• Title/Summary/Keyword: base resistance

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A Study on the Effect of Different Functional Groups in Anion Exchange Membranes for Vanadium Redox Flow Batteries (바나듐 산화환원 흐름전지를 위한 음이온교환막의 관능기에 따른 특성 연구)

  • Lee, Jae-Myeong;Lee, Mi-Soon;Nahm, Ki-Seok;Jeon, Jae-Deok;Yoon, Young-Gi;Choi, Young-Woo
    • Membrane Journal
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    • v.27 no.5
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    • pp.415-424
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    • 2017
  • Commonly cation exchange membranes have been used for vanadium redox flow batteries. However, a severe vanadium ion cross-over causes low energy efficiency. Thus in this study, we prepared 3 different anion exchange membranes to investigate the effect on the membrane properties such as vanadium ion cross-over and long term stability. The base membranes were prepared by an electrolyte pore filling technique using vinyl benzyl chloride (VBC), divinylbenzene (DVB) within a porous polyethylene (PE) substrate. Then 3 different functional amines were introduced into the base membranes, respectively. These resulting membranes were evaluated by physico-chemical properties such as ion exchange capacity, dimensional stability, vanadium ion cross-over and membrane area resistance. Conclusively, TEA-functionalized membrane showed longest term stability than other membranes although all the membranes are similar to coulombic efficiency.

Study on the Proper Emulsified-Asphalt Content for a Cold-Recycling Asphalt Mixture (상온 재활용 아스팔트 혼합물의 적정 유화아스팔트 함량 선정 연구)

  • Yang, Sung Lin;Son, Jung Tan;Lee, Kang Hun
    • International Journal of Highway Engineering
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    • v.20 no.1
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    • pp.47-58
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    • 2018
  • PURPOSES : The purpose of this study is to evaluate the mechanical properties of a cold-recycling asphalt mixture used as a base layer and to determine the optimum emulsified-asphalt content for ensuring the mixture's performance. METHODS : The physical properties (storage stability, mixability, and workability) of three types of asphalt emulsion (CMS-1h, CSS-1h, and CSS-1hp) were evaluated using the rotational viscosity test. Asphalt emulsion residues, prepared according to the ASTM D 7497-09 standard, were evaluated for their rheological properties, including the $G*/sin{\delta}$and the dynamic shear modulus (${\mid}G*{\mid}$). In addition, the Marshall stability, indirect tensile strength, and tensile-strength ratio (TSR) were evaluated for the cold-recycling asphalt mixtures fabricated according to the type and contents of the emulsified asphalt. RESULTS : The CSS-1hp was found to be superior to the other two types in terms of storage stability, mixability, and workability, and its $G*/sin{\delta}$ value at high temperatures was higher than that of the other two types. From the dynamic shear modulus test, the CSS-1hp was also found to be superior to the other two types, with respect to low-temperature cracking and rutting resistance. The mixture test indicated that the indirect tensile strength and TSR increased with the increasing emulsified-asphalt content. However, the mixtures with one-percent emulsified-asphalt content did not meet the national specification in terms of the aggregate coverage (over 50%) and the indirect tensile strength (more than 0.4 MPa). CONCLUSIONS : The emulsified-asphalt performance varied greatly, depending on the type of base material and modifying additives; therefore, it is considered that this will have a great effect on the performance of the cold-recycling asphalt pavement. As the emulsified-asphalt content increased, the strength change was significant. Therefore, it is desirable to apply the strength properties as a factor for determining the optimum emulsified-asphalt content in the mix design. The 1% emulsified-asphalt content did not satisfy the strength and aggregate coverage criteria suggested by national standards. Therefore, the minimum emulsified-asphalt content should be specified to secure the performance.

