methods in nanoscale science and technology. In the context, a variety of researches on fabrication of active materials for energy conversion applications by ALD are emerging. Among those materials, one-dimensional nanotubular titanium dioxide, providing not only high specific surface area but also efficient carrier transport pathway, is a class of the most intensively explored materials for energy conversion systems, such as photovoltaic cells and photo/electrochemical devices. The monodisperse, stoichiometric, anatase, TiO2 nanotubes with smooth surface morphology and controlled wall thickness were fabricated via low-temperature template-directed ALD followed by subsequent annealing. The ALD-grown, anatase, TiO2 nanotubes in alumina template show unusual crystal growth behavior which allows to form remarkably large grains along axial direction over certain wall thickness. We also fabricated dye-sensitized solar cells (DSCs) introducing our anatase TiO2 nanotubes as photoanodes, and studied the effect of blocking layer, TiO2 thin films formed by ALD, on overall device efficiency. The photon convertsion efficiency ~7% were measured for our TiO2 nanotubebased DSCs with blocking layers, which is ~1% higher than ones without blocking layer. We also performed open circuit voltage decay measurement to estimate recombination rate in our cells, which is 3 times longer than conventional nanoparticulate photoanodes. The high efficiency of our ALD-grown, anatase, TiO2 nanotube-based DSCs may be attributed to both enhanced charge transport property of our TiO2 nanotubes photoanode and the suppression of recombination at the interface between transparent conducting electrode and iodine electrolytes by blocking layer.

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Two Dimensional Numerical Simulation of Bed Change in the Reach near Buyeo Intake Station (부여취수장 부근에서의 하상변동에 대한 2차원 수치모의)

  • Han, Geon-Yeon;Lee, Eul-Rae;Son, Gwang-Ik;Im, Chang-Su
    • Journal of Korea Water Resources Association
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    • v.32 no.6
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    • pp.697-709
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    • 1999
  • Two dimensional finite element model(RMA) is applied to examine sediment transport behavior near Buyeo water intake station of the Keum River. The simulation results of bed change with various discharge conditions agree with those of observation. As the alternatives of channel modification and resulting bed lowering near intake station, construction of jetties and removal of small island are considered. The station of jetties diverted the main stream toward the other side and the width of the main stream did not change so much. The bed elevation of the main channel is reduced about 5~20 cm, when flow condition of 12,030㎥/sec applied. The removal of small island provides the less significant effect on sediment movement. This study shows that the construction of jetties would be effective to reduce the entrainment of sediment.

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The Effects of Physical Activity Programs on Physical Fitness, Blood Lipids, and Growth-Related Factors among Young Normal Weight and Obese Children (유아체육프로그램이 정상체중유아와 비만유아의 체력과 혈중지질 및 성장관련인자에 미치는 영향)

  • Bak, Hyong-Gon;Kim, Gun-Do;Park, Chan-Ho
    • Journal of Life Science
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    • v.22 no.3
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    • pp.380-386
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    • 2012
  • This study was conducted to examine the effects of physical activity programs on young children's body composition, physical fitness, blood lipids, and growth-related factors. Fourteen young male child subjects participated in this study. Experimental groups were divided into a young obese children group (OG; n=7) and a young normal weight children group (NG; n=7). The subjects performed supervised physical activity programs with moderate intensity for 12 weeks, 40 minutes per session, 3 times per week. The results of this study are as follows: HDL-C, growth hormone, and IGF-I were significantly increased in NG, but OG was showed no changes. Physical fitness was significantly increased in both NG and OG. This study demonstrated that physical activity programs have a positive effect on the prevention of obesity, as well as a positive effect on growth and development in young normal weight children. However, long-term follow-up studies are necessary to clarify the additive effect of exercise program with behavior modification in young obese children.

Factors Associated with Attendance in a Nutrition Education Program for Hyperlipidemic Patients

