• Title/Summary/Keyword: average pore size

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Effect of calcination temperature on mechanical properties of spinel-glass dental composites (하소온도에 따른 인공치관용 스피넬-유리 복합체의 기계적 특성)

  • 이득용;이준강;김대준
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.12 no.5
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    • pp.234-239
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    • 2002
  • The spinel was calcined at temperatures in the range of $1000^{\circ}C$ to $1300^{\circ}C$ with $100^{\circ}C$ interval to evaluate the effect of calcination temperature on mechanical properties of spinel-glass dental composites. Although the average particle size of spinel calcined at temperatures from $1000^{\circ}C$ to $1200^{\circ}C$ was within 2.8~3.0 $\mu\textrm{m}$, the spinel calcined at $1300^{\circ}C$ was 4.66 $\mu\textrm{m}$ due to abnormal grain growth. Shrinkage and pore size of the spinel preform decreased and increased, respectively, as calcination temperature increased, indicating that the calcination temperature was significant to the powder compaction and the densification of the composites as a result of particle size and distribution. The optimum strength and the fracture toughness of the composite calcined at $1200^{\circ}C$ were 284$\pm$40 MPa, 2.5$\pm$0.1 MPaㆍ$m^{1/2}$ respectively. Optical experimental results showed that transmittance of the spinel-glass composite in the visible region was twice higher than that of the alumina-glass composite, suggesting that the spinel-glass composites possessed better aesthetic properties for all-ceramic dental crown application.

Quantitative Evaluation of Geotextile Void Structures Using Digital Image Analysis (디지털 이미지 분석을 이용한 지오텍스타일 공극 분포의 정량화)

  • Kim, Duhwan
    • Journal of the Korean Geosynthetics Society
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    • v.12 no.1
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    • pp.51-61
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    • 2013
  • This paper presents results from a study undertaken to quantitatively evaluate the geotextile pore sizes using optical image analysis. The evaluation was conducted by observing surfaces of coupons cut from resin-impregnated specimens of geotextile-geomembrane layered under various load conditions. Stereological concepts were applied to collect representative specimens from a series of laboratory tests. The sizes of voids enclosed by filaments were expressed in terms of the largest inscribing opening size (LIOS) distribution. The opening diameter corresponding to the 50% cumulative frequency decreased by about 45mm as the load increased from 10 to 300kPa and recovered to about 90% of its initial state on unloading back to 10kPa. The average void size was reduced by 32 and 16.5% as the geotextile was sheared against a textured geomembrane under normal stresses of 100 and 300kPa, respectively. The results showed how the LIOS distribution varied as a function of normal stress and interface shear displacement against a smooth and a textured geomembrane surfaces.

Fabrication and Properties of Reaction Bonded SiC Hot Gas Filter Using Si Melt Infiltration Method (용융 Si 침윤방법에 의한 반응소결 탄화규소 고온가스 필터의 제조 및 특성)

  • 황성식;김태우
    • Journal of the Korean Ceramic Society
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    • v.40 no.9
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    • pp.891-896
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    • 2003
  • Novel fabrication technique was developed for high strength Reaction-Bonded SiC (RBSC) hot gas filter for use in IGCC (Integrated Gasification Combined Cycle) system. The room and high temperature fracture strengths for Si-melt infiltrated reaction-bonded SiC were 50-123, and 60-66 MPa, respectively. The average pore size was 60-70 $\mu\textrm{m}$ and the porosity was about 34 vol%. RBSC infiltrated with molten silicon showed improved fracture strength at high temperature, as compared to that of clay-bonded SiC, due to SiC/Si phase present within SiC phase. The thickness for SiC/Si phase was increased with increasing powder particle size of SiC from 10 to 34 $\mu\textrm{m}$. Pressure drop with dust particles showed similar response as compared to that for Schumacher type 20 filter. The filter fabricated in the present study showed good performance in that the filtered powder size was reduced drastically to below 1 $\mu\textrm{m}$ within 4 min.

Water Treatment Application of a Large Pore Micro-Filtration Membrane and Its Problems (대기공 정밀여과막의 수처리 응용 및 문제점)

