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http://dx.doi.org/10.5012/bkcs.2013.34.1.75

Asymmetric Synthesis of (+)-trans-Aerangis Lactone  

Kim, Aejin (School of Pharmacy, Sungkyunkwan University)
Sharma, Satyasheel (School of Pharmacy, Sungkyunkwan University)
Kwak, Jong Hwan (School of Pharmacy, Sungkyunkwan University)
Kim, In Su (School of Pharmacy, Sungkyunkwan University)
Publication Information
Bulletin of the Korean Chemical Society / v.34, no.1, 2013 , pp. 75-78 More about this Journal
Abstract
Asymmetric synthesis of (+)-trans-aerangis lactone was achieved from commercially available 1-hexanol or 1-hexanal in four steps via iridium-catalyzed diastereoselective and enantioselective carbonyl crotylation from the alcohol or aldehyde oxidation level, and ruthenium-catalyzed olefin metathesis.
Keywords
Aerangis lactone; Asymmetric; Catalytic; Crotylation; Metathesis;
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