High temperature oxidation behavior and surface modification of Ni-based superalloys (니켈기 초합금의 고온산화거동과 표면개질에 관한 연구)

  • Seol, Gyeong-Won
    • Korean Journal of Materials Research
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    • v.4 no.2
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    • pp.166-176
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    • 1994
  • Ni base superalloys are composed of solid sohltion hardening elements(Co, Cr. Mo. W and so on) and $\gamma '$ precipitation hardening elements(A1, Ti, Nb, Ta and so on). To Improve the mechanical properties and oxidation resistanre of superalloys, rare earth elements(%r, Hf, Y and so on) are added to the inner substrate, or are used as coating materials. Their pffects on the growth rate and adhes~on of oxide are changed according to the kinds of oxides such as $AI_2O_3$ and $Cr_2O_3$. The effect of yttrium on the oxidation rate, grain size of oxide, internal structure, and crack resistance was investigated for two kinds of Ni-base superalloys. One in AF'115 superalloy containing Hf and the other is MA6000 superalloy containing $Y_2O_3$. They werr owid~zed at high temperature after yttrium surface modification using ion coater. Yttrium coating on the AF115 and MA6000 superalloys results in a marked change in the growth of the inner oxide. For AF115 superalloy, the degree of gram boundary segregation of $Cr_2O_3$, and prefer en^ tial oxidation of Hf are decreased, and the shape of inner oxidation layer was changed from triangle to plate type. For MA6000 superalloy, $Cr_2O_3$ oxide scale was transformed as outer oxidation layer of CrZOI and inner oxidation layer of $Cr_2O_3$.

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Transformation of Plant Cells by Gene Transfer : Construction of a Chimeric Gene Containing Deleted Maize Alcohol Dehydrogenase Intron and ${\beta}-Glucuronidase$ Gene and Its Expression in Potato (유전자 도입에 의한 식물세포의 형질전환 : 옥수수 알코올 탈수소효소 유전자의 절단된 인트론 및 ${\beta}-Glucuronidase$ 유전자를 함유하는 키메라 유전자의 제조와 감자에서의 발현)

  • 이광웅
    • Journal of Plant Biology
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    • v.35 no.3
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    • pp.237-245
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    • 1992
  • To understand the properties of the cauliflower mosaic virus (CaMV) 35S promoter and the effect of the deleted maize alcohol dehydrogenase I-S (Adhl-S) intron 1 on the expression of the CaMV $35S{\beta}-glucuronidase$ (GUS) gene in potato (Solanum tuberosum L. cv. Superior), we constructed a chimeric gene and transferred it into potato with Agrobacterium tumefaciens mediated method. The pLS201, a gene transfer vector of 17.7 kilobase pairs, was composed of the CaMV 35S promoter, the 249 base pairs of deleted maize Adhl-S intron 1, the GUS reporter gene, and the kanamycin resistance gene as a selectable marker for transformation. The GUS activity was examined by histochemical and spectrophotometric assay in transformed potato plants. The GUS activity was found primarily around the vascular tissue cells in stem and root. In the spectorophotometric assay, the level of GUS activity of transgenic potato transformed with CaMV 35S/249 bp of intron 1 fragment-GUS (pLS201) was compared with that of potato transformed with CaMV 35S-GUS (pBI121). The quantitative spectrophotometric assay showed that the level of GUS activity in potato transformed with pLS201 was higher in leaf, stem and root by 30-, 34- and 42-fold, respectively than those in potato transformed with pBI121. This results indicate that the inclusion of the deleted maize Adhl-S intron 1 resulted in increament of the GUS gene expression in transgenic potato.potato.

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A Study on Predominant Periods and Attenuation Characteristics of Ground Motion (지반 탁월주기와 지반 운동특성에 관한 연구)

