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Manufacture of Ordinary Portland Cement Clinker Using Cement Paste of the Waste Concrete (폐콘크리트로부터 회수된 시멘트 페이스트 미분말의 시멘트 원료화 연구)

  • Ahn, Ji-Whan;Kim, Hyung-Seok;Cho, Jin-,Sang;Han, Gi-Chun;Han, Ki-Suk;Kim, Hwan
    • Journal of the Korean Ceramic Society
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    • v.40 no.8
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    • pp.804-810
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    • 2003
  • The fine powder produced by heating and grinding of the waste concrete in the waste construction was investigated whether utilize as substitution raw material of SiO$_2$, CaO, and Al$_2$O$_3$ source for OPC clinker manufacture is possible or not. In order to synthesize OPC clinker, limestone, shale, converter slag and fly ash were used as main raw materials, and modulus was fixed LSF 91.0, SM 2.60, IM 1.60. The synthesized clinkers were characterized. The Main products of synthesized clinker were C$_3$S, ${\beta}$-C$_2$S, C$_3$A, C$_4$AF as OPC clinker at 1,43$^{\circ}C$. As a result of TG-DTA and burnability index(B.U) analysis of each raw mixtures, the formation temperature of clinker phases was similar and B.I was showed easy burning as 48.6∼51.4.

Preparation of PMN-PT-BT Powder by Modified Mixed Oxide Method and Effect of Ag on Dielectric Properties (Modified Mixed Oxide 방법에 의한 PMN-PT-BT 분말 합성 및 그의 물성에 미치는 Ag의 영향)

  • Lim, Kyoung-Ran;Jeong, Soon-Yong;Kim, Chang-Sam
    • Journal of the Korean Ceramic Society
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    • v.39 no.2
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    • pp.159-163
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    • 2002
  • A single phase perovskite relaxor ferroelectric PMN-PT-BT was prepared by a single calcination and the modified mixed oxide process. It was accomplished by ball-milling PbO, $Nb_2O_5,\;Ti(OC_3H_7)_4,\;BaCO_3,\;and\;Mg(NO_3)_2$ instead of MgO, removing the solvent, and then followed by calcination at 900$^{\circ}C$ for 2h. The specimen sintered at 1100$^{\circ}C$/2h showed the sintered density of 7.83 g/$cm^3$, room temperature dielectric constant of 22000, and dielectric loss of 2.5%. Addition of 1.0 mole% (0.3 wt%) of Ag as $AgNO_3$ and followed by calcination at 550$^{\circ}C$/2h lowered the sintering temperature to 900$^{\circ}C$. It still showed the sintered density of 7.88 g/$cm^3$, room temperature dielectric constant of 20000 and dielectric loss of 2.4%.

Electrical Characteristics of High Power Multilayer Piezoelectric Transformer Fabricated using Atrrition Milling Method (Attrition Milling법으로 제작된 고출력 적층 압전변압기의 전기적 특성)

