• Title/Summary/Keyword: atomic ordering

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Hydrothermal treatment effects on [6,6]-phenyl-$C_{61}$-butyric acid methyl ester

  • Kim, Hyo-Jung;Lee, Kyu-Won;Lee, Cheol-Eui
    • Proceedings of the Korean Magnestics Society Conference
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    • 2011.12a
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    • pp.57-58
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    • 2011
  • We have carried out magnetic and spectroscopic studies on the physical properties of hydrothermally-treated PCBM samples. Strong ferromagnetic ordering was observed depending on the treatment time, and was studied in relation to the atomic bonding configurations.

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Nonmonotonic Ordering of Lanthanon Nitrates in the Phosphine Oxide Extraction Systems (稀土類元素의 溶媒抽出의 不均一性)

  • C. T. Rhee
    • Journal of the Korean Chemical Society
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    • v.7 no.4
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    • pp.271-276
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    • 1963
  • The distribution ratio of lanthanon nitrates in the TBPO- and TOPO-toluene systems were studied radiometrically as a function of solvent, nitrate and atomic number(Z). The plots of log Kd vs. Z shows two straight lines which are crossing at Z = 63∼64. The solvent dependency was same for lighter and heavier lanthanons but nitrate dependency was different between the two parts.

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Effect of BSO addition on Cu-O bond of GdBa2Cu3O7-x films with varying thickness probed by extended x-ray absorption fine structure

  • Jeon, H.K.;Lee, J.K.;Yang, D.S.;Kang, W.N.;Kang, B.
    • Progress in Superconductivity and Cryogenics
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    • v.18 no.4
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    • pp.1-4
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    • 2016
  • We investigated the relation between the Cu-O bond length and the superconducting properties of $BaSnO_3$ (BSO)-added $GdBa_2Cu_3O_{7-x}$ (GdBCO) thin films by using extended x-ray absorption fine structure (EXAFS) spectroscopy. 4 wt.% $BaSnO_3$ (BSO) added $GdBa_2Cu_3O_{7-x}$ (GdBCO) thin films with varying thickness from $0.2{\mu}m$ to $1.0{\mu}m$ were fabricated by using pulsed laser deposition (PLD) method. The transition temperature ($T_c$) and the residual resistance ratio (RRR) of the GdBCO films increased with increasing thickness up to $0.8{\mu}m$, where the crystalline BSO has the highest peak intensity, and then decreased. This uncommon behaviors of $T_c$ and RRR are likely to be created by the addition of BSO, which may change the ordering of GdBCO atomic bonds. Analysis from the Cu K-edge EXAFS spectroscopy showed an interesting thickness dependence of ordering behavior of BSO-added GdBCO films. It is noticeable that the ordering of Cu-O bond and the transition temperature are found to show opposite behaviors in the thickness dependence. Based on these results, the growth of BSO seemingly have evident effect on the alteration of the local structure of GdBCO film.

Metal-Insulator Transition Induced by Short Range Magnetic Ordering in Mono-layered Manganite

  • Chi, E.O.;Kim, W.S.;Hong, C.S.;Hur, N.H.;Choi, Y.N.
    • Bulletin of the Korean Chemical Society
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    • v.24 no.5
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    • pp.573-578
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    • 2003
  • The structural, magnetic, and transport properties of a mono-layered manganite $La_{0.7}Sr_{1.3}MnO_{4+{\delta}}$ were investigated using variable temperature neutron powder diffraction as well as magnetization and transport measurements. The compound adopts the tetragonal I4/mmm symmetry and exhibits no magnetic reflection in the temperature region of 10 K ≤ T ≤ 300 K. A weak ferromagnetic (FM) transition occurs about 130 K, which almost coincides with the onset of a metal-insulator (M-I) transition. Extra oxygen that occupies the interstitial site between the [(La,Sr)O] layers makes the spacing between the [MnO₂] layers shorten, which enhances the inter-layer coupling and eventually leads to the M-I transition. We also found negative magneto resistance (MR) below the M-I transition temperature, which can be understood on the basis of the percolative transport via FM metallic domains in the antiferromagnetic (AFM) insulating matrix.

Epidemic-Style Group Communication Algorithm ensuring Causal Order Delivery (인과적 순서 전달을 보장하는 전염형 그룹 통신 알고리즘)

  • Kim Chayoung;Ahn Jinho
    • The KIPS Transactions:PartA
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    • v.12A no.2 s.92
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    • pp.137-144
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    • 2005
  • Many reliable group communication algorithms were presented to satisfy predetermined message ordering properties in small or medium-scale distributed systems. However, the previous algorithms with their strong reliability properties may be unappropriate for large-scale systems. To address this issue, some epidemic-style group communication algorithms were proposed for considerably improving scalability while guaranteeing the reasonably weaker reliability property than the existing ones. The algorithms are all designed for ensuring the atomic order message delivery property. But, some distributed applications such as multimedia systems and collaborative work, may require only the weaker message ordering property, i.e., causal order delivery. This paper proposes an efficient epidemic-style group communication algorithm ensuring causal order delivery to provide the indigenous scalability of the epidemic-style approach.

