• Mass Spectrometry Letters
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• v.3 no.2
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• pp.29-38
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• 2012

A new approach of volatile compounds analysis is proposed using a linear ion trap Orbitrap mass spectrometer coupled with gas chromatography through an atmospheric pressure photoionization interface. In the proposed GC-HRMS/MS approach, direct chemical composition analysis is made for the precursor ions in high resolution MS spectra and the structural identifications were made through the database search of high quality MS/MS spectra. Successful analysis of a complex perfume sample was demonstrated and compared with GC-EI-Q and GC-EI-TOF. The current approach is complementary to conventional GC-EI-MS analysis and can identify low abundance co-eluting compounds. Toluene co-sprayed as a dopant through API probe significantly enhanced ionization of certain compounds and reduced oxidation during the ionization.

• Tribology and Lubricants
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• v.13 no.1
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• pp.70-75
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• 1997

The lubrication characteristics of high-speed ball bearings at oil-starvation have been investigated empirically using the bearings employed in small industrial gas turbine engines. For the close structural simulation, experiments carried our with bearing mounting supports of real engines, such as bearing housings and oil nozzle assemblies with squeeze film dampers. Thus the results of tests can be applied to the design and the development of gas turbine engines. Testing was done by simulating the oil-starvation conditions in engines, such as stopping the oil-supply to the bearing during normal operating, starting without oil-supply at atmospheric temperature, and accelerating with oil-supply at atmospheric temperature. From this study, the relative comparison of the frictional resistance and the resistance due to the bearing cavity oil was demonstrated visually, and the resistance due to the bearing cavity oil was dominant in the resistance of bearing at high speed.

• Journal of Korean Society for Atmospheric Environment
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• v.19 no.6
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• pp.733-743
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• 2003

The flow field in multiple fluid sphere systems was studied analytically. The expanded zero vorticity cell model based on Kuwabara's theory (1959) was applied and the effects of gas slippage at the collecting surface were considered. Also, the solid sphere system was extended to fluid sphere including the effects of the induced internal circulation inside the liquid droplet spheres or gas bubble systems. As a result, the obtained analytic solution was converged to the existing solutions for flow field around solid and bubble sphere systems with proper boundary conditions. Based on the resolved flow field, the terminal velocity around the collecting fluid spheres was obtained. Subsequently, this study evaluated the most general solution for flow field around the multiple fluid sphere systems. The obtained flow field in multiple fluid sphere could be used as a fundamental consideration of wet scrubber design and devices for removing particles by fluid-fluid interactions.

• Journal of Korean Society for Atmospheric Environment
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• v.4 no.2
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• pp.38-46
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• 1988

NOx is an important air pollution material which is generated when fossil fuels are burning, NOx removal in flue gas by selective catalytic reduction was studied over various catalysts in a fixed bed continuous flow reactor. The ranges of experimental conditions were at the temperatures between $200^\circ$C and $350^\circ$C, the $NH_3/NOx$ mole ratios between 0.8 and 1.4, oxygen concentrations between 1.5% and 3% and the space velocities between 5, 000 $hr^-1$ and 12, 500 $hr^-1$. The efficiency of NOx removal in the ranges of experimental conditions was highest at the temp. of 300$^\circ$C, oxygen concentration of 2.5-2.6% and $NH_3/NOx$ mole ratios of 1.0-1.2. The catalyst with high activity for NOx removal in flue gas was found to be $MoO_3-V_2O_5/TiO_2$.

• Journal of Korean Society for Atmospheric Environment
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• v.16 no.3
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• pp.285-291
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• 2000

EGR(Exhaust Gas Recirculation) is known as the technique reducing the NOx emissions from diesel engine. Low pressure roote and high pressure roote are applied for heavy-duty diesel engine are. In this study, as research for the heavy duty diesel engine equipped with EGR, reduction characteristic of CO, THC, NOx, and PM in HD diesel engines are investigated by applying EGR device. Also, through the experiments using 11 liters, turbocharged diesel engine with EGR valve and intercooler, exhaust gas reduction characteristics were measured as changing in EGR rate according to D-13 mode.

• Journal of Korean Society for Atmospheric Environment
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• v.20 no.6
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• pp.729-738
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• 2004

Seasonal variation of major inorganic ions in the greater Seoul area was estimated using a photochemical box model and a gas/aerosol equilibrium model with emphasis on semi -volatile nitrate. Pollutant emission was determined by season by comparing the predicted concentration with the measurement one obtained for a year from the late 1996. The results showed that particulate nitrate was the highest in summer but about 40% of total nitrate was present in the gas phase. This was due to volatilization at high temperature since ammonia was sufficient to neutralize all nitrate regardless of season. As relative humidity in summer was higher than the deliquescence point, particulate ion concentration with water was two times higher than that in other season. So called ‘NOx disbenefit’ indicating increase in particulate ion concentration with decrease in NOx emission was evident especially in winter.