  • Kim, So-Gu;Cha, Jeong-Sik;Jeong, Hyeong-Sik
    • Geotechnical Engineering
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    • v.11 no.2
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    • pp.139-156
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    • 1995
  • A set of field investigations was performed to estimate accurately the predominant periods of seismic 8round motions and the attenuation characteristics of the seismic ground vibration. Predominant periods of ground motions were estimated from the measurement of the continuous microseismic vibratins of certain periods, inherent in the ground and in the buildings, utilizing the high sensitivity digital velocity seismometer consisting of 3-component geophones and a digital seismograph. Estimated predominant periods of microseismic vibraion of the ground(measured on'the ground surface) and the building (measured on the second floor) were in the range of 0.18~0.235 sec. and 0.26~0.31 sec. respectively. The subsurface structure of the site ground was surveyed by the seismic refraction method utilizing the digital seismicwave probing system. The ground structure was found to be a two-layered system : an upper top soil layer of 7m in thickness with the P-wave velocity of 662m1sec and a lower layer of silty-clayey soils with the P -wave velocity of 2210m1 sec. The attenuation characteristics of the seismic ground vibrations were determined by the amplitude decay measurement method us;ng the Seisgun, which produces strong artificial seismic energy. Measured spatial attenuation coefficients of the ground vibration in vertical(Z) longitudinal(X), transverse(Y) direction were 0.1137, 0.0025, and 0.0290 respectively. Estimated Spartial QP's (inverse of the specific dissipation constant w.r.t. shear waved of X, Y, and Z directions were in the range of 5.913~7.575, 32.371~41.452, 2.794~3.579 re spectively. This indicates that aseimic design of the structures on the site should take stronger consideration regarding the earthquake resistance characteristics of the structures against longitudinal ground motion.

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Experimental Assessment of Reduction in the Negative Skin Friction Using a Pile with a Member Responding to Ground Deformation (지반 변형 대응 부재를 적용한 말뚝의 부마찰력 저감 성능의 실험적 검증)

  • Shin, Sehee;Lee, Haklin;Woo, Sang Inn
    • Journal of the Korean Geotechnical Society
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    • v.38 no.3
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    • pp.5-16
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    • 2022
  • Ground in extremely cold and hot regions can sink by various environmental factors. Ground settlement can generate the negative skin friction to pile shaft, increase the base load of pile, and cut the stability of the pile. This study proposed a member responding ground deformation which can be inserted inside the pile. The member slightly compresses according to the ground settlement to reduce the negative skin friction. As the member materials, this study considered spring and spring-dashpot. To assess the ability of the member, the present research performed model tests for piles with or without the member within settled ground. In the model tests, the base load, total shaft resistance, and horizontal earth pressure were monitored and analyzed. Experimental results show that the pile with spring member can reduce the negative skin friction under small settlement conditions whereas it acts similar to the pile without the member under large settlement conditions as the spring was no longer compressed. However, the pile with the spring-dashpot member can reduce the negative skin friction continuously upon the ground settlement as the dashpot delays the load transfer to the spring and locates friction force on the unloading path.

A Suggestion of Mix, Construction Method and Quality Control Criteria of Fine-size Exposed Aggregate PCC Pavement by Experimental Construction (시험시공을 통한 소입경 골재노출 콘크리트 포장의 배합, 시공 및 품질관리 기준 제안)

  • Lee, Seung-Woo;Kim, Young-Kyu;Choi, Don-Hwa;Shim, Jae-Won;Yoo, Tae-Seok
    • International Journal of Highway Engineering
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    • v.13 no.3
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    • pp.51-63
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    • 2011
  • Surface of fine-size exposed aggregate portland cement concrete pavements(FS-EAPCC) is consist by exposed coarse aggregate to remove upper 2~3mm mortar of concrete slabs. Advantages of FS-EAPCC are maintaining low-noise and adequate skid-resistance level during the performance period. However, FS-EAPCC is required rational management criteria for field application, since it is early stage for application. Design construction and quality control criteria of FS-EAPCC was temporary laboratory tests which including optimum mix and exposing method, selection of adequate aggregate, resistance against, environmental loading and etc. However, these criteria need to be validated base on field application. In this study, experimental constructions were performed and construction procedure and quality control criteria were suggested based on the performance of the FS-EAPCC.