  • Yun, Chang-Han;Kim, Jeong-Hak;Lee, Kang Won;Park, Sung Ho
    • Membrane Journal
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    • v.24 no.3
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    • pp.194-200
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    • 2014
  • The purpose of this study was to evaluate the performance of newly developed Large Pore Micro-Filtration (LPMF) membrane in Lab size for the application of water treatment, and to find its problems with solutions. The out-to-inside filtration hollow fiber LPMF membrane of which average pore size was $5{\mu}m$ was used at this study and its material was the PET braid reinforced PVDF. Filtration tests were done through gravity with 30 cm water head difference or pressure below 1.5 bar, and the backwash was done instantaneously with the filtrate after pressurizing it to about 4 bar. The water flux of the LPMF membrane with 0.2 bar TMP (Trans Membrane Pressure) was 2 times higher than $0.4{\mu}m$ MF membrane with $0.05{\mu}m$ UF filtrate of the tap water and it was measured also with 20~30 cm water head difference which showed over 800 LMH at 30 cm water head difference. And Time-To-Filter (TTF) was performed by using $5{\mu}m$ filter paper to optimize coagulants and dosage which enhanced filtrate's turbidity and stabilized filtration flux. When the LPMF was operated with 30 cm gravity with very high dose of inorganic coagulants, the flux was maintained over 80 LMH with 93.5~99.5% turbidity removal. Especially, the filtration was maintained stably in the flux and about 97% of the recovery rate by instantaneous pressurized backwash with about 4 bar of the filtrate when the packing density was about 19%. But there was instability in filtration, since the TMP was continuously going up by inefficient backwash when the packing density was 43%.

Operating Characteristics of a Sintered-Metal Wick/Methanol Loop Heat Pipe Having a Bypass Line (소결금속 윅과 메탄올을 사용하며 바이패스라인이 부착된 루프히트파이프의 작동 특성)

  • Boo, Joon-Hong;Jung, Eui-Guk
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.2130-2135
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    • 2007
  • Operating characteristics of a loop heat pipe (LHP) having a bypass line was investigated experimentally. The LHP had a sintered metal wick as a capillary structure and methanol as a working fluid. The sintered metal wick was made of stainless steel of which the average pore size was 5 ${\mu}m$and porosity of 47%. A bypass line of a small diameter was attached between the vapor escape passage and the liquid reservoir. The dimension of the flat evaporator was $50(L){\times}40(W){\times}30(H)$ mm and that of the condenser was $50(L){\times}40(W){\times}11(H)$ mm. Wall and pipe material of the LHP was stainless steel and heating area was 35(W) mm${\times}$35(L) mm. The inner diameters of vapor and liquid transport lines were 4.0 mm and 2.0 mm, and the lengths of the two lines were both 0.5 m. The LHP was tested for three different tilt angles of horizontal, favorite tilt, and adverse tilt. The thermal load range was up to 290 W at the condenser above evaporation position. Furthermore, the effect of a bypass line on the start-up transient as well as steady-state operation was presented and discussed.

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Biofilter pretreatment for the control of microfiltration membrane fouling

  • Park, Jae-Hyung;Satoshi Takizawa;Hiroyuki Katayama;Shinichiro Ohgaki
    • Proceedings of the Membrane Society of Korea Conference
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    • 2003.05a
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    • pp.31-38
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    • 2003
  • A pilot scale biofilter pretreatment-microfiltration system (BF-MF) was operated to investigate the effect of biofilter treatment in fouling reduction of microfiltration. Biofiltration was expected to reduce the membrane fouling by removal of turbidity and metal oxides. The hollow-fiber MF module with a nominal pore size of 0.1$\mu$m and a surface area of 8m$^2$ was submerged in a filtration tank and microfiltration was operated at a constant flux of 0.5 m/d. Biofiltration using polypropylene pellets was performed at a high filtration velocity of 320 m/d. Two experimental setups composed of MF and BF/MF, i.e., without and with biofilter pretreatment, were compared. Throughout the experimental period of 9 months, biofilter pretreatment was effective to reduce the membrane fouling, which was proved by the result of time variations of trans-membrane pressure and backwash conditions. The turbidity removal rate by biofiltration varied between 40% to 80% due to the periodic washing for biofilter contactor and raw water turbidity. In addition to turbidity, metals, especially Mn, Fe and Al were removed effectively with average removal rates of 89.2%, 67.8% and 64.9%, respectively. Further analysis of foulants on the used membranes revealed that turbidity and metal removal by biofiltration was the major effect of biofiltration pretreatment against microfiltration fouling.

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Behavior of Hepatocytes Inoculated in Gelatin-Immobilized Polyurethane Foam

