• Title/Summary/Keyword: band composition

Search Result 376, Processing Time 0.029 seconds

Dielectric and Optical Properties of Amorphous Hafnium Indium Zinc Oxide Thin Films on Glass Substrates

  • Shin, Hye-Chung;Seo, Soon-Joo;Denny, Yus Rama;Lee, Kang-Il;Lee, Sun-Young;Oh, Suhk-Kun;Kang, Hee-Jae;Heo, Sung;Chung, Jae-Gwan;Lee, Jae-Cheol
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2011.08a
    • /
    • pp.225-225
    • /
    • 2011
  • The dielectric and optical properties of GaInZnO (GIZO), HfInZnO (HIZO) and InZnO (IZO) thin films on glass by RF magnetron sputtering method were investiged using reflection electron energy loss spectroscopy (REELS). The band gap was estimated from the onset values of REELS spectra. The band gaps of GIZO, HIZO and IZO thin films are 3.1 eV, 3.5 eV and 3.0 eV, respectively, Hf and Ga incorporated into IZO results in an increase in the energy band gap of IZO by 0.5 eV and 0.1 eV. The dielectric functions were determined by comparing the effective cross section determined from experimental REELS with a rigorous model calculation based on the dielectric response theory, using available software package, good agreement between the experimental and fitting results gives confidence in the accuracy of the determined dielectric function. The main peak of Energy Loss Function (ELF) obtained from IZO shows at 18.42 eV, which shifted to 19.43 eV and 18.15 eV for GIZO and HIZO respectively, because indicates the corporation of cation Ga and Hf in the composition. The optical properties represented by the dielectric function e, the refractive index n, the extinction coefficient k, and the transmission coefficient, T of HIZO and IZO thin films were determined from a quantitative analysis of REELS. The transmission coefficient was increased to 93% and decreased to 87% in the visible region with the incorporation of Hf and Ga in the IZO compound.

  • PDF

Structural Modification of Alkali Tellurite Binary Glass System and Its Characterization

  • Lee, Kyu-Ho;Kim, Tae-Ho;Kim, Young-Seok;Jung, Young-Joon;Na, Young-Hoon;Ryu, Bong-Ki
    • Korean Journal of Materials Research
    • /
    • v.18 no.5
    • /
    • pp.235-240
    • /
    • 2008
  • This paper presents results and observations obtained from a study of the optical and thermal properties of alkali tellurite depending on the composition. Fourier transform infrared (FT-IR) spectra showed evidence of chemical modification from $TeO_4$ trigonal bipyramids (tbp) to $TeO_3$ trigonal pyramids (tp) in tellurite glasses. The optical band gaps of the different glass samples calculated using Tauc's method were found to range from 3.5-3.8 eV. The glass transition temperature (Tg) and glass stability (${\Delta}T$) of alkali tellurite glasses were investigated, as $M_2O$ [M: Li, Na, K] amounted to 25 mol%, through the use of differential thermal analysis (DTA). The coefficient of thermal expansion (CTE) was measured in a thermo mechanical analysis (TMA) with a slow heating rate after the glass samples were annealed. The results confirm that the optical band gap of alkali tellurite glasses depends on the Te-O-Te structural relaxation related to the ratio of bridging/non bridging oxygen (BO/NBO). In contrast, the thermal properties are related to the ionic field strength of the Te-O-M and M-O-M bonds, and the Te-O-Te breakage depends on the ratio of BO/NBO.

스퍼터링 법으로 증착한 CdS 박막의 광전도도 특성 평가

  • Heo, Seong-Gi;Jang, Dong-Mi;Choe, Myeong-Sin;An, Jun-Gu;Seong, Nak-Jin;Yun, Sun-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2008.06a
    • /
    • pp.81-81
    • /
    • 2008
  • Applications of CdS films in this study are to exhibit a high conductivity when they are exposed at light with visible wavelength and sequentially to show a low conductivity in dark state. For this purpose, CdS films should have a high photosensitivity, still maintaining a high conductivity at a visible light. In this study, CdS films were prepared at room temperature on glass substrates by rf magnetron sputtering. In order to increase the photo-conductivity in visible light, various defect levels should be located within the CdS band gap. In order to nucleate the defect sites within the CdS band gap, CdS films were deposited on glass substrates at room temperature using various $H_2$/(Ar+$H_2$) flow ratios by an rf magnetron sputtering. Through the investigation of the structural and photoconductive properties of CdS films by an addition of hydrogen, the relationship between photo- and dark-resistance in CdS films was investigated in detail. 200-nm-thick CdS films for photoconductive sensor applications were prepared at various $H_2$/(Ar+$H_2$) flow ratios on glass substrates at room temperature by rf magnetron sputtering. Sulfur concentration in CdS films crystallized at room temperature with (002) preferred orientation depends directly on the hydrogen atmosphere and the surface roughness of the films gradually increases with increasing hydrogen atmosphere. Films deposited at 8% of $H_2$/(Ar+$H_2$) exhibit an abrupt decrease of dark- and photo-resistance, showing a low photo-sensitivity ($R_{dark}/R_{photo}$). Onthe other hand, films deposited at a hydrogen atmosphere of 42% exhibit a photo-sensitivity of $5\times10^3$, maintaining a photo-resistance of an approximately $2\times10^4\Omega$/square. The dark- and photo-resistance values of CdS films were related with a composition, surface roughness, and defect sites within the band gap.