  • Yim, Kyeong-Sook;Kim, Young-Joo;Cho, Young-Yun;Rha, Mi-Yong;Kim, Duk-Kyoung
    • Journal of Community Nutrition
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    • v.3 no.1
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    • pp.21-29
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    • 2001
  • This study was conducted to examine factors with attendance in hyperlipidemia nutrition eduction program among 101 hyperlipidemic outpatients (38 males 63 females) at Samsung Medical Center We employed the Health Belief Model (HBM) as the theoretical framework The individual nutrition education and counseling program was scheduled with 4- half hour session sin 2 to 4 weeks intervals. Upon initiation of the program a trained dietitian surveyed HBM constructs and psychosocial factors. The following were included perceived susceptibility to cardiovascular disease(CVD) perceived severity to CVD percieved benefits to diet modification perceived barriers to persistence in maintaining therapy and self efficicacy and social support from family Sociodemographic data health factors stress level nutrition knowledge, and 24-hour dietary recall behavior were also surveyed All these data was analyzed according to the number of nutrition sessions attended The subjects were 55.9$\pm$9.4 year old and 24.6$\pm$kg/㎡ Sociodemographic factors were not associated with the number of nutrition sessions attended HBM constructs and psychosocial factors were significantly associated with the number of nutrition sessions attended. According to Spearman correlation coefficients. From stepwis regression analyses using HBM constructs as independent variables perceive barriers to persistence in maintaining diet therapy (negative) proved to be the strongest predictors for the number of nutrition sessions attended (partial R$^2$= 72.3%) followed by perceived severity to CVD and self efficacy (model R$^2$=76.6% The findings indicate that HBM constructs and psychosocial factors were closely associated with patient attendance It suggests that information and guidance to minimize patients perceived barriers to diet therapy might help to improve patients to scheduled appointments in nutrition education programs.

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The Role of the Surface Oxide Layer on Ru Nanoparticles in Catalytic Activity of CO Oxidation

  • Kim, Sun-Mi;Qadir, Kamran;Jin, Sook-Young;Jung, Kyeong-Min;Reddy, A. Satyanarayana;Joo, Sang-Hoon;Park, Jeong-Young
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.304-304
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    • 2010
  • The study on the catalytic oxidation of carbon monoxide (CO) to carbon dioxide ($CO_2$) using the noble metals has long been the interest subject and the recent progress in nanoscience provides the opportunity to develop new model systems of catalysts in this field. Of the noble metal catalysts, we selected ruthenium (Ru) as metal catalyst due to its unusual catalytic behavior. The size of colloid Ru NPs was controlled by the concentration of Ru precursor and the final reduction temperatures. For catalytic activity of CO oxidation, it was found that the trend is dependent on the size of Ru NPs. In order to explain this trend, the surface oxide layer surrounding the metal core has been suggested as the catalytically active species through several studies. In this poster, we show the influence of surface oxide on Ru NPs on the catalytic activity of CO oxidation using chemical treatments including oxidation, reduction and UV-Ozone surface treatment. The changes occurring to UV-Ozone surface treatment will be characterized with XPS and SEM. The catalytic activity before and after the chemical modification were measured. We discuss the trend of catalytic activity in light of the formation of core-shell type oxide on nanoparticles surfaces.

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Stabilization of PAN Nanofibers Using Electron Beam Irradiation and Thermal Compression Technique (전자선 조사와 열압축공정을 이용한 PAN 나노섬유의 안정화 및 특성분석)

  • Kim, Du Yeong;Jeun, Joon Pyo;Shin, Hye Kyoung;Kang, Phil Hyun
    • Journal of Radiation Industry
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    • v.6 no.1
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    • pp.55-59
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    • 2012
  • Polyacrylonitrile (PAN)-based carbon fibers have been widely used due to their unique chemical, electrical, and mechanical properties. Electron beam irradiation has been extensively employed as means of altering properties of polymeric materials. Electron beam irradiation can induce chemical reactions in materials without any catalyst. Electron beam irradiation may be useful in accelerating the thermal compression stabilization of PAN nanofibers. To investigate the irradiation effect on PAN fibers, PAN nanofibers were irradiated by electron beam at 1,000~5,000 kGy. Irradiated and non-irradiated PAN nanofibers were heated at 180 and $220^{\circ}C$ without applying pressure for 15 min. Then 1 metric ton has been applied for 5 min. SEM images have been found that the fiber kept its morphological behavior after the hot pressing up to electron beam irradiated 1,000 kGy. DSC thermograms showed that the peak temperatures of the exothermic reactions were found to decrease with increasing electron beam irradiation doses and temperature. FT-IR spectra have been found to decrease $C{\equiv}N$ stretch band with increasing the electron beam irradiation dose. These results indicate that the modification of PAN via reactions such as cyclization is significantly enhanced by electron beam irradiation and thermal compression technique.

