• Title/Summary/Keyword: bead radius

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Characteristics of Electrospun Poly(methyl methacrylate) Nanofibers Embedding Multi-Walled Carbon Nanotubes(MWNTs) (다중벽 탄소 나노튜브가 분산된 Poly(methyl methacrylate) 고분자 용액의 전기방사연구)

  • Kim Dong Ouk;Lee Dai-Hoi;Yoon Seong-sik;Lee Sun-Ae;Nam Jae Do
    • Polymer(Korea)
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    • v.30 no.1
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    • pp.90-94
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    • 2006
  • An electrospinning process was used to fabricate poly(methyl methacrylate) (PMMA) nanofibers embedding multi-walled carbon nanotubes(MWNTs). SEM images showed that the nanofiber surface and structural morphology depended on solvent types (dimethyl formamide, chlor-form and toluene) and carbon nanotube contents (0.5 and $3.0\;wt\%$). Nano-fiber alignments could be controlled by adjusting the electrodes configuration at collector sites. Relationship between carbon nanotube and PMMA nanofiber was studied with radius of gyration of polymer chain and carbon nanotube sizes. As the carbon nanotube content ratio increased, the number of bead increased.

A Shape Control of Welded Joints to Improve Fatigue Strength (피로강도 향상을 위한 용접이음부의 형상제어에 관한 연구)

  • Kang, Chang Ib;Kook, Seung Kyu;Lee, Dong Uk
    • Journal of Korean Society of Steel Construction
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    • v.16 no.4 s.71
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    • pp.479-492
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    • 2004
  • When U-ribs of steel deck plates are connected at the field, overhead welding should be done with backing strips. Misalignments may occur and lead to eccentric moments as well as high stress concentrations at welded joints. In this study, stress analyses and fatigue tests were carried out. Stress analyses for U-ribs' welded joints with backing strips were performed with different misalignments, root shapes, root gaps, and backing strip sizes. From the stress analyses, the stress concentration factors increased with increasing misalignments and root gaps. With the fixed misalignments and root gaps, the stress concentration factors obtained in the case of the semi-circle root shape were lower than those in the case of the right-angle root shape. It was verified that backing strip sizes have little influence on stress concentration factors. The fatigue tests for U-ribs' welded joints with backing strips indicated that increased misalignments shorten fatigue life drastically and cracks usually initiate at the root of the base metal and are propagated to the weld bead surface. Based on the results of the stress analyses, root-shape control methods were developed to mitigate stress concentration by changing welding condition control, radius curvature, and flank angle.

Crosslinking Density Control and Its Carbonization Characteristics of Spherical Phenolic Resin Particles by Using Cresol as Comonomer (구형 페놀수지 입자의 크레졸을 이용한 가교조절 및 탄화물성 변화)

  • Hahn, Dongseok;Kim, Hongkyeong
    • Korean Chemical Engineering Research
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    • v.58 no.4
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    • pp.618-623
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    • 2020
  • Spherical phenolic resin beads were synthesized by suspension polymerization at 98 ℃ from phenol, ortho-cresol, formaldehyde, with triethylamine as a basic catalyst, and spherical phenol-cresol copolymer resin beads with relatively low crosslinking density as well. Phenol reacts with formaldehyde at two ortho- and one para- positions to form a crosslinked structure, but ortho-cresol instead of phenol reduces the crosslinking density during copolymerization due to the methyl group at a ortho- position. As a result, spherical phenol-cresol copolymer beads showed more shrinkage with decreasing apparent density compared to the spherical phenol beads when carbonized at 700 ℃ under nitrogen. As the molecular weight of the cresol oligomer increases, the pore radius of the carbonized copolymer beads decreases, which is consistent with the density and shrinkage results. It was confirmed that the characteristics such as density decrease, shrinkage, yield and so on during carbonization can be controlled by controlling the degree of crosslinking of the spherical phenolic resin particles with cresol.

Assessing the Refractive Index of Glass Beads for Use in Road-marking Applications via Retroreflectance Measurement

  • Shin, Sang Yeol;Lee, Ji In;Chung, Woon Jin;Cho, Sung-Hoon;Choi, Yong Gyu
    • Current Optics and Photonics
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    • v.3 no.5
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    • pp.415-422
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    • 2019
  • Retroreflection of vehicle headlights, as induced by spherical glass beads, is a key optical phenomenon that provides road-surface markings with greatly enhanced visibility, thus better securing a driver's safety in the nighttime as well as in unclear daytime. Retroreflectance of glass beads is a quite sensitive function of their refractive index, so that measurement of the refractive index of glass specifically in the shape of spherical beads needs to be performed within a reasonable uncertainty that is tolerable for road-marking applications. The Becke line method has been applied in assessing refractive index of such glass beads as e.g. an industrial standard in the Republic of Korea; however, the reference refractive-index liquids are not commercially available these days for refractive index greater than 1.80 due to the toxicity of the constituent materials. As such, high-refractive-index glass beads require an alternate method, and in this regard we propose a practically serviceable technique with uncertainty tantamount to that of the Becke line method: Based on comparison of calculated and measured retroreflectance values of commercial glass beads, we discover that their refractive index can be determined with reasonable precision via the retroreflectance measurement. Specifically, in this study the normalized retroreflectance originating from a single glass sphere is computed as a function of refractive index using the Fresnel equations, which is then validated as coinciding well with retroreflectance values measured from actual specimens, i.e. glass-bead aggregates. The uncertainties involved are delineated in connection with radius and imperfections of the glass beads.

문경지역에 분포하는 변성 염기성암과 변성 퇴적암에 대한 백악기 화강암의 열변성작용

  • 오창환;김성원;김종섭
    • The Journal of the Petrological Society of Korea
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    • v.2 no.2
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    • pp.74-94
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    • 1993
  • Metabasites and metapelites in the Mungyong area were intruded by Cretaceous granites with radius of 4-8 km. As the distance from granite body increases, the mineral assemblage of metabasite changes from amphibole + plagioclase through amphibole + plagioclase + epidote to amphibole + plagioclase + epidote + chlorite. The compositional variations of amphibole and plagioclase according to the change of metamorphic grade and bulk rock compositions are very complex. Towards the Mungyong Cretaceous granite body, the mineral assemblage of metapelite changes from chlorite+ muscovite(ch1orite zone) through biotite + chlorite + muscovite(biotite zone) to andalusite+biotite + muscovite${\pm}$chlorite or cordierite+ biotite+ muscovite${\pm}$chlorite(cordierite zone). The estimated metamorphic conditions of cordierite zone are 480~$580^{\circ}C$ 1.5-3.3 kb. The theoretical study on the thermal metamorphism caused by the Cretaceous granite with radius longer than 4 km in the Mungyong area suggests the followings: The degree of metamorphism is mainly determined not by the size of granite body but by the temperature of granite intrusion; The country rocks within 2 km from Cretaceous granite have undergone metamorphism with temperature higher than $500^{\circ}C$, which is consistent with the petrological study in the Mungyong area. Mungyong Cretaceous granite caused a low P/T thermal metamorphism to the country rocks; the amphibolite facies metamorphism to the country rocks within 1-2 km from the granite body and the epidote-amphibolite and greenschist facies metamorphism to the country rocks within 2-5 km.

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