  • Oh, Young-Kwang;Seo, Byeong-Ho;Yoo, Ju-Hyun;Kim, In-Sung;Song, Jae-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.18-18
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    • 2010
  • 전기적 에너지를 기계적 에너지로 변환하고 또한, 기계적 에너지를 전기적 에너지로 변환할 수 있는 압전 세라믹스는 압전 변압기 (piezoelectric transformer), 초음파 모터, 센서 등과 같은 응용분야에 광범위하게 사용되고 있다. 특히, 전원장치에 있어서 현재 주요 전자제품에 사용되고 있는 권선형 변압기와 같은 전자 변환기의 대체품으로 압전 세라믹스 소재의 특성을 이용한 압전변압기의 개발과 응용연구는 국내외적으로 활발히 연구되어왔다. 압전변압기는 권선형 변압기와 비교 하였을 때 누설자속이 없어 노이즈 발생이 없고, 공진주파수만을 이용하므로 출력의 파형이 정현파에 가까워 고조파 잡음이 없으며, 불연성의 특징을 가지고 있다. 추가적으로 압전 변압기는 소형화, 슬림화, 경량화가 가능하며 90%이상의 높은 효율을 얻을 수 있다. 또한, 단판형 압전변압기의 출력한계를 개선하기 위해 높은 승압비와 고출력을 갖는 적층타입의 압전변압기가 제안되었다. 압전변압기용 조성 세라믹스는 높은 에너지 변환효율을 위해서 전기기계결합계수 ($k_p$)가 커야 하며, 발열에 의한 온도 상승을 억제하기 위하여 기계적 품질계수(Qm)가 큰 것이 바람직하다. 또한, 높은 전류를 발생하기 위해서는 유전상수가 커 압전변압기의 출력측 정전용량을 크게 하여야한다. 이러한 압전변압기의 제작 조건을 위해 우수한 압전 및 유전특성을 갖는 PZT계 세라믹스가 주로 사용 되어져 왔다. 그러나, PZT계 세라믹스의 우수한 압전 및 유전특성에도 불구하고 $1000^{\circ}C$에서 급격히 휘발하는 PbO의 성질 때문에 환경적으로나 인체의 건강문제로 인해 전세계적으로 그 사용량을 제한하고 있다. 또한 적층 압전변압기의 구조적 특성상 내부전극과 함께 소결하여야 하는데, 이때 소결온도가 높으면 값비싼 Pd합량이 높은 전극을 사용하여야 한다. Pd함량이 10%미만인 Ag/Pd 전극을 사용하기 위해서는 $950^{\circ}C$ 이하에서 저온소결이 가능한 세라믹스 제조가 필수적이라 할 수 있다. 소결온도를 낮추는 방법으로는 다른 물질들을 치환하여 소결온도를 낮추는 방법과 미세분말을 만들어 그레인사이즈를 미세화 하는 방법들이 있다. 많은 미세 분말 제조 방법 중에서 Attrition mill은 일반적인 ball mill에 비해 분말의 입도를 미세하게 할 수 있어 증가된 분말의 비표면적에 의하여 반응을 촉진시킴으로써 저온소결이 가능한 세라믹스를 만들 수 있다. 따라서 본 연구에서는 소결온도가 낮으면서도 유전 및 압전특성이 우수한 조성을 사용하여 적층 압전변압기를 제작하여 전기적 특성을 조사하였다.

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Effects of Aggregate Size and Steel Fiber Volume Fraction on Compressive Behaviors of High-Strength Concrete (골재크기 및 섬유혼입률에 따른 강섬유 보강 고강도 콘크리트의 압축거동)

  • Ahn, Kyung-Lim;Jang, Seok-Joon;Jang, Sang-Hyeok;Yun, Hyun-Do
    • Journal of the Korea Concrete Institute
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    • v.27 no.3
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    • pp.229-236
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    • 2015
  • This paper describes the effect of aggregate size on compressive behavior of high-strength steel fiber reinforced concrete. The Specified compression strength is 60 MPa and the range of fiber volume fraction is 0~2%. The main variable is the aggregate size, which was used for the aggregate size of 8 and 20 mm. So, ten concrete mixtures were prepared and tested to evaluate the fresh and hardened properties of SFRC at curing ages (7, 14, 28, 56 and 91 days), respectively. Items estimated in this study are the fresh properties (air contents, slump), hardened properties (compressive strength, modulus of elasticity, post-peak response and compressive toughness). As a result, the aggregate size has little effect on the compressive strength and modulus of elasticity. On the other hand, the ductile behavior was shown after post peak and the compressive toughness was increasing as decreasing the aggregate size. These effects are clearly represented in the fiber volume fraction 2%, which are the point appeared fiber ball. It is considered that the decreasing the aggregate size has effect on the fiber dispersibility.

