• 제목/요약/키워드: arginine-fructose-glucose

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Arginyl-fructosyl-glucose and Arginyl-fructose, Compounds Related to Browning Reaction in the Model System of Steaming and Heat-drying Processes for the Preparation of Red Ginseng

  • Suzuki, Yukio;Choi, Kang-Ju;Uchida, Kei;Ko, Sung-Ryong;Sohn, Hyun-Joo;Park, Jong-Dae
    • Journal of Ginseng Research
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    • 제28권3호
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    • pp.143-148
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    • 2004
  • Brown color intensity has been a major factor to estimate the quality of red ginseng and its products. This study deals with the relationship between the browning reaction of ginseng root and two compounds, arginyl-fructosyl-glucose(Arg-fru-glc) and arginyl-fructose (Arg-fru), in the model system of steaming and heat-drying processes for the preparation of red ginseng. During the steaming process, a marked decrease of starch and a considerable formation of maltose occurred in main roots of raw ginseng, but the formation of glucose was scarcely observed. After the heat-drying process, the brown color intensity of the powdered preparation of steamed main roots was 3 to 4 times higher than that of the powdered preparation of raw main roots. Also, when the heat- drying process was done with the addition of L-arginine, brown color intensity of the powdered preparation of steamed main roots was 12 to 13 times higher than that of the powdered preparation of raw main roots. The amount ratios of browning reaction products formed from sugar compounds and amino acids in the model system of steaming and heat-drying treatments in vitro were in order of xylose > glucose > fructose > maltose > dextrin (DE 9) > sucrose > dextrin (DE 8) and soluble starch. Each solution of Arg-fru-glc and Arg-fru that were synthesized chemically from maltose plus L-arginine and glucose plus L-arginine, respectively, changed from colorless to brown color during the heat-drying treatment. Amino acids or sugars were effective on the acceleration of each browning reaction of Arg-fru-gIc and Arg-fru during the heat-drying treatment.

배의 성숙 중 유리당과 유리아미노산 함량 변화 (Variation of free Sugar and Amino Acid Contents of Pears During the Ripening Period)

  • 최옥자;박혜령;조성효
    • 한국식품조리과학회지
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    • 제14권3호
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    • pp.250-254
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    • 1998
  • A variation of free sugar and amino acid contents of pears during the ripening period was determined by HPLC and amino acid analyzer. The research results are as follws: Fructose, glucose and sucrose were present in the pears. The contents of fructose was the highest, followed by glucose and sucrose in order. The contents of total sugar in Shingo and Youngsan was similar, but the contents of frucose in Shingo was lower and the contents of sucrose was higher than that of Youngsan (p<.001). During the ripening period, the contents of fructose and glucose gradually increased during the harvesting season and then somewhat decreased. The contents of sucrose increased continually, while the contents of total free sugar reached the maximum during the harvesting season, it was 10.41%, 10.29% in Shingo and Youngsan and then decreased gradually. The contents of total free amino acid in Shingo was higher than that of Youngsan. A variation ratio and the composition of amino acid in Shingo and Youngsan during the ripening period didn't make a significant difference. The major free amino acid of the pears was in the order of aspartic acid, serine, threonine, histidine, glutamic acid, valine, arginine, and alanine. During the ripening period, aspartic acid, threonin, serine, methionine, isoleucine, leucine, histidine, and Iysine increased gradually. Glutamic acid, alanine, valine, arginine didn't show much change. The contents of total free amino acid increased during the ripening period.

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사과의 성숙 중 유리당과 유리아미노산 함량 변화 (Variation of Free Sugar and free Amino Acid Contents of Apples During the Ripening Period)

  • 최옥자;박혜령;조성효
    • 한국식생활문화학회지
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    • 제12권2호
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    • pp.149-153
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    • 1997
  • A variation of free sugar and free amino acid contents of apples during the ripening period was determined by HPLC and amino acid analyzer. The research results are as followes: Fructose, glucose and sucrose were present in the apples. The contents of fructose was the highest, followed by the order of sucrose and glucose. The contents of total sugar in Red fuji was relatively higher than that of Fuji. During the ripening period, the contents of fructose increased conspicuously for the harvesting season and then it decreased gradually. The contents of glucose increased gradually for the harvesting season and then it somewhat decreased. The contents of sucrose increased continually, while, the contents of total free sugar reached the maximum for the harvesting season and then it decreased gradually. A variation in the contents of free amino acid and composition during the ripening period didn't make a significant difference. The major free amino acid of the apples was in the order of aspartic acid, serine, threonine, glutamic acid, histidine, arginine, and alanine. During the ripening period, aspartic acid, threonin, serine, alanine, histidine, and arginine increased gradually. Especially, alanine, histidine, and arginine increased remarkably after the the harvesting season. Glutamic acid, valine, isoleucine, and leucine didn't show much change. The contents of total amino acid increased little by little as the apples ripened, dranstically increased during the harvesting season and slowly increased or slightly decreased after the harvesting seasom.

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진도산(珍島産) 구기자(枸杞子)의 아미노산조성(組成)과 유리당(遊離糖)의 분석(分析) (Quantitative Analysis of Total Aimno Acids and Free Sugars in Lycii fructus)

  • 이명열;서화중
    • 한국식품영양과학회지
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    • 제15권3호
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    • pp.249-252
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    • 1986
  • 구기자(枸杞子)의 총(總)아미노산조성(組成) 및 유리(遊離)당을 각각 amino acid autoanalyzer, HPLC로 분석(分析)한 결과(結果)는 다음과 같다. 1. 17종(種)의 총(總)아미노산이 검출(檢出)되었다. 즉 asparatic acid, threonine, serine, glutamic acid, proline, glycine, alanine, cystine, valine, methionine, isoleucine, leucine, tyrosine, phenr-lalanine, hisidtine, lysine, arginine인데 이중 threonine을 가장 많이 함유하였으며 aspartic acid는 가장 적었다. 2. 총(總) essential amino acid량은 총(總)아미노산량의53.93%로 양질(良質)의 아미노산을 함유하였다. 3. Glucose, fructose, saccharose 등 3종(種)의 유리(遊離)당이 검출(檢出)되었는데 이중 fructose를 가장 많이 함유하였다.

