• Title/Summary/Keyword: auto ignition temperatures

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Appropriateness of MSDS by Means of the Measurement of Combustible Properties of Anisole (아니솔의 연소특성치의 측정에 의한 MSDS의 적정성)

  • Ha, Dong-Myeong
    • Fire Science and Engineering
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    • v.29 no.2
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    • pp.20-24
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    • 2015
  • For the safe handling of anisole, this study was investigated the explosion limits of anisole in the reference data. The flash points and auto-ignition temperatures (AITs) by ignition delay time were experimented. The lower flash points of Anisole by using closed-cup tester were experimented in $39^{\circ}C$ and $42^{\circ}C$. The lower flash points of Anisole by using open cup tester were experimented in $50^{\circ}C$ and $54^{\circ}C$. This study measured relationship between the AITs and the ignition delay times by using ASTM E659 tester for Anisole. The AIT of Anisole was experimented as $390^{\circ}C$. The lower explosion limit (LEL) by the measured the lower flash point for Anisole were calculated as 1.07 Vol%.

The Measurement of Combustible Properties of Cyclohexanol (사이클로헥산올의 연소특성치의 측정)

  • Ha, Dong-Myeong
    • Fire Science and Engineering
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    • v.28 no.2
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    • pp.64-68
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    • 2014
  • For the safe handling of cyclohexanol, this study was investigated the explosion limits of cyclohexanol in the reference data. The flash points and auto-ignition temperatures (AITs) by ignition delay time were experimented. The lower flash points of cyclohexanol by using closed-cup tester were experimented in$60^{\circ}C{\sim}64^{\circ}C$. The lower flash points of cyclohexanol by using open cup tester were experimented in $66^{\circ}C{\sim}68^{\circ}C$. This study measured relationship between the AITs and the ignition delay times by using ASTM E659 tester for cyclohexanol. The AIT of cyclohexanol was experimented as $297^{\circ}C$. The lower explosion limit (LEL) and the upper explosion limit UEL) by the measured the lower flash point and the upper flash point of cyclohexanol were calculated as 0.95 Vol% and 10.7 Vol%, respectively.

The Measurement of Fire and Explosion Properties of n-Hexadecane (노말헥사데칸의 화재 및 폭발 특성치의 측정)

  • Ha, Dong-Myeong
    • Journal of the Korean Society of Safety
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    • v.29 no.3
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    • pp.39-45
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    • 2014
  • For the safe handling of n-hexadecane, the lower flash points and the upper flash point, fire point, AITs(auto-ignition temperatures) by ignition delay time were experimented. Also lower and upper explosion limits by using measured the lower and upper flash points for n-hexadecane were calculated. The lower flash points of n-hexadecane by using the Setaflash and the Pensky-Martens closed testers were measured $128^{\circ}C$ and $126^{\circ}C$, respectively. The lower flash points of the Tag and the Cleveland open cup testers were measured $136^{\circ}C$ and $132^{\circ}C$, respectively. The fire points of the Tag and the Cleveland open cup testers were measured $144^{\circ}C$. respectively. This study measured relationship between the AITs and the ignition delay times by using ASTM E659 apparatus for n-hexadecane. The experimental AIT of n-hexadecane was $200^{\circ}C$. The calculated lower and upper explosion limit by using measured lower $128^{\circ}C$ and upper flash point $180^{\circ}C$ for n-hexadecane were 0.42 Vol.% and 4.70 Vol.%.

Measurement and Prediction of Combustion Properties of Styrene (스티렌의 연소특성치 측정 및 예측)

  • Ha, Dong-Myeong;Na, Byeong-Gyun
    • Journal of the Korean Institute of Gas
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    • v.17 no.4
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    • pp.70-76
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    • 2013
  • For the safe handling of styrene, this study was investigated the explosion limits of styrene in the reference data. The flash points and AITs(auto-ignition temperatures) by ignition delay time were experimented. As a results, the lower and upper explosion limits of styrene recommended 0.9 Vol.% and 8.0 Vol.%, respectively. The lower flash points of styrene by using closed-cup tester were experimented $29^{\circ}C{\sim}31^{\circ}C$. The lower flash points of styrene by using open cup tester were experimented $32^{\circ}C{\sim}36^{\circ}C$. This study measured relationship between the AITs and the ignition delay times by using ASTM E659 tester for styrene. The experimental AIT of styrene was $460^{\circ}C$.

A Study on the Reliability of the Combustible Properties for Acrylic Acid (아크릴릭산의 연소특성치의 신뢰성 연구)

  • Ha, Dong-Myeong
    • Journal of Energy Engineering
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    • v.24 no.3
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    • pp.20-26
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    • 2015
  • For the reliability of the combustible properties of arylic acid, this study was investigated the explosion limits of acrylic acid in the reference data. The flash points and AITs(auto-ignition temperatures) by ignition delay time were experimented. The lower flash points of acrylic acid by using Setaflash and Pensky-Martens closed-cup testers were experimented in $48^{\circ}C$ and $51^{\circ}C$, respectively. The lower flash points of arylic acid by using Tag and Cleveland open cup testers were experimented in $56^{\circ}C$. This study measured relationship between the AITs and the ignition delay times by using ASTM E659 tester for acrylic acid. The AIT of acrylic acid was experimented as $417^{\circ}C$. The lower explosion limit(LEL) and the upper explosion limit(UEL) by the measured the lower flash point and the upper flash point of acrylic acid were calculated as 2.2 Vol% and 7.9 Vol%, respectively.

