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http://dx.doi.org/10.7317/pk.2012.36.3.251

Effects of Oxyfluorinated Graphene Oxide Flake on Mechanical Properties of PMMA Artificial Marbles  

Kim, Hyo-Chul (Department of Fine Chemical Engineering Applied Chemistry, Chungnam National University)
Jeon, Son-Yeo (Department of Fine Chemical Engineering Applied Chemistry, Chungnam National University)
Kim, Hyung-Il (Department of Fine Chemical Engineering Applied Chemistry, Chungnam National University)
Lee, Young-Seak (Department of Fine Chemical Engineering Applied Chemistry, Chungnam National University)
Hong, Min-Hyuk (Lion Chemtech Co., Ltd.)
Choi, Ki-Seop (Lion Chemtech Co., Ltd.)
Publication Information
Polymer(Korea) / v.36, no.3, 2012 , pp. 251-261 More about this Journal
Abstract
The nanocomposites containing graphene oxide flakes were prepared in order to improve the mechanical properties of artificial marbles based on poly(methyl methacrylate)(PMMA) matrix. Graphene oxide flakes were prepared from graphite by oxidation with Hummers method followed by exfoliation with thermal treatment. Surface of graphene oxide flakes were modified with oxyfluorination in various oxygene:fluorine compositions to improve the interfacial compatibility. The nanocomposites containing graphenes modified with oxyfluorination in the oxygen content of 50% and higher showed the significant increase in flexural strength, flexural modulus, Rockwell hardness, Barcol hardness, and Izod impact strength. The morphology of fractured surface showed the improved interfacial adhesion between PMMA matrix and the graphenes which were properly treated with oxyfluorination. The mechanical properties of nanocomposite were deteriorated by increasing the content of graphene above 0.07 phr due to the nonuniform dispersion of graphenes.
Keywords
PMMA; graphene oxide flake; oxyfluorination; mechanical property; artificial marbles;
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