• Bulletin of the Korean Chemical Society
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• v.26 no.7
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• pp.1044-1050
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• 2005

The reaction of cis-[Cr([14]-decane)($OH_2)_2]^+$ ([14]-decane = rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-teraazacyclotetradecane) with auxiliary ligands {$L_a$ = isothiocyanate ($NCS^-$), azide ($N3^-$) or chloroacetate(caa)} leads to a new cis-[Cr([14]-decane)($NCS)_2]ClO_4{\cdot}H_2O$ (1), cis-[Cr([14]-decane)($N_3)_2]ClO_4$ (2) or cis-[Cr([14]-decane)($caa)_2]ClO_4$ (3). These complexes have been characterized by a combination of elemental analysis, conductivity, IR and Vis spectroscopy, mass spectrometry, and X-ray crystallography. Analysis of the crystal structure of cis-[Cr([14]-decane)($NCS)_2]ClO_4{\cdot}H_2O$ reveals that central chromium(III) has a distorted octahedral coordination environment and two $NCS^-$anions are bonded to the chromium(III) ion via the Ndonor atom in the cis positions. The angle $N_{axial}-Cr-N_{axial}$ deviates by 13$^{\circ}$ from the ideal value of 180$^{\circ}$ for a perfect octahedron. The bond angle N-Cr-N between the Cr(III) ion and the two nitrogen atoms of the isothiocyanate ligands is close to 90$^{\circ}$. The bond lengths of Cr-N between the chromium and $NCS^-$groups are 1.964(5) and 2.000(5) $\AA$. They are shorter than those between chromium and nitrogen atoms of the macrocycle. The IR spectra of 1, 2 and 3 display bands at 2073, 1344 and 1684 $cm^{-1}$ attributed to the $NCS^-$, ${N_3}^-$ and caa groups stretching vibrations, respectively.

• The Journal of the Petrological Society of Korea
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• v.28 no.3
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• pp.217-225
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• 2019

This study describes a large recumbent fold, which occurs at the north entrance slope of the Batjae tunnel, Pyeongchang-gun, Gangwon-do, and interprets its formation mechanism. The several-hundred-meter scale fold, developed in the Jeongseon Limestone of the Paleozoic Joseon Supergroup, has a nearly horizontal axial plane and its head is facing north. Stretching lineations ($L_1$) observed on the composite foliations of bedding and axial plane cleavage plunge southward at about $10^{\circ}$. Small A-type or eye-shaped sheath folds together with S-shaped asymmetrical folds are often observed in the fold limbs and their axes are nearly parallel to the lineations ($L_1$) within center and rear parts of the fold. It is thus interpreted that the recumbent fold is a large sheath fold produced by the top-to-the-north ductile shearing due to the Songrim orogeny during the late Paleozoic to Triassic.

• Journal of the Korean Electrochemical Society
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• v.9 no.1
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• pp.29-33
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• 2006

A new porous separator based on poly(vinyl chloride) (PVC)/poly(vinylidene fluoride-co-hexafluoro-propylene) (P(VdF-co-HFP)/poly(methyl methacrylate) (PMMA) was prepared by a phase inversion method. To enhance mechanical property, the membrane was stretched uniaxially at high temperature. Tensile strength and ionic conductivity were measured for various draw ratios. The tensile strength and ionic conductivity were increased with increasing draw ratio. The tensile strength of the separator reached 52MPa after stretching to draw ratio of 5, and the ionic conductivity of the separator was increased from $1.9Xs10^{-4}S/cm\;to\;4.6X10^{-4}S/cm\;at\;25^{\circ}C$. The stretched separator immersed in liquid electrolyte was electrochemically stable up to 4.7 V. The cell based on the stretched separator was maintained at about 99% of the initial discharge capacity after 10th cycle operation at 0.2C rate.