Strengthening of the panel zone in steel moment-resisting frames

  • Abedini, Masoud;Raman, Sudharshan N.;Mutalib, Azrul A.;Akhlaghi, Ebrahim
    • Advances in Computational Design
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    • v.4 no.4
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    • pp.327-342
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    • 2019
  • Rehabilitation and retrofitting of structures designed in accordance to standard design codes is an essential practice in structural engineering and design. For steel structures, one of the challenges is to strengthen the panel zone as well as its analysis in moment-resisting frames. In this research, investigations were undertaken to analyze the influence of the panel zone in the response of structural frames through a computational approach using ETABS software. Moment-resisting frames of six stories were studied in supposition of real panel zone, different values of rigid zone factor, different thickness of double plates, and both double plates and rigid zone factor together. The frames were analyzed, designed and validated in accordance to Iranian steel building code. The results of drift values for six stories building models were plotted. After verifying and comparing the results, the findings showed that the rigidity lead to reduction in drifts of frames and also as a result, lower rigidity will be used for high rise building and higher rigidity will be used for low rise building. In frames with story drifts more than the permitted rate, where the frames are considered as the weaker panel zone area, the story drifts can be limited by strengthening the panel zone with double plates. It should be noted that higher thickness of double plates and higher rigidity of panel zone will result in enhancement of the non-linear deformation rates in beam elements. The resulting deformations of the panel zone due to this modification can have significant influence on the elastic and inelastic behavior of the frames.

Experimental and analytical investigation of composite columns made of high strength steel and high strength concrete

  • Lai, Binglin;Liew, J.Y. Richard;Xiong, Mingxiang
    • Steel and Composite Structures
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    • v.33 no.1
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    • pp.67-79
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    • 2019
  • Composite columns made of high strength materials have been used in high-rise construction owing to its excellent structural performance resulting in smaller cross-sectional sizes. However, due to the limited understanding of its structural response, current design codes do not allow the use of high strength materials beyond a certain strength limit. This paper reports additional test data, analytical and numerical studies leading to a new design method to predict the ultimate resistance of composite columns made of high strength steel and high strength concrete. Based on previous study on high strength concrete filled steel tubular members and ongoing work on high strength concrete encased steel columns, this paper provides new findings and presents the feasibility of using high strength steel and high strength concrete for general double symmetric composite columns. A nonlinear finite element model has been developed to capture the composite beam-column behavior. The Eurocode 4 approach of designing composite columns is examined by comparing the test data with results obtained from code's predictions and finite element analysis, from which the validities of the concrete confinement effect and plastic design method are discussed. Eurocode 4 method is found to overestimate the resistance of concrete encased composite columns when ultra-high strength steel is used. Finally, a strain compatibility method is proposed as a modification of existing Eurocode 4 method to give reasonable prediction of the ultimate strength of concrete encased beam-columns with steel strength up to 900 MPa and concrete strength up to 100 MPa.

POWER UPRATES IN NUCLEAR POWER PLANTS: INTERNATIONAL EXPERIENCES AND APPROACHES FOR IMPLEMENTATION

  • Kang, Ki-Sig
    • Nuclear Engineering and Technology
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    • v.40 no.4
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    • pp.255-268
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    • 2008
  • The greater demand for electricity and the available capacity within safety margins in some operating NPPs are prompting nuclear utilities to request license modification to enable operation at a higher power level, beyond their original license provisions. Such plant modifications require an in-depth safety analysis to evaluate the possible safety impact. The analysis must consider the thermo hydraulic, radiological and structural aspects, and the plant behavior, while taking into account the capability of the structures, systems and components, and the reactor protection and safeguard systems set points. The purpose of this paper is to introduce international experiences and approaches for implementation of power uprates related to the reactor thermal power of nuclear power plants. The paper is intended to give the reader a general overview of the major processes, work products, issues, challenges, events, and experiences in the power uprates program. The process of increasing the licensed power level of a nuclear power plants is called a power uprate. One way of increasing the thermal output from a reactor is to increase the amount of fissile material in use. It is also possible to increase the core power by increasing the performance of the high power bundles. Safety margins can be maintained by either using fuels with a higher performance, or through the use of improved methods of analysis to demonstrate that the required margins are retained even at the higher power levels. The paper will review all types of power uprates, from small to large, and across various reactor types, including light and heavy water, pressurized, and boiling water reactors. Generally, however, the content of the report focuses on power uprates of the stretch and extended type. The International Atomic Energy Agency (IAEA) is developing a technical guideline on power uprates and side effects of power uprates in nuclear power plants.