• Title/Summary/Keyword: atomic ratio

Search Result 1,009, Processing Time 0.033 seconds

Evaluation of cementation of intermediate level liquid waste produced from fission 99Mo production process and disposal feasibility of cement waste form

  • Shon, Jong-Sik;Lee, Hyun-Kyu;Kim, Tack-Jin;Kim, Gi-Yong;Jeon, Hongrae
    • Nuclear Engineering and Technology
    • /
    • v.54 no.9
    • /
    • pp.3235-3241
    • /
    • 2022
  • The Korea Atomic Energy Research Institute (KAERI) is planning the construction of the KIJANG Research Reactor (KJRR) for stable supply of 99Mo. The Fission 99Mo Production Process (FMPP) of KJRR produces solid waste such as spent uranium cake and alumina cake, and liquid waste in the form of intermediate level liquid waste (ILLW) and low level liquid waste (LLLW). This study thus established the operating range and optimum operating conditions for the cementation of ILLW from FMPP. It also evaluated whether cement waste form samples produced under optimum operational conditions satisfy the waste acceptance criteria (WAC) of a disposal facility in Korea (Korea radioactive waste agency, KORAD). Considering economic feasibility and safety, optimum operational conditions were achieved at a w/c ratio of 0.55, and the corresponding salt content was 5.71 wt%. The cement waste form samples prepared under optimum operational conditions were found to satisfy KORAD's WAC when tested for structural stability and leachability. The results indicate that the proposed cementation conditions for the disposal of ILLW from FMMP can be effectively applied to KJRR's disposal facility.

Development of thermal conductivity model with use of a thermal resistance circuit for metallic UO2 microcell nuclear fuel pellets

  • Heung Soo Lee;Dong Seok Kim;Dong-Joo Kim;Jae Ho Yang;Ji-Hae Yoon;Ji Hwan Lee
    • Nuclear Engineering and Technology
    • /
    • v.55 no.10
    • /
    • pp.3860-3865
    • /
    • 2023
  • A metallic microcell UO2 pellet has a microstructure where a metal wall is connected to overcome the low thermal conductivity of the UO2 fuel pellet. It has been verified that metallic microcell fuel pellets provide an impressive reduction of the fuel centerline temperature through a Halden irradiation test. However, it is difficult to predict the effective thermal conductivity of these pellets and researchers have had to rely on measurement and use of the finite element method. In this study, we designed a unit microcell model using a thermal resistance circuit to calculate the effective thermal conductivity on the basis of the microstructure characteristics by using the aspect ratio and compared the results with those of reported metallic UO2 microcell pellets. In particular, using the thermal conductivity calculated by our model, the fuel centerline temperature of Cr microcell pellets on the 5th day of the Halden irradiation test was predicted within 6% error from the measured value.

A FLOW AND PRESSURE DISTRIBUTION OF APR+ REACTOR UNDER THE 4-PUMP RUNNING CONDITIONS WITH A BALANCED FLOW RATE

  • Euh, D.J.;Kim, K.H.;Youn, Y.J.;Bae, J.H.;Chu, I.C.;Kim, J.T.;Kang, H.S.;Choi, H.S.;Lee, S.T.;Kwon, T.S.
    • Nuclear Engineering and Technology
    • /
    • v.44 no.7
    • /
    • pp.735-744
    • /
    • 2012
  • In order to quantify the flow distribution characteristics of APR+ reactor, a test was performed on a test facility, ACOP ($\underline{A}$PR+ $\underline{C}$ore Flow & $\underline{P}$ressure Test Facility), having a length scale of 1/5 referring to the prototype plant. The major parameters are core inlet flow and outlet pressure distribution and sectional pressure drops along the major flow path inside reactor vessel. To preserve the flow characteristics of prototype plant, the test facility was designed based on a preservation of major flow path geometry. An Euler number is considered as primary dimensionless parameter, which is conserved with a 1/40.9 of Reynolds number scaling ratio. ACOP simplifies each fuel assembly into a hydraulic simulator having the same axial flow resistance and lateral cross flow characteristics. In order to supply boundary condition to estimate thermal margins of the reactor, the distribution of inlet core flow and core exit pressure were measured in each of 257 fuel assembly simulators. In total, 584 points of static pressure and differential pressures were measured with a limited number of differential pressure transmitters by developing a sequential operation system of valves. In the current study, reactor flow characteristics under the balanced four-cold leg flow conditions at each of the cold legs were quantified, which is a part of the test matrix composing the APR+ flow distribution test program. The final identification of the reactor flow distribution was obtained by ensemble averaging 15 independent test data. The details of the design of the test facility, experiment, and data analysis are included in the current paper.