• Elastomers and Composites
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• v.42 no.3
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• pp.137-142
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• 2007

In the performance test of polytetrafluoroethylene (PTFE) membrane, melting temperature and crystallinity were $344.1^{\circ}C$ and 42.5%, respectively, according to TGA and DSC analysis. These values were similar to those of commercially available GE Osmonics PTFE membrane. The average of pore size was observed $0.716{\mu}m$ and the average flow rate was 1.570 LMH. These are slightly higher values than those of GE Osmonics sample. The filtering efficiency rate was 30.5%.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.08a
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• pp.274.1-274.1
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• 2013

We report the circumferential alignment of human aortic smooth muscle cells (HASMCs) in an orthogonally micropatterned circular microfluidic channel to form an in vivo-like smooth muscle cell layer. To realize a biomimetic smooth muscle cell layer which is aligned perpendicular to the axis of blood vessel, we first fabricated a half-circular polydimethylsiloxane (PDMS) microchannel by soft lithography using a convex PDMS mold. The orthogonally micro wrinkle patterns were generated inside the half-circular microchannel by stretching-releasing operation under UV irradiation. Upon UV treatment with uniaxial 40 % stretch of a PDMS substrate and releasing process, the microwrinkle patterns perpendicular to the axial direction of the circular microchannel were generated, which could guide the circumferential alignment of HASMCs successfully during cultivation. The analysis of orientation angle, shape index, and contractile protein marker expression indicates that the cultured HASMCs revealed the in vivo-like cell phenotype. Finally, we produced circular microchannels by bonding two half-circular microchannels, and cultured the HASMCs circumferentially with high alignment and viability for 5 days. These results are the first demonstration for constructing an in vivo-like 3D smooth muscle cell layer in the circular microfluidic channel which can provide novel bioassay platforms for in-depth study of HASMC biology and vascular function.

• Structural Engineering and Mechanics
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• v.76 no.4
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• pp.451-463
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• 2020

In this paper, a new semi-analytical solution for estimating the pull-in parameters of electrically actuated functionally graded (FG) nanobeams is proposed. All the bulk and surface material properties of the FG nanoactuator vary continuously in thickness direction according to power law distribution. Here, the modified couple stress theory (MCST) and Gurtin-Murdoch surface elasticity theory (SET) are jointly employed to capture the size effects of the nanoscale beam in the context of Euler-Bernoulli beam theory. According to the MCST and SET and accounting for the mid-plane stretching, axial residual stress, electrostatic actuation, fringing field, and dispersion (Casimir or/and van der Waals) forces, the nonlinear nonclassical equation of motion and boundary conditions are obtained derived using Hamilton principle. The proposed semi-analytical solution is derived by employing Galerkin method in conjunction with the Particle Swarm Optimization (PSO) method. The proposed solution approach is validated with the available literature. The freestanding behavior of nanoactuators is also investigated. A parametric study is conducted to illustrate the effects of different material and geometrical parameters on the pull-in response of cantilever and doubly-clamped FG nanoactuators. This model and proposed solution are helpful especially in mechanical design of micro/nanoactuators made of FGMs.

• Computers and Concrete
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• v.24 no.4
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• pp.347-367
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• 2019

This work investigates the effect of Winkler/Pasternak/Kerr foundation and porosity on dynamic behavior of FG plates using a simple quasi-3D hyperbolic theory. Four different patterns of porosity variations are considered in this study. The used quasi-3D hyperbolic theory is simple and easy to apply because it considers only four-unknown variables to determine the four coupled vibration responses (axial-shear-flexion-stretching). A detailed parametric study is established to evaluate the influences of gradient index, porosity parameter, stiffness of foundation parameters, mode numbers, and geometry on the natural frequencies of imperfect FG plates.