Fluxless Plasma Soldering of Pb-free Solders on Si-wafer -Effect of Plasma Cleaning - (Si-wafer의 플럭스 리스 플라즈마 무연 솔더링 -플라즈마 클리닝의 영향-)

  • 문준권;김정모;정재필
    • Journal of the Microelectronics and Packaging Society
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    • v.11 no.1
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    • pp.77-85
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    • 2004
  • To evaluate the effect of plasma cleaning on the soldering reliability the plasma cleaning using Ar-10vol%$H_2$ gas was applied on a UBM(Under Bump Metallization). The UBM consisted of Au/ Cu/ Ni/ Al layers which were deposited on a Si-wafer with 20 nm/ 4 $\mu\textrm{m}$/ 4 $\mu\textrm{m}$/ 0.4 $\mu\textrm{m}$ thickness respectively. Sn-3.5%Ag, Sn-3.5%Ag-0.7%Cu and Sn-37%Pb solder balls sized of 500 $\mu\textrm{m}$ in diameter were used. Solder balls on the UBM were plasma reflowed under Ar-10%$H_2$ plasma (with or without plasma cleaning). They were compared with air reflowed solder balls with flux. The spreading ratios of plasma reflowed solder with plasma cleaning was 20-40% higher than that of plasma reflowed solder without plasma cleaning. The shear strength of plasma reflowed solder with plasma cleaning was about 58-65MPa. It showed 60-80% higher than that of plasma reflowed solder without plasma cleaning and 15-35% higher than that of air reflowed solder. Thus it was believed that plasma cleaning for the UBM using Ar-10vol%$H_2$ gas was considerably effective for the improvement of the strength of solder ball.

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Mechanical Characteristic Evaluation of Sn-Ag-Cu Lead Free Solder Ball Joint on The Pad Geometry (패드 구조에 따른 Sn-Ag-Cu계 무연 솔더볼 접합부의 기계적 특성평가)

  • Jang, Im-Nam;Park, Jai-Hyun;Ahn, Yong-Sik
    • Journal of the Microelectronics and Packaging Society
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    • v.17 no.2
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    • pp.41-47
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    • 2010
  • The effect of PCB and BGA pad designs was investigated on the mechanical property of Pb-free solder joints. The mechanical property of solder joint was tested by three different test methods of drop impact tests, bending impact test, and high speed shear test. Two kinds of pad design such as NSMD (Non-Solder Mask Defined) and SMD (Solder Mask Defined) were applied with the OSP finished Pb-free solder (Sn-3.0Ag-0.5Cu, Sn-1.2Ag-0.5Cu). in the drop impact test and bending impact test, the characterized lifetime showed the same tendency, and SMD design showed better mechanical property of solder joint than NSMD regardless of test method, which was due to the different crack path. The fracture crack on SMD pad was propagated along the intermetallic compound (IMC) layer of solder joint, while the fracture crack on NSMD pad propagated through upper edge of land which shields pattern. In the high speed shear test, pad lift occurred on the solder joint of NSMD. SMD/SMD combination of pad design consequently illustrated the best mechanical property of BGA/PCB solder joint, followed by SMD/NSMD, NSMD/SMD, and NSMD/NSMD.

Systematic Review of High Frequency of Acupuncture Point and Self Exercise Therapy for Lower Back Pain (요통 치료의 빈용 경혈과 자가 운동 요법에 대한 체계적 문헌 고찰)

