• Title/Summary/Keyword: atomic ratio

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Atomic Layer Deposition-incorporated Catalyst Deposition for the Vertical Integration of Carbon Nanotubes

  • Jung, Sung-Hwan
    • Journal of Electrical Engineering and Technology
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    • v.6 no.5
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    • pp.688-692
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    • 2011
  • Carbon nanotubes (CNTs) are vertically grown inside high-aspect-ratio vertical pores of anodized aluminum oxide. A CNT catalyst layer is introduced by atomic layer deposition to the bottom of the pores, after which the CNTs are successfully grown from the layer using chemical vapor deposition. The CNTs formed a complete vertical conductive path. The conductivity of the CNT-vertical path is also measured and discussed. The present atomic layer deposition-incorporated catalyst deposition is predicted to enable the integration of CNTs with various challenging configurations, including high-aspect-ratio vertical channels or vertical interconnects.

Initial Performance Degradation of Hydrogen-Fueled Ceramic Fuel Cell with Plasma-Enhanced Atomic Layer-Deposited Ultra-Thin Electrolyte (플라즈마 원자층증착 초박막전해질 수소 세라믹연료전지의 초기성능 저하)

  • JI, SANGHOON
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.5
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    • pp.340-346
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    • 2021
  • The initial electrochemical performance of ceramic fuel cell with thin-film electrolyte fabricated by plasma-enhanced atomic layer deposition method was evaluated in terms of peak power density ratio, open circuit voltage ratio, and activation/ohmic resistance ratios at 500℃. Hydrogen and air were used as anode fuel and cathode fuel, respectively. The peak power density ratio reduced as ~52% for 30 min, which continually decreased as time increased but degradation rate gradually decreased. The open circuit voltage ratio decreased with respect time; however, its behavior was evidently different from the reduction behavior of the peak power density. The activation resistance ratio increased as ~127% for 30 min, which was almost similar with the reduction behavior of the peak power density ratio.

Measurement of Aerosol Parameters with Altitude by Using Two Wavelength Rotational Raman Signals

  • Song, Im-Kang;Kim, Yong-Gi;Baik, Sung-Hoon;Park, Seung-Kyu;Cha, Hyung-Ki;Choi, Sung-Chul;Chung, Chin-Man;Kim, Duk-Hyeon
    • Journal of the Optical Society of Korea
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    • v.14 no.3
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    • pp.221-227
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    • 2010
  • Aerosol size distribution provides good information for predicting weather changes and understanding cloud formation. Aerosol extinction coefficient and backscattering coefficient are measured by many scientists, but these parameters depend not only on aerosol size but on aerosol concentrations. An algorithm has been developed to measure aerosol parameters such as ${\AA}$ngstr$\ddot{o}$m exponent, color ratio, and LIDAR ratio without any assumptions by using two wavelength rotational Raman LIDAR signals. These parameters are good indicators for the aerosol size. And we can find ${\AA}$ngstr$\ddot{o}$m exponent, color ratio, and LIDAR ratio under various weather conditions. Finally, it can be seen that the ${\AA}$ngstr$\ddot{o}$m exponent has an inverse relationship to the particle size of the aerosol and the color ratio is linearly dependent on the aerosol size. An ${\AA}$ngstr$\ddot{o}$m exponent from 1.2 to 3.1, a color ratio from 0.28 to 1.04, and a LIDAR ratio 66.9 sr at 355 nm and 32.6 sr at 532 nm near the cloud were obtained.

Effect of Ni/Fe Ion Concentration Ratio on Fuel Cladding Crud Deposition (핵연료 피복관 부식생성물 부착에 관한 Ni/Fe 이온 농도비의 영향)

  • Baek, S.H.;Kim, U.C.;Shim, H.S.;Lim, K.S.;Hur, D.H.
    • Corrosion Science and Technology
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    • v.13 no.4
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    • pp.145-151
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    • 2014
  • The objectives of this study are to investigate the effect of the concentration ratios of Ni and Fe ions on crud deposition onto the fuel cladding surface in the simulated primary environments of a pressurized water reactor. Crud deposition tests were conducted in the Ni and Fe concentration ratios of 20:20 ppm, 39:1 ppm and 1:39 ppm at $325^{\circ}C$ for 14 days. In the case of the same Ni and Fe ion ratio (20:20), nickel ferrite with a polyhedral shape was formed. Nickel oxide deposits with a needle shape were formed in the condition of high Ni to Fe ion ratio (39:1), While polyhedral iron oxide and needle-like nickel oxide formed in the condition of low Ni to Fe ion ratio (1:39). The amount of deposits increased, when Fe oxides were formed. This indicates that Fe rich oxides stimulated Ni oxide deposition.