• The Journal of the Petrological Society of Korea
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• v.6 no.3
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• pp.244-244
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• 1997

The Janggunbong area(this study area) at the central-south part in the North Sobaegsan Massif, Korea, consists mainly of Precambrian(Wonnam and Yulri Formations)-Paleozoic [Joseon Supergroup(Jangsan Quarzite, Dueumri Formation and Janggum Limestone) and Pyeongan Group(Jaesan and Dongsugok Formations)] metasedimentary rocks and Mesozoic granitoid(Chunyang granite.) This study is to interpret geological structure of the North Sobaegsan Massif in the Jang-gunbong area by analysing rock-structure and microstructure of the constituent rocks. It indicates that its geological structure was formed at least by four phases of deformation after the formation of gneissosity(S0) in the Wonnam Formation and bedding plane(S0) in the Paleozoic metasedimentary rocks. The first phase deformation(D1) formed tight isoclinal fold(F1). Its axial plane(S1) strikes east-west and steeply dips north. Its axis (L1) subhorizontally plunges east-west. The second phase deformation(D2), which was related to ductile shear deformation, formed stretching lineation(L2) and shear foliation(S2). The sense of the shear movement indicates dextral strike-slip shearing(top-to-the east shearing). The third phase deformation(D3) formed open inclined fold(F3). Its axial plane(S3) strikes east-west and moderately or gently dips north. Its axis(L3) subhorizontally plunges east-west. The F3 fold reoriented the original north-dipping S1 foliation and D2 shear sense into south-dipping S1 foliation(top-to-the west shear sense on this foliation) at its a limb. The four phase of deformation(D4) formed asymmetric-type open inclined fold(F4) of NE-vergence with NW striking axial plane(S4) and NW-NNW plunging axis(L4). The F4 fold partly reoriented pre-D4 structural elements with east-west trend into those with north-south trend. Such reorientation is recognized mainly in the Paleozoic metasedimentary rocks.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.35 no.7
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• pp.709-715
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• 2011

In order to observe the wake interaction between tip vortices generated by a two-bladed rotor with slightly different pitch angles, the velocity components of the tip vortices were measured by using a two-dimensional LDV system. It was observed that the swirl velocity components of the ensuing blade deviated from the Vatistas' n = 2 vortex model and the axial velocity components of the preceding blade deviated from the Gaussian profile. It was also found that in the wake-age range of $200^{\circ}$ to $240^{\circ}$, the filament of the ensuing blade tip vortex was stretched as result of the closing in of two vortices. The results from these observations suggest the possibility that a similar wake interaction is generated in actual rotor blades, especially, in the ones with articulated hubs.

• Smart Structures and Systems
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• v.17 no.1
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• pp.73-89
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• 2016

The stress dependence of ultrasonic wave velocity is known as the acoustoelastic effect. This effect is useful for stress monitoring if the acoustoelastic coefficient of a subject medium is known. The acoustoelastic coefficients of metallic materials such as steel have been studied widely. However, the acoustoelastic coefficient of concrete has not been well understood yet. Basic constituents of concrete are water, cement, and aggregates. The mix proportion of those constituents greatly affects many mechanical and physical properties of concrete and so does the acoustoelastic coefficient of concrete. In this study, influence of the water-cement ratio (w/c ratio) and the fine-coarse aggregates ratio (fa/ta ratio) on the acoustoelastic coefficient of concrete was investigated. The w/c and the fa/ta ratios are important parameters in mix design and affect wave behaviors in concrete. Load-controlled uni-axial compression tests were performed on concrete specimens. Ultrasonic wave measurements were also performed during the compression tests. The stretching coda wave interferometry method was used to obtain the relative velocity change of ultrasonic waves with respect to the stress level of the specimens. From the experimental results, it was found that the w/c ratio greatly affects the acoustoelastic coefficient while the fa/ta ratio does not. The acoustoelastic coefficient increased from $0.003073MPa^{-1}$ to $0.005553MPa^{-1}$ when the w/c ratio was increased from 0.4 to 0.5. On the other hand, the acoustoelastic coefficient changed in small from $0.003606MPa^{-1}$ to $0.003801MPa^{-1}$ when the fa/ta ratio was increased from 0.3 to 0.5. Finally, it was also found that the relative velocity change has a linear relationship with the stress level of concrete.