Validating Timing of Vehicle Automatic Shut-off and Study on Appropriate Shut-off Timing (자동 Shut-off 시간 적정성 검증 방법 및 최적 시간 설정 방안 연구)

  • Yang, Dong Il;Choi, Byeong Nam;Park, Ji Woon;Yu, Min Sang;Beema, Stephanie
    • Journal of Auto-vehicle Safety Association
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    • v.13 no.2
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    • pp.15-23
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    • 2021
  • Even though the number of CO poisoning casualties caused by unintended idling for the vehicles equipped with keyless ignition systems is more than 70, the problem still remains unsolved and became social issue in the US, and Senates introduced the bill which urges NHSTA to make regulation for this accordingly. To meet market safety needs and the regulations, we decided to provide automatic shut-off system very soon. In this paper, we would like to describe how to validate vehicle shut-off timing including defining required tests and case selections considering vehicle condition, garage/room size and temperatures with several assumptions. We believe that safe implementation of the shut-off function is possible via this methodology and the results. As NHTSA must be interested in shut-off timing, the methodology can be enhanced and conclusions could be reflected highly in the future regulation in case we continue this study with NHTSA or any other 3-rd party institutes.

Characteristics of Auto-ignition for Trichlorosliane and Dichlorosilane-Trichlorosliane Mixtures (Trichlorosliane 및 Dichlorosilane-Trichlorosliane 혼합물의 자연발화 특성)

  • Ha, Dong-Myeong
    • Journal of the Korean Institute of Gas
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    • v.14 no.4
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    • pp.24-30
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    • 2010
  • An accurate information of the autoignition temperature(AIT) is important in developing appropriate prevention and control measures in industrial fire. This study measured the AITs of trichlorosliane and dichlosilane(DCS)-trichlorosliane(TCS) mixtures by using ASTM E659-78 apparatus. The experiment AITs of trichlorosliane, TCS(90wt%)-DCS(10wt%) and the TCS(70wt%)-DCS(30wt%) were $225^{\circ}C,\;250^{\circ}C\;and\;236^{\circ}C$, respectively.

The Measurement of Combustible Characteristics of n-Undecane (노말언데칸의 연소특성치의 측정)

  • Ha, Dong-Myeong
    • Fire Science and Engineering
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    • v.27 no.2
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    • pp.11-17
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    • 2013
  • For the safe handling of n-undecane, the lower flash points and the upper flash point, fire point, AITs (auto-ignition temperatures) by ignition delay time were experimented. Also lower and upper explosion limits by using measured the lower and upper flash points for n-undecane were calculated. The lower flash points of n-undecane by using closed-cup tester were measured $59^{\circ}C$ and $67^{\circ}C$. The lower flash points of n-undecane by using open cup tester were measured $67^{\circ}C$ and $72^{\circ}C$, respectively. The fire point of n-undecane by using Cleveland open cup tester was measured $74^{\circ}C$. This study measured relationship between the AITs and the ignition delay times by using ASTM E659 apparatus for n-undecane. The experimental AIT of n-undecane was $198^{\circ}C$. The estimated lower and upper explosion limit by using measured lower flash point $59^{\circ}C$ and upper flash point $83^{\circ}C$ for n-undecane were 0.65 Vol.% and 2.12 Vol.%.

The Study on the Compatibility of MSDS by Means of Measurement of Combustible Properties for Isobutylalcohol(IBA) (이소부틸알코올(IBA)의 연소특성치 측정에 의한 MSDS의 적정성 연구)

  • Ha, Dong-Myeong
    • Journal of the Korean Institute of Gas
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    • v.18 no.3
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    • pp.75-81
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    • 2014
  • For the safe handling of isobutylalcohol(IBA), this study was investigated the explosion limits of isobutylalcohol in the reference data. And the lower flash points, upper flash points and AITs(auto-ignition temperatures) by ignition delay time were experimented. By using the literatures data, the lower and upper explosion limits of isobutylalcohol recommended 1.7 Vol% and 10.9 Vol.%, respectively. The lower flash point of isobutylalcohol by using Setaflash and Penski-Martens closed-cup testers were experimented $25^{\circ}C$ and $30^{\circ}C$, respectively. The lower flash point isobutylalcohol by using Tag and Cleveland open cup testers were experimented $36^{\circ}C$ and $39^{\circ}C$, respectively. Also, this study measured relationship between the AITs and the ignition delay times by using ASTM E659 tester for isobutylalcohol. The experimental AIT of isobutylalcohol was $400^{\circ}C$.

Measurement and Investigation of Combustible Properties of n-Heptane for Risk Assessment of Gasoline Tank (가솔린탱크의 위험성평가를 위한 노말헵탄의 연소특성치 측정 및 고찰)

  • Ha, Dong-Myeong;Jeong, Kee-Sin;Lee, Sung-Jin;Cho, Yong-Sun;Yoon, Myung-O
    • Fire Science and Engineering
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    • v.24 no.6
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    • pp.76-81
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    • 2010
  • For the safe handling of n-heptane, the explosion limit at $25^{\circ}C$, the temperature dependence of the explosion limits and the lower flash point were investigated. And AITs (auto-ignition temperatures) by ignition time delay for n-heptane were experimented. By using the literatures data, the lower and upper explosion limits of n-heptane recommended 1.0 Vol% and 7.0 Vol%, respectively. And the lower flash points of n-heptane recommended $-4^{\circ}C$. This study measured relationship between the AITs and the ignition delay times by using ASTM E659-78 apparatus for n-heptane and the experimental AIT of n-hexane was $225^{\circ}C$. The new equation for predicting the temperature dependence of the explosion limits of n-heptane is proposed. The values calculated by the proposed equations were a good agreement with the literature data.