  • Nam, Dae-Jin;Huh, Gun;Lee, Hyung-Eun;Choi, Bo-Mi;Lee, Jung-Min;Lee, Eun-Jung;Oh, Min-Seok
    • Journal of Korean Medicine Rehabilitation
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    • v.23 no.4
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    • pp.59-71
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    • 2013
  • Objectives The aim of this review is to figure out which acupoints are frequently used to treat low back pain and which exercises are effective to low back pain. Methods We searched the three electronic database (RISS, KISS, KTKP) and manually checked related Korean journals and reference lists up to June 2013. We investigated the frequency of acupoints for using treatment of low back pain. We Introduce exercise therapies we can do easily at home without professional skills for treatment low back pain. Results We included 72 articles in this study. The most frequently adopted acupoints were BL25, BL23, BL24, GB30, BL40, BL26, BL60, GB34, BL52, BL57, GB39. The most frequently adopted meridian pathways were BL, GB, GV, ST. The most frequently adopted disease causing low back pain were HIVD (Herniated intervertebral disc), Lumbar sprain, Spinal stenosis, Compression fracture, Cauda equina syndrome, Spondylolisthesis, Ankylosing spondylitis. There are many exercise therapies (Lumbar stabilizing exercise, Resistance exercise, Bareunmom physical exercise, Mckenzie exercise, Williams exercise, Emblass exercise, Swiss ball exercise, Thera band exercise, Yoga) for treatment low back pain. Conclusions These results suggest that most frequently adopted acupoints were foot taeyang urinary bladder channel acupoints. Beacuse foot taeyang urinary bladder channel is passes through the waist, it will be effective for treatment of low back pain. Also exercise therapy is effective for enhance Muscular strength. In order to treatment of low back pain, Acupuncture treatment is also important, as well as exercise therapy.

COMPARATIVE STUDY ON THE FRACTURE STRENGTH OF EMPRESS 2 CERAMIC AND TARGIS-VECTRIS CROWN

  • Cha Young-Joo;Yang Jae-Ho;Lee Sun-Hyung;Han Jung-Suk
    • The Journal of Korean Academy of Prosthodontics
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    • v.39 no.6
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    • pp.599-610
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    • 2001
  • Due to an increasing interest in esthetics and concerns about toxic and allergic reactions to certain alloys, patients and dentists have been looking for metal-free tooth-colored restorations. Recent improvement in technology of new all-ceramic materials and composite materials has broadened the options for esthetic single crown restorations. The aim of this investigation was to study the fracture strength of the metal-free posterior single crowns fabricated using two recently introduced systems, Empress 2 ceramic and Targis-Vectris. Forty premolar-shaped stainless steel dies with the 1mm-wide circumferential shoulder were prepared. Ten cylindrical crowns having a diameter of 8.0mm and total height of 7.5mm were fabricated for each crown system respectively(PFM, Empress staining technique, Empress 2 layering technique, and Targis- Vectris). The crowns were filled with cement and placed on the stainless steel dies with firm finger pressure. The crowns were then stored in distilled water at room temperature for 24 hours before testing. The crowns were tested for fracture strength in an Instron universal testing machine (Instron 6022). With a crosshead speed of 1mm/min the center of the occlusal surface of the crown was loaded using a 4-mm-diameter stainless steel ball until fracture occurred. The fracture surfaces of the crowns were gold coated and examined using scanning electron microscopy(Jeol JSM-840 Joel Ltd., Akishima, Tokyo, Japan). Within the parameters of this study the following conclusions were drawn: 1. The mean fracture strength for PFM crowns was 5829(${\pm}906$)N; for Empress staining technique the fracture strength was 1697(${\pm}604$)N; for Empress 2 Layering technique the fracture strength was 1781N(${\pm}400$)N, and the fracture strength for Targis- Vectris was 3093(${\pm}475$)N. 2. The fracture strength of the PFM crowns was significantly higher than that of the Empress 2 and the Targis-Vectris crowns (P<0.05). 3. The fracture strength of the Targis-Vectris crowns was significantly higher than that of the Empress 2 crowns (P<0.05). 4. No statistical difference was found when Empress staining technique was compared with Empress 2 layering technique. 5. The SEM image of fracture surface of Empress 2 crown showed a very dense microstructure of the lithium disilicate crystals and the SEM image of fracture surface of Targis-Vectris crown showed indentations of Vectris and some fibers tom off from Vectris.