Variation of Characteristics on the Surface of Pyrite as Microbial Leaching by Thiobacillus ferrooxidans Progresses (Thiobacillus ferrooxidans에 의한 Pyrite의 생물학적 침출에 따른 기질 표면 특성변화)

  • 이인화;박천영
    • KSBB Journal
    • /
    • v.16 no.3
    • /
    • pp.295-301
    • /
    • 2001
  • The leaching effect of Thiobacillus ferrooxidance (ATCC 19859) upon polished pyrite ore in 9K medium at $30^{circ}C$ for 30 days was investigated. The surface atomic ratios for Fe, S, Al, Si, and Cu were analyzed by EPMA using fresh and leached samples. The atomic ratio of Fe and S were changed to Fe rich phase as leaching progressed over 13 days but the Fe/S ratio became constant between 13 and 30 days. SEM imaging showed that $10\mum$ oblong shapes formed on the surface after 13 days and that these further developed until 23 days. Fe, S and K atomic ratios were analyzed by SEM-EDS.

  • PDF

Liquid Crystalline Polymer for the Alignment of Ferroelectric Liquid Crystal Display (강유전정 액정 디스플레이의 배향을 위한 액정성 고분자)

  • Jin, Sung-Ho;Jeon, Young-Jae;Lee, Jong-Chun;Kim, Gang
    • Korean Journal of Materials Research
    • /
    • v.10 no.5
    • /
    • pp.350-353
    • /
    • 2000
  • Thermotropic liquid crystalline polymer(LCP) has been used for the alignment of ferroelectric liquid crystal (FLC) molecules and the surface morphology of the resulting polymeric thin film has been observed by atomic forced microscope. The uniform alignment of FLC molecules on the surface of thermotropic LCP thin film was obtained even though microgroove structures were not formed. The contrast ratio of sample cell was about 23:1 including two polarizers and a good memory capability due to the bistability of FLC was obtained. After AC field stabilization at 20V, the typical stripe-shaped patterns appeared.

  • PDF

Transmutation of Am-241, 243 and Cm-244 in a Conventional Pressurized Water Reactor

  • Koh, Duck-Joon;Lee, Myung-Chan;Jeong, Woo-Tae;Boris P. Kochurov
    • Proceedings of the Korean Nuclear Society Conference
    • /
    • 1996.05c
    • /
    • pp.423-428
    • /
    • 1996
  • The feasibility study on burning Am-241, 243 and Cm-244 nuclides in a conventional PWR (Pressurized Water Reactor) was carried out by using the TRIFON code that was developed by the Institute of Theoretical and Experimental Physics in Russia in 1992. TRIFON code uses updated ABBN Russian nuclear cross section library. The reference reactor is the Korea nuclear power plant unit 8 (YGN 2). The burning effect of Am-241, 243 and Cm-244 nuclides was studied with UO$_2$(3.5 w/o)fuel assembly and MOX (4.44 w/o) fuel assembly. The loaded mass ratio of Am-241, 243 and Cm-244 nuclides was obtained from the mass ratio of Am-241, 243 and Cm-244 nuclides in 10 year cooling spent fuel with average discharge burnup of 33 GWD/MTU. The effective transmutation rates of Am-241, 243 and Cm-244 nuclides in UO$_2$ fuel assembly were found to be higher than those in MOX fuel assembly. The result from TRIFON code was compared to that from CASMO-3/NEM-3D code system. For more reliable calculation of transmutation for MA(Minor Actinides) more sophisticated decay chain scheme of MA should be investigated and nuclear cross section library of MA should be considerably improved.