• Journal of Korean Society for Atmospheric Environment
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• v.12 no.1
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• pp.43-53
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• 1996

Numerical simulation was performed for the 3-dimensional flow filed of gas and particle phase for cyclone dust collector. FVM(Finite Volume Method) was employed for gas phase. The flow was solved suing the k-.varepsilon. epsilon turbulence model. The particle exit at the bottom of the cone was treated as a solid wall in this model because the gas flow through the effective dust exit is usually insignificant. The major parameters considered in this study was vortex finder diameter, effective dust exit diameterm vortex finder length, inlet type for dimension performance. Particle trajectory calculations were made for three different, particle sizes of 1, 25 and 50 .mu.m. The results obtained from this study give some physical insight of dust particle collection mechanism together with the indication of the collection efficiency. The simulation results were in generally good agreement with empirical knowledge. The application of this kind of computer program looks promising as a potential tool for the design of cyclone and determination of optimum operating condition.

• Journal of Korean Society for Atmospheric Environment
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• v.12 no.3
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• pp.243-254
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• 1996

The main purpose of this study is to investigate the collection efficiency characteristics of a cylindrical ESP. To do that, it is necessary to analyze the electric field, gas flow field, and mechanism of particle movement by numerical simulation based on EHD model. For a gas flow field, Navier-Stokes equation involving the electric source term was solved by SIMPLE algorithm. In case of the electric field, the current continuity and electric field equations were solved by S.O.R. method. The analysis of particle movement was performed on the basis of PSI-CELL model from the Lagrangian viewpoint. The results showed that the influence on the gas flow field by the electric field is almost negligible in a cylindrical ESP. The particle drift velocity $V_P$ toward the collection surface is increased continuously by the electrostatic force due to the rise of particle charge as the particle is moving to the flow direction and the particle size becomes larger. The collection efficiency is to quitely higher with the increase of applied voltage for the same particle size, while becomes smaller as the inlet velocity is increased.

• Applied Chemistry for Engineering
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• v.33 no.2
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• pp.229-233
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• 2022

In this study, a gas-liquid hybrid atmospheric pressure plasma reactor of the dielectric barrier discharge method was fabricated and characterized. The solubility of copper oxide in the organic acid solution was increased when argon having a larger atomic weight than helium was used during plasma discharge. There was no significant effect of mixing organic acid solutions under plasma discharge treatment on the variation of copper oxide's solubility. As the applied voltage for plasma discharge and the concentration of the organic acid solution increased, the dissolution and removal power of the copper oxide layer increased. Solubility of copper oxide was more affected by the concentration in organic acid solution rather than the variation of plasma applied voltage. The usefulness of hybrid plasma reactor for the surface cleaning process was confirmed.

• Journal of the Korean Wood Science and Technology
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• v.17 no.2
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• pp.13-19
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• 1989

Two different quartz types of gasification reactor were used for pyrolysis and gasification of sawdust, ricestraw, ricehusk and municipal wastes which contain only cellulosics., operating at 1 atmospheric and vacuum pressure respectively. Also a stainless steel autoclave gasification reactor was used which is possible to use up to 100 atmospheric pressures and $800^{\circ}C$ of reaction temperature to complete pyrolysis and gasification reaction. The catalysts used in this reaction w- ere $K_2CO_3$, $Na_2CO_3$, Ni and Ni-$K_2CO_3$ as CO-Catalyst. The product gas mixtures were identified to be CO, $CO_2$, $C_3H_3$, $CH_4$ and $CH_3CHO$ etc. by Gas Chromatography and Mass Spectrometry. The pressurized gasification reaction shows significant increase in terms of methane composition and yield of product gases, comparing with those from unpressurized gasification reactions. The total volume of product gas mixtures amounts to 1600-1800ml per1gof waste of waste lignocellulosics or municipal waste, and the metane content of the gas mixtures reached to 40%, when $800^{\circ}C$ of reaction temperature and 100 atmospheric pressures with Ni-$K_2CO_3$ as CO-catalyst in the pressurized gasification reaction were used. This results show that the product gas mixtures containing 40% of methane call be used for alternative enegy source.