Structural and Magnetic Properties of Co2MnSi Heusler Alloy Films

  • Lim, W.C.;Okamura S.;Tezuka N.;Inomata K.;Bae, J.Y.;Kim, H.J.;Kim, T.W.;Lee, T.D.
    • Journal of Magnetics
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    • v.11 no.1
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    • pp.8-11
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    • 2006
  • Recently half-metallic full-Heusler alloy films have attracted significant interests for spintronics devices. As these alloys have been known to have a high spin polarization, very large TMR ratio is expected in magnetic tunnel junctions. Among these alloys, $Co_2MnSi$ full-Heusler alloy with a high spin polarization and a high Curie temperature is considered a good candidate as an electrode material for spintronic devices. In this study, the magnetic and structural properties of $Co_2MnSi$ Heusler alloy films were investigated. TMR characteristics of magnetic tunnel junctions with a $Co_2MnSi/SiO_2/CoFe$ structure were studied. A maximum MR ratio of 39% with $SiO_2$ substrates and 27% with MgO(100) substrates were obtained. The lower MR ratio than expectation is considered due to off-stoichiometry and atomic disorder of $Co_2MnSi$ electrode together with oxidation of the electrode layer.

Creep Mechanisms of Calcium-Silicate-Hydrate: An Overview of Recent Advances and Challenges

  • Ye, Hailong
    • International Journal of Concrete Structures and Materials
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    • v.9 no.4
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    • pp.453-462
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    • 2015
  • A critical review on existing creep theories in calcium-silicate-hydrate (C-S-H) is presented with an emphasis on several fundamental questions (e.g. the roles of water, relative humidity, temperature, atomic ordering of C-S-H). A consensus on the rearrangement of nanostructures of C-S-H as a main consequence of creep, has almost been achieved. However, main disagreement still exists on two basic aspects regarding creep mechanisms: (1) at which site the creep occurs, like at interlayer, intergranular, or regions where C-S-H has a relatively higher solubility; (2) how the structural rearrangement evolutes, like in a manner of interlayer sliding, intra-transfer of water at various scales, recrystallization of gelled-like particles, or dissolution-diffusion-reprecipitation at inter-particle boundary. The further understanding of creep behavior of C-S-H relies heavily on the appropriate characterization of its nanostructure.

Length- and parity-dependent electronic states in one-dimensional carbon atomic chains on C(111)

  • Kim, Hyun-Jung;Oh, Sang-Chul;Kim, Ki-Seok;Zhang, Zhenyu;Cho, Jun-Hyung
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.56-56
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    • 2010
  • Using first-principles density-functional theory calculations, we find dramatically different electronic states in the C chains generated on the H-terminated C(111) surface, depending on their length and parity. The infinitely long chain has $\pi$ electrons completely delocalized over the chain, yielding an equal C-C bond length. As the chain length becomes finite, such delocalized $\pi$ electrons are transformed into localized ones. As a result, even-numbered chains exhibit a strong charge-lattice coupling, leading to a bond-alternated structure, while odd-numbered chains show a ferrimagnetic spin ordering with a solitonlike structure. These geometric and electronic features of infinitely and finitely long chains are analogous to those of the closed (benzene) and open (polyacetylene) chains of hydrocarbons, respectively.

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A Study on the Mechanochemical Effects of Dickite (Dickite의 메카노케미칼 효과에 관한 연구)

  • Ryu, Ho-Jin
    • Korean Journal of Materials Research
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    • v.7 no.2
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    • pp.152-156
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    • 1997
  • In this paper, I meritioned ,I study on thc rnechanochernic;~l effec ts of grountl iljckite To investigate the mechanochemical effects of ground tlickite 1,y planet,~r\- mill. a structul-ill i~nalvsis of dickite prepared with different grinding time has been made 11y X-ray diffraction and ilifierenti,~l tl~i.~-ni;~i analysis. 'l'he $SiO_{4}$ hecira was unchanged bl- milling and remained ;is the local ordering unit s t t - ~ c ~ u ~ - c ~ s in the ground dickitc samples I ) v analyzing the radial distribution function. On the other hand, with an increi~se of the grinding time a decrease of coordination number and atomic distance bet\vccn aluminum and oxygen hi1c.r l~een octurreil, and Li~~antitativcl\. coniirrned them This result corresponded to the local c,hange around aliimi~iuni I>V tliftercntii~l t1ii:rm;il ani~lysis. Therefore, the mechanochemical phenomina of ground tiickite werc3 h e to the local c~l~mge around aluminum \IT. the prolonged grinding.

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