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Membrane Technology for Waste Water Recovery

  • Okazaki, Minoru
    • Proceedings of the Membrane Society of Korea Conference
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    • 1996.10a
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    • pp.22-33
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    • 1996
  • With the experience of the 1994 drought, and the shortage of water resources in Japan, it has been re-informed upon us ensure and maintain the stability of water resources. Accordingly, with each plant, a serious appraisal has begun looking at the re-use of waste water. Membrane technology is an important process for waste water recovery. Effluent kom waste water facilities changes the quality of water significantly. The conventional pre-treatment of RO is hard to supply good quality feed water to RO in the waste water recovery system. The microfiltration system as a pre-treatment of RO in the paper overcomes the fouling with the air backwash and is operated in direct flow mode at a low pressure producing a high flux. The paper will focus the waste water recovery using membrane technology and many examples will be given.

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Tertiary Treatment of Municipal Wastewater and Bypassed Rainfall Treatment using by BAF (BAF를 이용한 하수의 3차 처리 및 by-pass된 우수의 처리)

  • Lee, Kwang Je;Park, Jae-Hong
    • Journal of Korean Society on Water Environment
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    • v.21 no.4
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    • pp.327-331
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    • 2005
  • The study was conducted with two laboratory biological aerated filter (BAF) reactors: denitrification filter (DF) and nitrification BAF. The influent flow (Q) was fixed to 48 L/d and total empty bed contact time (EBCT) was 1 hr. The flow direction was upflow with NRCY of 1 to 2Q. The secondary effluent was fed to the reactors and the influent concentrations were adjusted with some stock solutions to simulate by-pass concentration during rainfall. The study results indicate that COD and SS removal efficiencies were excellent and not influenced by temperature. Nitrification efficiency was over 90% at the influent loading less than $1.12kg/media\;m^3/d$, but the efficiencies were decreased in low temperature. TN removal efficiencies were 10% to 60%.

Relationship Between China's College Entrance Examination and High School Teaching-Learning

  • Ren, Zizhao
    • Research in Mathematical Education
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    • v.2 no.2
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    • pp.79-88
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    • 1998
  • To investigate the relationship between the College Entrance Examination (CEE) exams and high school teaching-learning, we conducted a questionnaire survey and collected 2439 valid questionnaires with 16000 teachers involved. This paper discusses the topic with data gathered from the survey, and statistics on CEE examinations over the past few years. The following three questions will be addressed in detail: 1. As a talent selection test for colleges, can the CEE exams single out the elite students in high school? 2. Should the testing objectives of the CEE exams match the teaching objectives in high school so as to have a positive backwash effect on high school teaching and learning? 3. How do teachers assess the CEE exams from the angles of test structure, the functions of individual item types, reforms on test difficulties, and its actual checking effects?

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A Study on Operating Condition of Test-Bed Plant using Membrane filtration of D Water Treatment Plant in Gwang-Ju (D정수장 정밀여과막 실증플랜트의 최적 운전조건 연구)

  • Yang, Hyung-Jae;Yi, Seung-Hoon;Moon, Kyung-Ran
    • Journal of Korean Society of Environmental Engineers
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    • v.39 no.3
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    • pp.155-163
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    • 2017
  • Membrane filtration has become more popular in drinking water treatment recently, since the filtration can control not only particulate matters but also pathogenic microorganisms such as giardia and cryptosporidium very effectively. Pilot-scale ($120m^3/d$ of treatment capacity) and test-bed ($25,000m^3/d$ of treatment capacity) microfiltration experiments were conducted to find optimum operating mode and the critical flux. Optimum operating mode of pilot-test was assessed as inflow 1.0 min, filtration 36.5 min, air backwash 0.9 min, backwash 1.0 min and outflow 1.0 min with 50 LMH ($L/min{\cdot}m3^$) of critical flux. Critical Flux was calculated to be $50L/m^2-h$ (within TMP 0.5 bar) based on the increase formula of the transmembrane pressure difference according to the change of time at Flux 20, 40, 56 and 62 LMH in pilot operation. Chemical cleaning was first acid washed twice, and alkali washing was performed secondarily, and a recovery rate of 95% was obtained in the test-bed plant. The results of operating under these appropriate conditions are as follows. Turbidity of treated water were 0.028, 0.024, 0.026 and 0.028 NTU in spring, summer, autumn and winter time, respectively. Microfiltration has superior treatment capability and performance characteristics in removing suspended solids and colloidal materials, which are the main cause of turbidity and important carrier of metal elements, and it has shown great potential in being an economically substitute to traditional processes (sand filtration).