  • PDF

A Comparative Study on the Evaluation of the Wear Resistance in Zr-xNb-xSn Alloys

  • Lee, Young-Ho;Kim, Hyung-Kyu;Jung, Youn-Ho
    • KSTLE International Journal
    • /
    • v.4 no.2
    • /
    • pp.47-51
    • /
    • 2003
  • Sliding wear tests have been carried out in room temperature air and water in order to compare the wear resistance of Zr-xNb-xSn alloys of various alloying elements (Nb and Sn). The main focus was to quantitatively compare the wear properties of the recently developed Zr-xNb-xSn alloys with the commercial ones using the evaluation parameters of the wear resistance with the consideration of the worn area. As a result, the recently developed alloys had a similar wear resistance compared with the commercial ones. The dominant factor governing the wear resistance was the protruded volume of the wear debris that was formed on the worn area in the air condition, but the accommodation of the plastic deformation on the contact area in water. In addition, the worn area size appeared to be very different depending on the tested alloys. To evaluate the wear resistance of each test specimen, the ratio of the wear volume or the protruded volume to the worn area ($D_e$ or $D_p$) is investigated and proposed as the evaluation parameters of the wear resistance.

The Importance of Nitrogen Release and Denitrification in Sediment to the Nitrogen Budget in Hiroshima Bay

  • KIM Do-Hee;MATSUDA Osamu
    • Korean Journal of Fisheries and Aquatic Sciences
    • /
    • v.29 no.6
    • /
    • pp.779-786
    • /
    • 1996
  • The main purpose of this study was to estimate the role of dissolved inorganic nitrogen (DIN) released from sediment and denitrification process in sediment on the nitrogen budget of Hiroshima Bay by means of collecting data on distributions and budgets of nitrogen and phosphorus in the bay, DIN fluxes across sediment-water interface and denitrification rates in the sediments of the same area. The TN : TP and DIN:DIP atomic ratios of the discharged freshwater were about 26 and 21, respectively. The standing stocks in the seawater of the TN : TP atomic ratio varied from 8 to 14 with an annual mean value of 11, while the DIN : DIP atomic ratio varied from 10 to 15 with an annual mean value of 12 in the bay. The residence time of nitrogen and phosphorus were estimated to be about 109 days and 200 days in the bay, respectively. The proportion of DIN released from sediment and denitrification rate to the loading of total nitrogen into Hiroshima Bay were $45\%\;(37\~82\%)\;and\;13\%(0.0\~37\%)$, respectively, and the amount of nitrogen through denitrification process was 6.5 times larger than the outflow of nitrogen from the bay. The results show that DIN released from sediment and denitrification process in sediment play important roles on the nitrogen budget in Hiroshima Bay.

  • PDF

Studies on the Wholesomeness of Gamma-irradiated Rice -(II) On the Weight Gain, Reproduction Ratio, Mortality and Growth Rate after Weaning of Mice- (방사선 조사미(照射米)의 안전성(安全性) 연구 -제2보 시험동물의 증체량(增體量), 번식률(繁殖率), 사망율(死亡率) 및 이유시(離乳時) 생육상태(生育狀態)-)

  • Kim, Sung-Kih;Lee, Kwan-Young;Lee, Su-Rae
    • Korean Journal of Food Science and Technology
    • /
    • v.5 no.3
    • /
    • pp.149-152
    • /
    • 1973
  • As the third-year experiment on the wholesomeness of irradiated rice with 50 and 100 krad gamma-rays, a feeding test was undertaken with mice of $F_2-generation$ which were used in the preceding year. No significant difference was observed between the irradiated group and control group with respect to gain of body weight, reproductive ratio, mortality and average body weight of weaning mice.

  • PDF

Preparation of Radioiodine Labelled Human Follicle Stimulating Hormone for Radioimmunoassay Use

  • Kim, Jae-Rok;Kim, Tae-Ho;Kim, You-Sun
    • The Korean Journal of Nuclear Medicine
    • /
    • v.11 no.1
    • /
    • pp.9-15
    • /
    • 1977
  • Radioiodine labelled human follicle stimulating hormone has been prepared using chloramine-T, with the approximate labelling yield of 65%. The labelled product is purified by means of a starch gel electrophoresis, and a Sephadex gel filtration, and the separation efficiencies are assessed for the effective use in radioimmunoassay. The results indicate that the gel filtration is efficient in view of the separation time, simplicity and bindability of the labelled hormone to the antibody. In determining the ratio of the free to the antibody hound labelled hormone, a double antibody technique is applied in comparison with a chromatoelectrophoresis. The ratio could be obtained only in the case of applying the double antibody technique.

  • PDF