Fundamentals of Contact Lens Movement (콘택트렌즈 운동의 기초)

  • Kim, Dae Soo
    • Journal of Korean Ophthalmic Optics Society
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    • v.13 no.1
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    • pp.5-13
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    • 2008
  • Purpose: This review article was written to investigate what kind of forces are acting on the contact lens fitted on the cornea and its subsequent motion. Methods: A capillary action-induced force develops in the tear layer between the lens and cornea, which leads to the restoring force due to difference in layer thickness according to lens rotation. The characteristics of the lens movement can be determined by the various factors such as friction between eyelid and lens, acceleration force based on blinking and the restoring force incorporated with the viscous damping force. A mathematical model which consists of the differential equations and their numerical solution was proposed to analyze the damped motion of lenses. The model predicts the time dependence of lenses during and after the blink varying the BC, blink period and eyelid pressure. Results: It was found that both the blink period and lid pressure increases the movement increases because of the enhanced lid friction. As the BC increases the viscous damping reduces due to the lacrimal layer's increase which resulted in the enhanced lens motion. After blink the lens illustrates the damped oscillation because of the restoring force by the increased lacrimal layer thickness and reduced viscous resistance. The time for the lens to return to the equilibrium shortens as the BC increase because of the resistance reduction. Conclusions: The movement of the contact lens is governed by the characteristics of the lacrimal layer between the lens and cornea as well as the lid blink.

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A Study on the Correlation between Standard Penetration Resistance Value and Static Cone Penetration Resistance Value of the Soft Ground Subsurface of Yongdong Area (표준관입저항치와 정적콘관입저항치의 상관성에 관한 연구 - 영동지역의 연약지반을 중심으로 -)

  • Kim, Jinam;Park, Heunggyu
    • Journal of the Korean GEO-environmental Society
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    • v.7 no.5
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    • pp.13-20
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    • 2006
  • We have conducted standard penetration tests and static cone penetration tests that are widely used the land base examination on the soft ground subsurface of Yongdong area, and examined the correlation between them. We have also made a comparative analysis of the correlation between the indoor tests on the materials collected on the site and on-the-spot penetration tests. The results are as follows : The relationship between Standard Penetration Test N-value and Dutch Cone Tset show $Q_c=1.93N+0.29$ for organic soil, $Q_c=2.19N+0.20$ for clay, $Q_c=2.34N+1.06$ for silt, $Q_c=3.02N+0.54$ for silty sand, and $Q_c=3.47N+0.46$ for sand. In this case of sand $Q_c/N$ increases when the soil particles are larger. The relationship between standard penetration test N-value and Unconfined Compression Strength $q_u$ show $q_u=0.11N+0.03$ for organic soil, $q_u=0.11N+0.25$ for clay, and $q_u=0.18N-0.03$ for silt.

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Analysis Method for Damage Patterns of Low Voltage Switches for PL Judgment (PL 판정을 위한 저압용 스위치의 소손 패턴 해석기법)

  • Choi, Chung-Seog
    • Fire Science and Engineering
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    • v.24 no.5
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    • pp.136-141
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    • 2010
  • The purpose of this study is to examine the structure and heat generation mechanism of low voltage switches used to turn on or off the power supply to an indoor lighting system and investigate how the fixtures and movable contacts of the switches are damaged depending on the types of energy sources in order to secure the judgment base for expected PL disputes. Based on the Korean Standard (KS) testing method for incombustibility, this study applied a general flame to the switch. In addition, current was supplied to the switch using the PCITS (Primary Current Injection Test System). The ambient temperature and humidity were maintained at $22{\pm}2^{\circ}C$ and 40~60% respectively while performing the test. It is thought that the switch generated heat due to a defective connection of the wire and clip, insulation deterioration and defective contact of the movable contact, etc. The surface of the switch damaged by the general flame was uniformly carbonized. When the flame source was removed, the fire on the switch was extinguished naturally. From the result obtained by disassembling the switch carbonized by the general flame, it could be seen that fixtures and movable contacts remained in comparatively good shape but the enclosure, clip support, movable contact, indicating lamp, etc. showed carbonization and discoloration. In the case of the switch damaged by overcurrent, the clip connecting the wires, clip support, etc. showed almost no trace of damage, but the fixtures, movable contact, indicating lamp, etc. were severely carbonized. That is, the sections with high contact resistance were intensively damaged and showed a damage pattern indicating that carbonization progressed from the inside to the outside. Therefore, it is possible to judge the initial energy source by analyzing the characteristics of the carbonization pattern and the metal fixtures of damaged switches.