  • PDF

Micro-Landform Classification and Topographic Property of Tidal Flat in Julpo-Bay Using Satellite Image (위성영상을 이용한 줄포만 간석지의 미지형 분류와 지형적특성)

  • 조명희;조화룡
    • Korean Journal of Remote Sensing
    • /
    • v.15 no.3
    • /
    • pp.217-225
    • /
    • 1999
  • Through the ISODATA method of unsupervised classification, the micro-landform of Julpo-Bay tidal flat was classified into mudflat, mixedflat, and sandflat using Landsat TM image. Each showed an apparent differences in its topographical characteristics and grain size composition. Mudflat occupied innermost part of the tidal flat, sandflat located closest to the entrance of the bay and mixed flat in the center is. For example, mudlflats are formed with flat faces and tidal channel. Topographically, mudflat consist of tidal channels and flat intermediate surface. Its average relief of them is about 2 meter. Meanwhile, sandflat comprised very flat landform with well-developed ripple marks of less than 10cm average relief. And Mixed flat stood in between. In addition, Out of 7 bands of Landsat TM images, band 5 and 7 provided the highest power level for discrimination between micro-landforms of the tidal flat. Band 4 showed a clear boundary between the land and tidal flat, and band 3 did its share by showing well a boundary between the sea surface and the tidal flat.

Analysis Methods of Visible and Near-Infrared (VNIR) Spectrum Data in Space Exploration (우주탐사에서의 가시광-근적외선 분광 자료 분석 기법)

  • Eung Seok Yi;Kyeong Ja Kim;Ik-Seon Hong;Suyeon Kim
    • Journal of Space Technology and Applications
    • /
    • v.3 no.2
    • /
    • pp.154-164
    • /
    • 2023
  • In space exploration, spectroscopic observation is useful for understanding objects' composition and physical properties. There are various methods for analyzing spectral data, and there are differences depending on the object and the wavelength. This paper introduces a method for analyzing visible & nearinfrared (VNIR) spectral data, which is mainly applied in lunar exploration. The main analysis methods include false color ratio image processing, reflectance pattern analysis, integrated band depth (IBD) processing, and continuum removal as preprocessing before analysis. These spectroscopic analysis methods help to understand the mineral properties of the lunar surface in the VNIR region and can be applied to other celestial bodies such as Mars.

Electronic Structure and Elemental Composition of the Lead Sulfide Colloidal Quantum Dots Depending on the Types of Ligand and Post-Treatment (리간드 종류와 후처리 공정에 따른 황화납 콜로이드 양자점 박막의 전자 구조 및 원소 조성 분석)

  • Kim, Tae Gun;Choi, Hyekyoung;Jeong, Sohee;Kim, Jeong Won
    • Journal of the Korean Chemical Society
    • /
    • v.60 no.6
    • /
    • pp.402-409
    • /
    • 2016
  • Thin films of lead sulfide colloidal quantum dots (CQDs) of 2.8 nm in diameter are fabricated and their surfaces are passivated by 3-mercaptopropionic acid (MPA) ligand or hybrid type ($MPA+CdCl_2$) ligand, respectively. The changes in valence band electronic structure and atomic composition of each PbS CQD film upon post-treatment such as air, N2 annealing or UV/Ozone have been studied by photoelectron spectroscopy. The air annealing makes the CQD fermi level to move toward the valence band leading to "p-type doping" regardless of ligand type. The UV/Ozone post-treatment generates $Pb(OH)_2$, $PbSO_x$ and PbO on both CQD surfaces. But the amount of the PbO has been reduced in hybrid type ligand case, especially. That is probably because the extra Pb cations in (111) surface are additionally passivated by $Cl_2$ ligand, which limits the reaction between the Pb cation and ozone.