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FLEXURAL STRENGTH OF IMPLANT FIXED PROSTHESIS USING FIBER REINFORCED COMPOSITE (섬유성 강화 컴포지트를 사용한 임플랜트 고정성 보철물의 굴곡강도)

  • Kang, Kyung-Hee;Kwon, Kung-Rock;Lee, Sung-Bok;Choi, Dae-Gyun
    • The Journal of Korean Academy of Prosthodontics
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    • v.44 no.5
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    • pp.526-536
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    • 2006
  • Statement of problem : Use of fiber composite technology as well as development of nonmetal implant prosthesis solved many problems due to metal alloy substructure such as corrosion. toxicity, difficult casting, expensiveness and esthetic limit. After clinical and laboratory test, we could find out that fiber-reinforced composite prostheses have good mechanical properties and FRC can make metal-free implant prostheses successful. Purpose : The purpose of this study is to evaluate the flexural strength of implant fixed prosthesis using fiber reinforced composite. Material and methods : 2-implant fixture were placed in second premolar and second molar area in edentulous mandibular model, and their abutments were placed, and bridge prostheses using gold, PFG, Tescera, and Targis Vectris were fabricated. Tescera was made in 5 different designs with different supplements. Group I was composed by 3 bars with diameter 1.0mm and 5 meshes, 2 bars and 5 meshes for Group II, 1 bar and 5 meshes for Group III, and only 5 meshes were used for Group IV. And Group V is composed by only 3 bars. Resin (Tescera) facing was made to buccal part of pontic of gold bridge. All of gold and PFG bridges were made on one model, 5 Targis Vectris bridges were also made on one model, and 25 Tescera bridges were. made on 3 models. Each bridge was attached to the test model by temporary cement and shallow depression was formed near central fossa of the bridge pontic to let 5 mm metal ball not move. Flexual strength was marked in graph by INSTRON. Results : The results of the study are as follows. The initial crack strength was the highest on PFG. and in order of gold bridge Tescera I, Tescera II, Targis vectris, Tescera IV, Tescera III, and Tescera V. The maximum strength was the highest on gold bridge, and in order of PFG, Tescera I, Tescera IV Tescera II, Targis vectris, Tescera III, and Tescera V. Conculsions : The following conclusions were drawn from the results of this study. 1. Flextural strength of implant prosthesis using fiber reinforced composite was higher than average posterior occlusal force. 2. In initial crack strength, Tescera I was stronger than Tescera V, and weaker than PFG. 3. Kinds and number of auxillary components had an effect on maximum strength, and maximum strength was increased as number of auxillary components increased. 4 Maximum strength of Tescera I was higher than Targis vectris, and lower than PFG.

Implant-assisted removable partial denture using freely removable abutment in a fully edentulous patient: A case report (완전 무치악 환자에서 자유 착탈가능 임플란트 지대주를 이용한 임플란트 융합 국소의치 수복증례)

  • Oh, You-Kyoung;Jeong, Chang-Mo;Yun, Mi-Jung;Lee, So-Hyoun;Lee, Hyeon-Jong;Huh, Jung-Bo
    • The Journal of Korean Academy of Prosthodontics
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    • v.58 no.1
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    • pp.58-66
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    • 2020
  • Implant-Assisted Removable Partial Dentures (IARPDs) treatment is being performed in a fully edentulous patient using implant surveyed prosthesis as an abutment. Implant-supported prosthesis as an abutment of IARPDs is classified into screw-retained and cement-retained type according to the retention type, and each has advantages and disadvantages. The EZ crown system (Samwon DMP, Yangsan, Korea) has a cylinder combined with abutment, and the nickel-titanium spring in this cylinder provides a constant force on the zirconia ball to obtain retention in EZ crown system. In this patient, the natural abutment teeth of the mandibular overdenture was hopeless. We planned implant assisted removable partial denture using anterior implant surveyed prosthesis considering functional and esthetical rehabilitation, cost and patient's needs. When fabricating IARPDs using implant as abutment, we could compensate for the shortcomings of existing implant-supported prosthesis retention type and made the design of removable partial denture easy due to using EZ crown system.