A Study on Nitrification of Raw Waters Containing Linear Alkyl Sulfate in Biological Activated Carbon (생물활성탄을 이용한 Linear Alkyl Sulfate함유 원수에서의 질산화에 관한 연구)

  • Park, Seong Sun;Chang, Ji Soo;Yu, Myong Jin
    • Journal of Korean Society of Water and Wastewater
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    • v.9 no.3
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    • pp.116-126
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    • 1995
  • The purpose of this study was to investigate the removal of ammonium nitrogen by biological nitrification in raw water containing LAS using BAC. At batch teats, LAS removal by ozone followed the first order reaction, and the rate constants(k) by ozone dose 1, 3mg/min.L were $0.040min^{-1}$, $0.062min^{-1}$ respectively. Therefore, the more ozone was dosed, the higher LAS was removed The reaction between ozone and ammonium nitrogen also followed the first order, and rate constants(k) at pH7,8 and 9 were $8.9{\times}10^{-4}min-1$, $3.8{\times}10^{-3}min^{-1}$, and $2.9{\times}10^{-2}min^{-1}$ respectively at ozone dose of 3mg/min.L . Therefore, ammonium nitrogen was little removed by ozone under neutral pH of 7. The continuous flow apparatus had four sets composed of a ozone contacter and a GAC column. Through continuous filtration test for 50days, the following conclusions were derived; (1) LAS was removed 23%, 30% respectively by ozone dose 1, 3mg/L, and was not detected in all column effluents during the period of experiment. Therefore, it appeared that adsorption capacities of each column still remained. (2) Ammonium nitrogen concentration after ozone contact varied little in raw Water because pH of raw water was from 6 to 7, and was transfered to nitrite and nitrate within GAC columns as the result of staged nitrification. After 30days, nitrite was not detected in all column effluents due to biological equilbrium between nitro semonas and nitrobacter Average removals of ammonium nitrogen in each column after the lapse of 30days were the following; ${\cdot}$ column A (ozone dose 3mg/L, EBCT 9.5min): about 100% ${\cdot}$ column B (ozone dose 1mg/L, EBCT 9.5min): 91% ${\cdot}$ column C (ozone dose 3mg/L, EBCT 14.2min): about 100% ${\cdot}$ column D (ozone dose 0mg/L, EBCT 9.5min): 53% Though column A and C reached nitrification of about 100%, column C (longer EBCT than column A) was more stable than column A. (3) After backwash, nitrification reached steady state within 5 to 8 hours. Therefore, nitrification was not greatly affected by backwash. (4) According to the nitrification capacity in depth of column A, C, where 100% nitrification occured. LAS was removed within 20cm, while ammonium nitrogen required more depth to be removed by nitrification.

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Potable Water Treatment Study using the Double Stage Fiber Filter for the Pre-treatment of the Reverse Osmosis Membrane (역삼투막 전처리로서의 2단 섬유상 여과기를 이용한 정수처리 연구)

  • Bae, Si-Youl;Jang, Hyung-Wook;Yun, Chang-Han
    • Membrane Journal
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    • v.20 no.2
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    • pp.97-105
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    • 2010
  • This study was to evaluate the performance of the Double stage Pore controllable fiber (DP) filter system as the pre-treatment of the RO membrane. The evaluation for the pre-treatment filter was performed through the indirect method, SDI (Silt Density Index) measurement of the filtrate. This study was done during Jan. 3 of 2009 to Dec. 3 of 2009 at OO Water Treatment Plant that was suppling industrial water to plants, and the raw water was contaminated lake water and it was fed to the system after clarification with coagulation. The average turbidity of the feed water and that of the filtrate was 0.79 NTU (0.28~4.01 NTU), and 0.16 NTU (0.04~0.50) respectively. And so the average turbidity removal efficiency was 77%. The filtrate flow rate and the backwash water flow rate was about 230 $m^3$/day and about 8.7 $m^3$/day respectively, and so the backwash rate was 3.8%. The data for some samples were obtained after a few days storage, and it caused the higher turbidity and SDI15 as the storage time was increased. But average SDI value of the filtrate was 3.6 (2.26~5.00) which was lower than minimum value required by the RO membrane manufacturer as the RO feed water to guarantee the life time of the RO membrane. So, the DP filter system was enough for the application as the pre-treatment of the RO membrane.

The Study on Optimum Operation Conditions of Ceramic MF Membrane Process in Y Water Treatment Plant (Y 정수장 세라믹막 여과공정 최적 운영인자 평가)

  • You, Sang-Jun;Ahn, Hyo-Won;Park, Sung-Han;Lim, Jae-Lim;Hong, Sung-Chul;Yi, Pyong-In
    • Membrane Journal
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    • v.24 no.3
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    • pp.201-212
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    • 2014
  • This study was performed to discover the optimum operation conditions for the advanced water treatment using the ceramic membrane, introduced the first in the nation at the Y water treatment plant (WTP). The result of investigation to find the optimum operation conditions which can continue preserving the filtration performance as well as satisfying both the economics and the water quality is as follows. In the ordinary water quality condition of the Y WTP, the optimum filtration time(the backwash period), which can minimize the production of backwash waste and preserve the membrane performance was examined to be 4.0 hours on basis of institution capacity ($16,000m^3/day$). Examining the recovery rate of TMP from the chemical cleaning (CIP) discovered that the inorganic contaminants, which cause membrane fouling, such as iron, manganese, aluminum, were removed through the acidic cleaning using citric acid, whereas the membrane recovery rate was found to be low. But, on the other hand, the TMP was recovered to the initial value from the alkali cleaning using the NaOCl. Therefore, the main contaminant causing the fouling was determined to be hydrophilic organic compound( biopolymer). The membrane recovery rate is highly influenced by the temperature of the cleaning chemical. That is, the rate increased with increasing temperature.

