• Bulletin of the Korean Chemical Society
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• 제26권7호
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• pp.1044-1050
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• 2005

The reaction of cis-[Cr([14]-decane)($OH_2)_2]^+$ ([14]-decane = rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-teraazacyclotetradecane) with auxiliary ligands {$L_a$ = isothiocyanate ($NCS^-$), azide ($N3^-$) or chloroacetate(caa)} leads to a new cis-[Cr([14]-decane)($NCS)_2]ClO_4{\cdot}H_2O$ (1), cis-[Cr([14]-decane)($N_3)_2]ClO_4$ (2) or cis-[Cr([14]-decane)($caa)_2]ClO_4$ (3). These complexes have been characterized by a combination of elemental analysis, conductivity, IR and Vis spectroscopy, mass spectrometry, and X-ray crystallography. Analysis of the crystal structure of cis-[Cr([14]-decane)($NCS)_2]ClO_4{\cdot}H_2O$ reveals that central chromium(III) has a distorted octahedral coordination environment and two $NCS^-$anions are bonded to the chromium(III) ion via the Ndonor atom in the cis positions. The angle $N_{axial}-Cr-N_{axial}$ deviates by 13$^{\circ}$ from the ideal value of 180$^{\circ}$ for a perfect octahedron. The bond angle N-Cr-N between the Cr(III) ion and the two nitrogen atoms of the isothiocyanate ligands is close to 90$^{\circ}$. The bond lengths of Cr-N between the chromium and $NCS^-$groups are 1.964(5) and 2.000(5) $\AA$. They are shorter than those between chromium and nitrogen atoms of the macrocycle. The IR spectra of 1, 2 and 3 display bands at 2073, 1344 and 1684 $cm^{-1}$ attributed to the $NCS^-$, ${N_3}^-$ and caa groups stretching vibrations, respectively.

• 암석학회지
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• 제28권3호
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• pp.217-225
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• 2019

강원도 평창군 뱃재터널의 북쪽 입구 사면에서 대규모 횡와습곡이 확인되어 이를 기재하고 형성기작에 관해 해석하였다. 이 습곡은 고생대 조선누층군 정선석회암층 내에 수백 m 규모로 발달하고 있다. 습곡의 머리는 북쪽을 향하며, 층리와 축면엽리의 복합엽리면상에 발달하는 신장선구조($L_1$)는 남쪽으로 약 $10^{\circ}$ 침강하고 있다. 습곡 날개부에는 S-형 비대칭 습곡과 함께 A-형 또는 안상 칼집습곡들이 흔히 관찰되며 이들 습곡의 축은 습곡의 중앙부와 후면부에서 확인된 신장선구조($L_1$) 방향과 거의 평행하다. 따라서 이곳 대규모 횡와습곡은 상부가 북쪽으로 향하는 강한 연성전단작용에 의해 생성된 칼집습곡으로 고생대말-트라이아스기 송림조산운동의 결과로 해석된다.

• 전기화학회지
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• 제9권1호
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• pp.29-33
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• 2006

A new porous separator based on poly(vinyl chloride) (PVC)/poly(vinylidene fluoride-co-hexafluoro-propylene) (P(VdF-co-HFP)/poly(methyl methacrylate) (PMMA) was prepared by a phase inversion method. To enhance mechanical property, the membrane was stretched uniaxially at high temperature. Tensile strength and ionic conductivity were measured for various draw ratios. The tensile strength and ionic conductivity were increased with increasing draw ratio. The tensile strength of the separator reached 52MPa after stretching to draw ratio of 5, and the ionic conductivity of the separator was increased from $1.9Xs10^{-4}S/cm\;to\;4.6X10^{-4}S/cm\;at\;25^{\circ}C$. The stretched separator immersed in liquid electrolyte was electrochemically stable up to 4.7 V. The cell based on the stretched separator was maintained at about 99% of the initial discharge capacity after 10th cycle operation at 0.2C rate.