National SFN Composition Method based on T-DMB considering Local Broadcasting Station (지역 방송국을 고려한 T-DMB기반 전국 SFN 구성 방안)

  • Ju, Sang-Lim;Jeong, Won-Ho;Kim, Kyung-Seok
    • The Journal of the Institute of Internet, Broadcasting and Communication
    • /
    • v.14 no.4
    • /
    • pp.21-27
    • /
    • 2014
  • The broadcasting of the analog TV was terminated in 2012 and was converted into the broadcasting of the digital TV, so methods for arrival of DAB(Digital Audio Broadcasting) are planned recently. Thus, with digitization of analog broadcasting and appearance of new service, it takes effort to improve efficiency of broadcasting frequency. T-DMB which came in 2005 uses existing analog TV band and its channel is allocated inefficiently in order to avoid interference between mutual services. However, the foundation which can afresh reorganize T-DMB channel is building up because the broadcasting of the analog TV was terminated. So, this paper proposes the method for national SFN composition of T-DMB considering existing local broadcasting in order to provide better service to users as well as improve efficiency of broadcasting frequency.

Effects of Dietary Bong-ip(Morus alba L.), Gam-chei(Glycyrrhizae glabra), Sol-ip(Pinus densiflora) and Dang-gi(Angelica gigas) on Serum Composition in Rats (뽕잎, 감초, 솔잎 및 당귀분말이 흰쥐의 혈청조성에 미치는 영향)

  • Cho, Young-Ja;Hou, Won-Nyoung
    • Journal of the Korean Society of Food Culture
    • /
    • v.20 no.1
    • /
    • pp.123-129
    • /
    • 2005
  • The purpose of this study was to investigate the effect of dietary Morus alba L.(Bong-ip, B), Glycyrrhizae glabra(Gam-chei, C), Pinus densiflora(Sol-lp, S) and Angelica gigas(Dang-gi, D)powder on serum composition in rats(Sprague-Dawley male rats, 100-110g). Serum TG(triglyceride, p<0.01), total cholesterol, glucose, total protein, albumin, GGT$({\gamma}-glutamyl$ transferase, p<0.05) were significantly increased D group than that of nomal and other groups, but UA(uric acid, p<0.05) was significantly decreased, and C group(p<0.05) was significantly increased. but C group of urine(p<0.05) was significantly decreased. Also, B and S groups(p<0.05) of BUN(blood urea nitrogen), S group(p<0.05) of ALP(alkaline phosphokinase, Band C(p<0.05) of CPK(creatinine phosphokinsae, p<0.05) were significantly increased. B, S and C groups were better than D group for lipid metabolism, and pretection to liver. Also, B and C groups of glucose were same as normal diet, so Morus alba L. was good food for lipid metabolism and hypoglycemic effect.

Isolation of Sunflower Seed Protein and its Chemical Composition (해바라기씨중의 식용단백질에 관한 연구 -단백질의 분리 및 그의 화학적 조성에 관한 연구-)

  • Cho, Sung-Hye;Kim, Jun-Pyong
    • Korean Journal of Food Science and Technology
    • /
    • v.9 no.2
    • /
    • pp.153-156
    • /
    • 1977
  • We have investigated for amino acid composition and molecular weight of the sunflower main protein which was purfied by Sephadex column. The results were obtained as fellow. 1. The salt-soluble sunflower proteins were highly dispersible in 0.02M sodium phosphate buffer, containing 10% sodium chloride. 2. The sunflower proteins were characterized by comparatively high levels of essential amino acids. 3. Seven bands of component of sunflower proteins were found in disc electrophoretic gel column. 4. The sunflower main protein was purified by Sephadex G-150 and A-25 column chromatography 5. The molecular weight was estimated 86,000 for the sunflower main protein.

  • PDF

Photoluminescence of CuInS2/(Cd,Zn)S Nanocrystals as a Function of Shell Composition

  • Kim, Young-Kuk;Ahn, Si-Hyun;Choi, Gyu-Chae;Chung, Kook-Chae;Cho, Young-Sang;Choi, Chul-Jin
    • Transactions on Electrical and Electronic Materials
    • /
    • v.12 no.5
    • /
    • pp.218-221
    • /
    • 2011
  • We modified the optical properties of the $CuInS_2$ nanocrystal (NC) by alloying. Nanocrystals (NCs) with alloyed cores were synthesized by refluxing the as-synthesized $CuInS_2$ NCs with a mixture of cadmium acetate, zinc acetate and palmitic acid. The shift in emission wavelength of the NCs after shell layer formation was minimized by alloying. The photoluminescence (PL) spectra showed significant reduction of emission intensity. A detailed study on the emission process of NCs implies that the formation of shell layers with small lattice mismatch minimized the mismatch strain generated from the shell layers in contrast to core alloyed NCs. In particular, time-resolved PL spectra of the NCs showed a significant increase in the lifetime of excited carriers by modifying the band alignment of the NCs by modifying the shell composition.