• Nuclear Engineering and Technology
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• v.51 no.7
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• pp.1866-1870
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• 2019

Residual salt separation is an essential step in pyroprocessing because its reaction products, as prepared by electrochemical unit processes, contain frozen residual electrolyte species, which are generally composed of alkali-metal chloride salts (e.g., LiCl, KCl). In this study, a simple technique that utilizes high-temperature gas flux as a driving force to melt and push out the residual salt in the reaction products was developed. This technique is simple as it only requires the use of a heating gun in combination with a gas injection system. Consequently, $LiNO_3-ZrO_2$ and $LiCl-ZrO_2$ mixtures were successfully separated by the high-temperature gas injection (separation efficiency > 93%), thereby demonstrating the viability of this simple technique for residual salt separation.

• Proceedings of the IEEK Conference
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• 1998.10a
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• pp.581-584
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• 1998

TiN thin films were grown on (100) Si substrate by atomic layer epitaxy at 130 - $240^{\circ}C$ using TEMAT and NH3 as precursors. Reactants were injected into the reactor in sequence of TEMAT precursor vapor pulse, N2 purging gas pulse, NH3 gas pulse and N2 purging gas pulse so that gas-phase reactions could be removed. The films were characterized by means of x-ray diffraction(XRD), 4-point probe, atomic force microscopy(AFM) and auger electron spectroscopy(AES).

• Proceedings of the Korean Nuclear Society Conference
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• 1996.11b
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• pp.506-511
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• 1996

Research on the dry etching of UO$_2$ by using fluorine containing gas plasma is carried out for DUPIC (Direct Use of spent PWR fuel In CANDU) process which is taken into consideration for potential future fuel cycle in Korea. CF$_4$/O$_2$ gas mixture is chosen for the reactant gas and the etching rates of UO$_2$ by the gas plasma are investigated as functions of substrate temperature, plasma gas pressure, CF$_4$/O$_2$ ratio, and plasma power, It is tentatively found that the etching rate can reach 1000 monolayers/min. and the optimum CF$_4$/O$_2$ ratio is around 4:1.

• Journal of Powder Materials
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• v.17 no.5
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• pp.379-384
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• 2010

In the present work, bismuth nanopowders with various particle size distributions were synthesized by controlling argon (Ar) gas flow rate and chamber pressure of a gas condensation (GC) apparatus. From the analyses of transmission electron microscopy (TEM) images and nitrogen gas adsorption results, it was found that as Ar gas flow rate increased, the specific surface area of bismuth increased and the average particles size decreased. On the other hand, as the chamber pressure increased, the specific surface area of bismuth decreased and the average particles size increased. The optimum gas flow rate and chamber pressure for the maximized electrochemical active surface area were determined to be 8 L/min and 50 torr, respectively. The bismuth nanopowders synthesized at the above condition exhibit 13.47 $m^2g^{-1}$ of specific surface area and 45.6 nm of average particles diameter.

• Nuclear Engineering and Technology
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• v.55 no.3
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• pp.1125-1139
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• 2023

The system-integrated modular advanced reactor 100 (SMART100), an integral-type pressurized water small modular reactor, is based on a novel design concept for containment cooling and radioactive material reduction; it is known as the containment pressure and radioactivity suppression system (CPRSS). There is a passive cooling system using a condensation with non-condensable gas in the SMART CPRSS. When a design basis accident such as a small break loss of coolant accident (SBLOCA) occurs, the pressurized low containment area (LCA) of the SMART CPRSS leads to steam condensation in an incontainment refuelling water storage tank (IRWST). Additionally, the steam and non-condensable gas mixture passes through the CPRSS heat exchanger (CHX) submerged in the emergency cooldown tank (ECT) that can partially remove the residual heat. When the steam and non-condensable gas mixture passes through the CHX, the non-condensable gas can interrupt the condensation heat transfer in the CHX and it degrades CHX performance. In this study, condensation heat transfer experiments of steam and non-condensable gas mixture in the natural circulation loop were conducted. The pressure, temperature, and effects of the non-condensable gas were investigated according to the constant inlet steam flow rate with non-condensable gas injections in the loop.

• Analytical Science and Technology
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• v.12 no.4
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• pp.1051-1056
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• 1999

• Journal of Radiation Protection and Research
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• v.29 no.1
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• pp.25-31
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• 2004

Results of EGS4 based calculations to study the spatial resolution of gas detectors are described. The calculations include radial distribution of electrons generated by photons of various energies penetrating into variable thickness of Ar and Xe gas layers. Given a desired spatial resolution, the maximum allowed thickness of gas layer for each energy level is determined. In order to obtain 0.1mm spatial resolution, the maximum thickness for the Ar gas is found to be 2mm for photon energies below 14keV while the optimum energy of photons for Xe gas with the same thickness is about 45keV. The results of calculations performed to compare the number of electrons generated by CsI coated micro-channel plate and the number of electrons generated by the Ar and Xe gas layers are described. The results show that the number of electrons generated by the gases is about 10 times higher than the one generated by CsI coated micro-channel plate. A few sample gray scale images generated by these calculations are included.

• Nuclear Engineering and Technology
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• v.28 no.4
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• pp.423-430
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• 1996

The improved and advanced Annulus Gas System(AGS) has been developed for Wolsong 2 to satisfy the requirements of the regulatory body. The Atomic Energy Control Board(AECB) required a shorter detection time following a small leak from a pressure tube and/or calandria tube. This paper describes licensing requirements, functional requirements and detail design description for the AGS. The Wolsong unit No. 1 AGS was designed to operate as a stagnant system normally requiring only pressure regulation and having provisions for purging. no improved AGS involves the adoption of gas recirculation in AGS, duplication of dew point indicators with additional instrumentation and sampling provisions to prompt operator action. The improved system operates in the recirculation mode with continuous dew point measurement for leak detection. An AGS with improved detection instrumentation is provided.

• Proceedings of the Korean Nuclear Society Conference
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• 2002.05a
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• pp.420.1-420
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• 2002

Thermal decomposition reaction of gas-phase UO2(hfacac)2. THF was investigated in a static cell. IR spectroscopic method was used to study the thermal decomptsition of gas phase uranyl complexes. The decomposition reaction products were separated by using thermal-gradient fractional sublimation method utilizing the differences in their volatility.

• Nuclear Engineering and Technology
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• v.35 no.1
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• pp.55-63
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• 2003

Threshold porosity above which fission gas release channels would be formed in the rim egion of high burnup UO$_2$ fuel was estimated by the Monte Carlo method and Hoshen-Kopelman algorithm. With the assumption that both rim pore and rim grain can be represented by cube, pore distribution in the rim was simulated 3-dimensionally by the Monte Carlo method according to porosity and pore size distribution. Then, using the Hoshen-Kopelman algorithm, the fraction of open rim pores interlinked to the outer surface of a fuel pellet was derived as a function of rim porosity. The simulation showed that porosity of 24-25% is the threshold above which the number of rim pores forming release channels increases very rapidly. On the other hand, channels would not be formed if the porosity is less than about 23.5%. This is consistent with the observation that, for porosity less than 23.5%, almost no fission gas is released in the rim. However, once the rim porosity reaches beyond 25%, extensive open paths would be developed and considerable fission gas release would start in the rim.