• Elastomers and Composites
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• 제42권3호
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• pp.137-142
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• 2007

이축 연신에 의한 폴리테트라플루오로에틸렌 (PTFE) 막을 제조하기 위한 성능평가 실험에서 TGA 및 DSC 측정결과 용융점은 $344.1^{\circ}C$로 비교 시료인 수입산 GE Osmonics PTFE 막과 비슷함을 보였으며 결정화도는 42.5%로 GE Osmonics PTFE 막 보다 조금 높게 나타났다. 기공의 평균크기는 $0.716{\mu}m$였으며, 평균유량은 1,579 LMH로 GE Osmonics 샘플에 비해 다소 높게 나타났다. 제거효율은 30.5%로 비교 시료보다 다소 낮음을 알 수 있었다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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• pp.274.1-274.1
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• 2013

We report the circumferential alignment of human aortic smooth muscle cells (HASMCs) in an orthogonally micropatterned circular microfluidic channel to form an in vivo-like smooth muscle cell layer. To realize a biomimetic smooth muscle cell layer which is aligned perpendicular to the axis of blood vessel, we first fabricated a half-circular polydimethylsiloxane (PDMS) microchannel by soft lithography using a convex PDMS mold. The orthogonally micro wrinkle patterns were generated inside the half-circular microchannel by stretching-releasing operation under UV irradiation. Upon UV treatment with uniaxial 40 % stretch of a PDMS substrate and releasing process, the microwrinkle patterns perpendicular to the axial direction of the circular microchannel were generated, which could guide the circumferential alignment of HASMCs successfully during cultivation. The analysis of orientation angle, shape index, and contractile protein marker expression indicates that the cultured HASMCs revealed the in vivo-like cell phenotype. Finally, we produced circular microchannels by bonding two half-circular microchannels, and cultured the HASMCs circumferentially with high alignment and viability for 5 days. These results are the first demonstration for constructing an in vivo-like 3D smooth muscle cell layer in the circular microfluidic channel which can provide novel bioassay platforms for in-depth study of HASMC biology and vascular function.

• Structural Engineering and Mechanics
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• 제76권4호
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• pp.451-463
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• 2020

In this paper, a new semi-analytical solution for estimating the pull-in parameters of electrically actuated functionally graded (FG) nanobeams is proposed. All the bulk and surface material properties of the FG nanoactuator vary continuously in thickness direction according to power law distribution. Here, the modified couple stress theory (MCST) and Gurtin-Murdoch surface elasticity theory (SET) are jointly employed to capture the size effects of the nanoscale beam in the context of Euler-Bernoulli beam theory. According to the MCST and SET and accounting for the mid-plane stretching, axial residual stress, electrostatic actuation, fringing field, and dispersion (Casimir or/and van der Waals) forces, the nonlinear nonclassical equation of motion and boundary conditions are obtained derived using Hamilton principle. The proposed semi-analytical solution is derived by employing Galerkin method in conjunction with the Particle Swarm Optimization (PSO) method. The proposed solution approach is validated with the available literature. The freestanding behavior of nanoactuators is also investigated. A parametric study is conducted to illustrate the effects of different material and geometrical parameters on the pull-in response of cantilever and doubly-clamped FG nanoactuators. This model and proposed solution are helpful especially in mechanical design of micro/nanoactuators made of FGMs.

• Computers and Concrete
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• 제24권4호
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• pp.347-367
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• 2019

This work investigates the effect of Winkler/Pasternak/Kerr foundation and porosity on dynamic behavior of FG plates using a simple quasi-3D hyperbolic theory. Four different patterns of porosity variations are considered in this study. The used quasi-3D hyperbolic theory is simple and easy to apply because it considers only four-unknown variables to determine the four coupled vibration responses (axial-shear-flexion-stretching). A detailed parametric study is established to evaluate the influences of gradient index, porosity parameter, stiffness of foundation parameters, mode numbers, and geometry on the natural frequencies of imperfect FG plates.

• 암석학회지
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• 제6권3호
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• pp.244-244
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• 1997