  • Yang, Kyung-Su;Xinglin Guo;Wan Meng;Hyun, Jae-Yong;Kang, Inn-Kyu;Kim, Yang-Il
    • Macromolecular Research
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    • v.11 no.6
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    • pp.488-494
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    • 2003
  • We have fabricated gelatin-immobilized polyurethane foams (PUFG) by dipping polyurethane foam (PUF) in an aqueous solution containing gelatin and by subsequent reaction with glutaraldehyde after freeze-drying. Gelatin aqueous solutions of different concentrations were used as the dipping solutions to control the amount of immobilized gelatin. The average pore size of PUF decreased with an increase in gelatin concentration. It was found from the hepatocyte adhesion experiment that the amount of hepatocytes seeded on PUFG1, prepared by using a 1% aqueous gelatin solution, was higher than that on other PUFGs. The hepatocytes inoculated in PUFG1, were slightly aggregated as the incubation time increased. The cells inoculated in PUFG1 showed higher ammonia removal ability than those monolayer-cultured on a gelatin-immobilized polystyrene dish (PSG) after 1 and 4 days of incubation time. The inoculated cells exhibited higher albumin secretion relative to monolayer-cultured hepatocytes on PSG. Albumin secretion by hepatocytes seeded on PUFG1 was increased by the presence of serum and was further increased by both the presence of serum and cytokines. The results obtained from a 3-(3,4-dimethylthiazol-2yl)-2,5-diphenyltetrazolium bromide (MTT) assay indicated that PUFG can provide a better microenvironment for hepatocyte culture along with nutrition and metabolite transfer through the high porosity of PUF.

A Study on the Sound Absorption Properties of Foamed Concrete According to Dilution Ratio of Foaming Agent (기포제 희석비율에 따른 기포콘크리트의 흡음특성에 관한 연구)

  • Kang Ki-Woong;Kang Chul;Kim Ha-Seok;Kwag Eun-Gu;Kwon Ki-Joo;Kim Jin-Man
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2005.05a
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    • pp.5-8
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    • 2005
  • Sound absorbing performance is affected by porosity and continuity of void, therefore it is important to maintain stabilization of foam and to analyze properties of void pore in hardened state. The purpose of this study is to analyze the sound absorption properties and void characteristic of foamed concrete according to dilution ratio of foaming agent. The results of this experiment were as follows. It is determined that an increase in total and continuous void ratio is achieved by increasing of dilution ratio, and a shorter absorbing time was exhibited at a higher continuous void ratio. When the average void size of foamed concrete was below 1.5mm, the tendency of sound absorption coefficient compared with general sound absorber was appeared similarly.

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The Synthesis and Characterization of Mesoporous Microbead Incorporated with CdSe/ZnS QDs (양자점이 고밀도화된 마이크로 비드의 제조 및 특성)

  • Lee, Ji-Hye;Hyun, Sang-Il;Lee, Jong-Huen;Koo, Eun-Hae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.8
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    • pp.657-663
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    • 2012
  • The spherical mesoporous silica is synthesized and incorporated with CdSe/ZnS quantum dots(QDs) for preparing micro beads to detect toxic and bio-materials with high sensitivity. The spherical silica beads with the brunauer-emmett-telle(BET) average pore size of 15 nm were prepared with a ratio 1, 3, 5-trimethylbenzen, as a swelling agent, to the block-copolymer template surfactant of over 1 and under vigorous mixing condition. The surface of spherical mesoporous silica is modified using octadecylsilane for incorporating QDs. Based on photoluminescence(PL) spectra, the relative brightness of mesoporous silica beads incorporated with 10 nM of QDs is 79,000 times brighter than that of Rodamine 6 G.

Effect of $B_{2}O_{3}$ addition on mechanical strength and microstructure of a porous $LiAlO_{2}$ electrolyte support for molten carbonate fuel cells (용융 탄산염 연료전지용 gamma $LiAlO_{2}$ 전해질 지지체의 미세구조 및 기계적 강도 변화에 대한 $B_{2}O_{3}$ 첨가의 영향)

  • Ham, Hyung-Chul;Yoon, Sung-Pil;Hong, Seong-Ah
    • New & Renewable Energy
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    • v.3 no.1 s.9
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    • pp.54-59
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    • 2007
  • A sintering aid, $B_{2}O_{3}$ have been included into a $LiAlO_{2}$ electrolyte support by a tape casting method in order to reinforce mechanical strength of the support for molten carbonate fuel cells [MCFCs). Starting idea originates from the low melting point of $B_{2}O_{3}$ ($450^{\circ}C$), which can provide the low temperature consolidation of ceramic materials. The mechanical properties and the microstructure changes of the $B_{2}O_{3}$-included electrolyte support were examined by scanning electron microscope, mercury porosimetry, X-ray powder diffraction [XRD], high temperature differential scanning calorimeter and three-point bending strength measurement. The mechanical strength was clearly improved by addition of $B_{2}O_{3}$. The increase of mechanical strength results from the neck growth of a new $LiAlO_{2}$ phase between $LiAlO_{2}$ particles by the liquid phase sintering. Average pore size and porosity of the electrolyte support reinforced by addition of the sintering aid, $B_{2}O_{3}$, was $0.24{\mu}m$ and 59%, respectively which were suitable microstructure of a matrix for an application of MCFCs.

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