A pilot study of high flux membrane process for responding to influent turbidity changes in reservoir water (호소수 탁도변화 대응을 위한 고플럭스 막여과공정의 Pilot 연구)

  • Kang, Joonseok;Seong, Jayeong;Yoo, Jewan;Kim, Hyungsoo;Lee, Jaekyu;Jeon, Minhyuk;Cheon, Jihoon
    • Journal of Korean Society of Water and Wastewater
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    • v.34 no.6
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    • pp.393-402
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    • 2020
  • In the membrane process, it is important to improve water treatment efficiency to ensure water quality and minimize membrane fouling. In this study, a pilot study of membrane process using reservoir water was conducted for a long time to secure high flux operation technology capable of responding to influent turbidity changes. The raw water and DAF(Dissolved Air Flotation) treated water were used for influent water of membrane to analyze the effect of water quality on the TMP (Trans Membrane Pressure) and to optimize the membrane operation. When the membrane flux were operated at 70 LMH and 80 LMH under stable water quality conditions with an inlet turbidity of 10 NTU or less, the TMP increase rates were 0.28 and 0.24 kPa/d, respectively, with minor difference. When the membrane with high flux of 80 LMH was operated for a long time under inlet turbidity of 10 NTU or more, the TMP increase rate showed the maximum of 43.5 kPa/d. However, when the CEB(Chemically Enhanced Backwash) cycle was changed from 7 to 1 day, it was confirmed that the TMP increase rate was stable to 0.23 kPa/d. As a result of applying pre-treatment process(DAF) on unstability water quality conditions, it was confirmed that the TMP rise rates differed by 0.17 and 0.64 kPa/d according to the optimization of the coagulant injection. When combined with coagulation pretreatment, it was thought that the balance with the membrane process was more important than the emphasis on efficiency of the pretreatment process. It was considered that stable TMP can be maintained by optimizing the cleaning conditions when the stable or unstable water quality even in the high flux operation on membrane process.

Biofilter pretreatment for the control of microfiltration membrane fouling

  • Park, Jae-Hyung;Satoshi Takizawa;Hiroyuki Katayama;Shinichiro Ohgaki
    • Proceedings of the Membrane Society of Korea Conference
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    • 2003.05a
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    • pp.31-38
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    • 2003
  • A pilot scale biofilter pretreatment-microfiltration system (BF-MF) was operated to investigate the effect of biofilter treatment in fouling reduction of microfiltration. Biofiltration was expected to reduce the membrane fouling by removal of turbidity and metal oxides. The hollow-fiber MF module with a nominal pore size of 0.1$\mu$m and a surface area of 8m$^2$ was submerged in a filtration tank and microfiltration was operated at a constant flux of 0.5 m/d. Biofiltration using polypropylene pellets was performed at a high filtration velocity of 320 m/d. Two experimental setups composed of MF and BF/MF, i.e., without and with biofilter pretreatment, were compared. Throughout the experimental period of 9 months, biofilter pretreatment was effective to reduce the membrane fouling, which was proved by the result of time variations of trans-membrane pressure and backwash conditions. The turbidity removal rate by biofiltration varied between 40% to 80% due to the periodic washing for biofilter contactor and raw water turbidity. In addition to turbidity, metals, especially Mn, Fe and Al were removed effectively with average removal rates of 89.2%, 67.8% and 64.9%, respectively. Further analysis of foulants on the used membranes revealed that turbidity and metal removal by biofiltration was the major effect of biofiltration pretreatment against microfiltration fouling.

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Evaluation of Design Parameter on Residuals Treatment Facilities in Membrane Water Treatment Plants (막여과 정수장에서의 배출수처리시설 설계인자 평가)

  • Moon, Yong-Taik;Seo, In-Seok;Kim, Hong-Suck;Park, No-Suk;Ahn, Hyo-Won
    • Journal of Korean Society of Water and Wastewater
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    • v.20 no.1
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    • pp.138-146
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    • 2006
  • The characteristics of backwash and concentrate discharges depend upon the quality of the water being treated and the net recovery of the membrane system. This paper is to indicate a design methods on the capacities of residuals treatment facilities in membrane processes for drinking water. We operated a demonstration membrane plant with a recovery rate of 90% for designing G-water treatment plant. We investigated on design parameter (optimum coagulant dosage and surface loading rate etc.) to design efficiently the residuals treatment facilities. The settling test was conducted with 1m columns dosing PACl to kaolin and membrane residuals under the experimental condition that discharge permit was under a 60mg/L. When the quantity of membrane residuals was $1,575m^3/day$, the estimated results for 1st thickener demonstrated the surface loading rate of 14.4m/day, detention time of 5.83hr, available depth of 3.5m.