• Title/Summary/Keyword: asymmetric synthesis

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Asymmetric Synthesis of (+)-trans-Aerangis Lactone

  • Kim, Aejin;Sharma, Satyasheel;Kwak, Jong Hwan;Kim, In Su
    • Bulletin of the Korean Chemical Society
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    • v.34 no.1
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    • pp.75-78
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    • 2013
  • Asymmetric synthesis of (+)-trans-aerangis lactone was achieved from commercially available 1-hexanol or 1-hexanal in four steps via iridium-catalyzed diastereoselective and enantioselective carbonyl crotylation from the alcohol or aldehyde oxidation level, and ruthenium-catalyzed olefin metathesis.