• 폴리머
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• 제36권3호
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• pp.251-261
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• 2012

폴리(메틸메타크릴레이트)(PMMA) 매트릭스를 갖는 인조대리석의 기계적 강도를 향상시키기 위해 그래핀 산화물 플레이크(GOF)를 충전제로 사용하여 나노컴포지트를 제조하였다. 충전제로 사용한 GOF는 흑연을 Hummers법으로 산화한 후 열처리에 의해 박리시켜 제조하였다. PMMA 매트릭스와의 계면혼화성을 향상시키기 위하여 다양한 산소:불소 조성의 함산소불소화 처리로 GOF 계면을 개질시켰다. 산소함량 50% 이상에서 함산소불소화 처리한 GOF를 충전제로 사용한 나노컴포지트는 기존 인조대리석에 비해 굴곡강도, 굴곡탄성률, Rockwell경도, Barcol경도, Izod충격강도 모두 현저히 증가하였다. 적절히 함산소불소화 처리된 GOF는 PMMA 매트릭스와의 계면접착력이 우수함을 파단면의 모폴로지로부터 확인하였다. 하지만 GOF 충전제의 함량이 0.07 phr 이상으로 증가하면 충전제의 분산이 균일하지 못하여 인조대리석의 기계적 강도는 오히려 감소하는 경향을 나타내었다.

• 터널과지하공간
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• 제4권3호
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• pp.274-286
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• 1994

Direct shear tests were on ducted in a laboratory setting in order to investigate the shear strength and deformation behavior of rock joints. Also, the characteristics of acoustic emissions (AE) during shearing of rock joints were studied. The artificial rock joints were created by splitting the intact blocks of Hwangdeung granites and Iksan marbles. Joint roughness profiles were measured by a profile gage and then digitized by Image analyzer. Roughness profile indices(Rp) of the joints were calculated with these digitized data. Peak shear strength, residual shear strength, shear stiffness and maximum acoustic emission(AE) rate were investigated with joint roughness. The peak shear strenght, the residual shear strength and the shear stiffness were increased as roughness popfile index or normal stress increased in the shear tests of granites. In the tests of marble samples, the shear deformation characteristics were not directly affected by joint roughness. As the result of two directional shear tests, the shear characteristics were varied with shear direction. AE count rates were measured during the shear deformation and the AE signals in several stages of the deformation were analyzed in a frequency domain. The AE rate peaks coincided with the stress drops during the shear deformation of joint. The dominant frequencies of the AE signals were in the vicinity of 100 kHz fo rgranite sample and 900 kHz for marble samples. The distribution of amplitude was dispersed with increasing normal stress.