북부 소백산육괴의 중남부에 위치하는 장군봉지역(본 연구지역)은 선캠브리아대 변성퇴적암류(원남층과 율리층)와 고생대 변성퇴적암류[조선누층군(장산규암, 두음리층, 장군석회암)과 평안층군(동수곡층과 재산층)] 그리고 중생대 화강암류(춘양화강암) 등으로 구성되어 있다. 본 논문은 장군봉지역에서 북부 소백산육괴의 지질구조를 해석하기위해 구성암류의 암석구조와 미세구조를 연구하였다. 그 결과 연구지역의 지질구조는 선캠브리아대 원남층의 편마면(S0)과 고생대 변성퇴적암류의 층성전단변형 이후에 적어도 네 번의 변형단계(D2 연성전단변형 이전에 한 번의 습곡작용과 D2 연성전단변형 이후에 적어도 두 번의 습곡축(L1)과 동-서 주향에 북쪽으로 고각 경사하는 습곡축면(S1)을 갖는 밀착 등사습곡(tight isoclinal fold) (F1 습곡)을 형성시켰다. 두 번째 변형(D2 변형)은 전단엽리면(S2)의 상부가 동쪽으로 이동한 전단감각(top-to-the east shear sense)을 보이는 우수 주향 이동성 대규모 연성전단운동 발생기로서 이러한 D2 연성전단변형에 의해 신장선구조(L2)가 S2 전단엽리면상에 형성된다. 세 번째 변형(D3 변형)은 도-서 방향의 준 수평적인 습곡축(L3)과 동-서 주향에 북쪽으로 저각 내지 중각 경사하는 습곡축면(S3)을 갖는 열린 경사습곡(open inclined fold) (F3 습곡)을 형성시켰다. 그 결과 원래 북쪽으로 경사하는 S1 엽리면은 F3 습곡의 한쪽 날개부에서 남쪽으로 경사하게 되고, 원래의 D2 전단감각은 재 배열된 남쪽 경사 S1 엽리면상에서 상부가 서쪽으로 이동한 전단감각을 보이게 된다. 네 번째 변형(D4 변형)은 북북서 내지 북서 방향으로 침강하는 습곡축(L4)과 남서 방향으로 경사하는 습곡축면(S4)을 갖는 북동 버전스의 비대칭형 열린 경사습곡(F4 습곡)을 형성시켰다. 그 결과 동-서 방향성을 보이는 D4 변형 이전의 구조요소들은 부분적으로 남-북 방향성으로 재배열된다. 이러한 변형의 효과는 고생대 변성퇴적암류에서 주로 인지된다.

• 대한기계학회논문집B
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• 제35권7호
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• pp.709-715
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• 2011

대칭익형 단면에 미세한 피치각의 차이를 가지는 두 개의 로터 블레이드의 끝에서 발생하는 와류들의 상호 간섭을 관측하기 위하여 2차원 LDV를 활용하여 끝와류의 회전속도 성분과 축방향속도 성분들을 후류시기에 따라서 측정하였다. 선행 블레이드는 끝와류 축방향 성분이 정규분포를 나타내는 상사성을 위배한 반면, 후행 블레이드는 회전속도 성분이 복합와류를 나타내는 Vatistas' n=2 모형의 상사성을 위배하는 것으로 관찰되었다. 또한, 후류시기 200~240도 근방에서 두 끝와류의 궤적이 근접되어 상호 간섭을 나타내는 것으로 밝혀졌으며 이 시기 동안 후행블레이드의 와류이완 현상이 발생하는 것으로 확인이 되었다. 이러한 후류 간섭은 관절형 허브를 가지는 로터에서도 발생될 것으로 예측된다.

• Smart Structures and Systems
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• 제17권1호
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• pp.73-89
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• 2016

The stress dependence of ultrasonic wave velocity is known as the acoustoelastic effect. This effect is useful for stress monitoring if the acoustoelastic coefficient of a subject medium is known. The acoustoelastic coefficients of metallic materials such as steel have been studied widely. However, the acoustoelastic coefficient of concrete has not been well understood yet. Basic constituents of concrete are water, cement, and aggregates. The mix proportion of those constituents greatly affects many mechanical and physical properties of concrete and so does the acoustoelastic coefficient of concrete. In this study, influence of the water-cement ratio (w/c ratio) and the fine-coarse aggregates ratio (fa/ta ratio) on the acoustoelastic coefficient of concrete was investigated. The w/c and the fa/ta ratios are important parameters in mix design and affect wave behaviors in concrete. Load-controlled uni-axial compression tests were performed on concrete specimens. Ultrasonic wave measurements were also performed during the compression tests. The stretching coda wave interferometry method was used to obtain the relative velocity change of ultrasonic waves with respect to the stress level of the specimens. From the experimental results, it was found that the w/c ratio greatly affects the acoustoelastic coefficient while the fa/ta ratio does not. The acoustoelastic coefficient increased from $0.003073MPa^{-1}$ to $0.005553MPa^{-1}$ when the w/c ratio was increased from 0.4 to 0.5. On the other hand, the acoustoelastic coefficient changed in small from $0.003606MPa^{-1}$ to $0.003801MPa^{-1}$ when the fa/ta ratio was increased from 0.3 to 0.5. Finally, it was also found that the relative velocity change has a linear relationship with the stress level of concrete.