Feasibility Study of Isotope Ratio Analysis of Individual Uranium-Plutonium Mixed Oxide Particles with SIMS and ICP-MS

  • Esaka, Fumitaka;Magara, Masaaki;Suzuki, Daisuke;Miyamoto, Yutaka;Lee, Chi-Gyu;Kimura, Takaumi
    • Mass Spectrometry Letters
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    • v.2 no.4
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    • pp.80-83
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    • 2011
  • Isotope ratio analysis of nuclear materials in individual particles is of great importance for nuclear safeguards. Although secondary ion mass spectrometry (SIMS) and thermal ionization mass spectrometry (TIMS) are utilized for the analysis of individual uranium particles, few studies were conducted for the analysis of individual uranium-plutonium mixed oxide particles. In this study, we applied SIMS and inductively coupled plasma mass spectrometry (ICP-MS) to the isotope ratio analysis of individual U-Pu mixed oxide particles. In the analysis of individual U-Pu particles prepared from mixed solution of uranium and plutonium standard reference materials, accurate $^{235}U/^{238}U$, $^{240}Pu/^{239}Pu$ and $^{242}Pu/^{239}Pu$ isotope ratios were obtained with both methods. However, accurate analysis of $^{241}Pu/^{239}Pu$ isotope ratio was impossible, due to the interference of the $^{241}Am$ peak to the $^{241}Pu$ peak. In addition, it was indicated that the interference of the $^{238}UH$ peak to the $^{239}Pu$ peak has a possibility to prevent accurate analysis of plutonium isotope ratios. These problems would be avoided by a combination of ICP-MS and chemical separation of uranium, plutonium and americium in individual U-Pu particles.

Non-Destructive Detection of Hydride Blister in PHWR Pressure Tube Using an Ultrasonic Velocity Ratio Method

  • Cheong Yong-Moo;Lee Dong-Hoon;Kim Sang-Jae;Kim Young-Suk
    • Nuclear Engineering and Technology
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    • v.35 no.5
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    • pp.369-377
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    • 2003
  • Since Zr-2.5Nb pressure tubes have a high risk for the formation of blisters during their operation in pressurized heavy water reactors, there has been a strong incentive to develop a method for the non-destructive detection of blisters grown on the tube surfaces. However, because there is little mismatch in acoustic impedance between the hydride blisters and zirconium matrix, it is not easy to distinguish the boundary between the blister and zirconium matrix with conventional ultrasonic methods. This study has focused on the development of a special ultrasonic method, so called ultrasonic velocity ratio method for a reliable detection of blisters formed on Zr-2.5Nb pressure tubes. Hydride blisters were grown on the outer surface of the Zr-2.5Nb pressure tube using a cold finger attached to a steady state thermal diffusion equipment. To maximize a difference in the ultrasonic velocity in hydride blisters and the zirconium matrix, the ultrasonic velocity ratio of longitudinal wave to shear wave, $V_L/V_S$, has been determined based on the flight time of the longitudinal echo and reflected shear echo from the outer surface of the tubes. The feasibility of the ultrasonic velocity ratio method is confirmed by comparing the contour plots reproduced by this method with those of the blisters grown on the Zr-2.5Nb pressure tubes.

Microstructure and Mechanical Properties of TiC-Ni/Al Composites by the Reaction-Bonding Method (반응결합법에 의한 TiC-Ni/Al 복합체의 미세구조 및 기계적 특성)

  • 한인섭;우상국;김흥수;양준환;정윤중
    • Journal of the Korean Ceramic Society
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    • v.33 no.5
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    • pp.536-546
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    • 1996
  • The TiC-Ni/Al reaction-bonding composites were prepared by the infiltration of Ni/Al melt into the TiC preforms. The microstructure the reaction composition crystalline phase and the mechanical properties of the composites were investigated. During the reaction-bonding Ni/Al mixture had a good wettability and per-meability with TiC preform and pore-free and fully dense sintered bodies were produced. In the case of the Ni/Al atomic ratio of 0.3 and 0.5 TiC raw particle shape was changed to irregular particles because of the decomposition in the liquid matrix and its phenomena was more distinguished in the Al-rich liquid matrix. With increasing more than 1 of the Ni/Al atomic ratio the sample of TiC grain shape was changed from spherical to palatelet particles. Also with increasing the atomic ratio of Ni/Al bending strength and fracture spherical to palatelet particles. Also with increasing the atomic ratio of Ni/Al bending strength and fracture toughness were increased and its maximum value was 1073 MPa and 11 MPa.m1/2 respectively.

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