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밤의 저장 중 성분변화 (Changes of Constituent Components in Chestnut during Storage)

  • 나영아;양차범
    • 한국식품과학회지
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    • 제28권6호
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    • pp.1164-1170
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    • 1996
  • 밤의 저장중 품질변화를 평가하고져 실온$(20^{\circ}C)$ 및 냉장$(1^{\circ}C)$에서 각각 9주간 및 15주간 저장하면서 vitamin C, 당, 유기산 및 아미노산의 함량변화를 측정 하여 다음과 잘은 결과를 얻었다. 밤의 vitamin C함량은 환원형이 17.76 mg/100 g,f.w., 산화형이 4.08 mg/100g,f.w.로 환원형이 전체의 81.3%나 차지하였으며, 저장기간에 따라서 환원형은 감소하였으나 산화형은 저장온도 $20^{\circ}C$에서는 5주까지, $1^{\circ}C$에서는 7주까지 증가하였다. 밤의 유기산 조성으로는 malic acid와 citric acid가 대부분을 차지하였고, quinic acid는 적은 양 함유되었으며 저장기간에 따라서는 citric acid는 크게 감소하였으나, malic acid는 $20^{\circ}C$에서는 증가되었다. 밤의 유리당조성은 sucrose, maltose, fructose, glucose의 순으로 많이 함유되었고 저장기간에 따라서는 glucose와 fructose는 감소한 반면 sucrose와 maltose는 증가하였다. 밤의 유리아미노산 조성은 glutamic acid가 가장 많이 함유되어 전체의 51%를 차지하였고 그 다음 aspartic acid, arginine, alanine, proline, serine, threonine 등의 순으로 많이 함유되었으며, 저장기간에 따른 변화는 $20^{\circ}C$에서는 glutamic acid, arginine, alanine, threonine, phenylalanine, valine, lysine 등은 증가하였으나, proline, serine, isoleucine, leucine 및 ${\gamma}-aminobutyric{\;}acid$ 등은 감소하였으며 $1^{\circ}C$에서는 큰 변화가 없었다.

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수삼물추출물의 갈변반응중 아미노산과 당류변화 (Changes in Free Amino Acids and Sugars in Water-soluble Extracts of Fresh Ginseng during Browning Reaction)

  • 김만욱;박래정
    • Journal of Ginseng Research
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    • 제5권2호
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    • pp.122-131
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    • 1981
  • An aqueous extract s of fresh ginseng roots was heated at loot for 64 hrs. and the changes of color intensity, pH and the amount of free sugars and amino acids during the various intervals of the heating time were investigated. Color intensity and absorbance of the solution at 490nm were increased in proportion to the length of the heating time. Most of brown pigments produced during the treatment were water soluble, and pH 5.1 at initial stage of the solution, was slightly decreased at the final stages of the reaction. Sucrose, glucose and fructose were major free sugars in ginseng roots, and the amounts of sucrose was over 90 % of total free sugars. Sucrose. was largely decreased approximately 50%, by 64 hrs of the treatment, whereas sharp increase in the amount of glucose and fructose was observed during the reaction in the solution. The observed increase in reducing sugars, glucose and fructose was presumed due to hydrolysis of sucrose. Evidently, glucose and fructose were not important factor to control the browning reaction of the solution. Most of free amino acids and peptides except alanine and isoleucine especially arginine, serine and threonine, were sharply decreased up to 40 : 50% of the original concentration within 2 hrs. Accordingly, the content of free amino acids and peptides seems to be extremely important factor to control the browning reaction in ginseng. A free amino acid, presumed to be nor-leucine, was found in fresh ginseng root on the basis of re mention on liquid chromatography. Kinetic analysis of the browning reaction indicated a pseudo second order with respect to amino acid concentration at the initial stage.

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HPLC에 의한 증제와 볶음 녹차 중의 유리 아미노산과 유리당의 정량 (Quantitative Analysis of Free Amino Acids and Free Sugars in Steamed and Roasted Green Tea by HPLC)

  • 고영수;이인숙
    • 한국식품영양과학회지
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    • 제14권3호
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    • pp.301-304
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    • 1985
  • 녹차의 맛을 내는데 주요 성분인 유리아미노산과 유리당을 HPLC로 분석한 결과를 요약하면 다음과 같다. 1. 16종의 유리아미노산이 검출되었다. 즉, aspartic acid, threonine, serine, glutamic acid, proline, glycine, alanine, valine, methionine, isoleucine, leucine, tyrosine, phenylalanine, histidine, lysine, arginine이 그것이었다. 2. 증제차가 볶음차보다 유리아미노산의 함량이 많았고, 녹차중에는 특히 threonine과 aspartic acid, lysine의 함량이 많았다. 3. Fructose, glucose, sucrose, raffinose등 4종의 유리당이 검출되었다. 4. 유리당은 가열시간 증가에 따라 각 성분의 함량이 현저히 감소하였다.

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홍경천(Rhodiola sachazinensis) 뿌리의 식품학적 성분 및 휘발성 향기성분 (Food Components and Volatile Flavors in Rhodiola sachalinensis Roots)

  • 이은정;임지순;박채규;전병선;김석창
    • 식품산업과 영양
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    • 제9권1호
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    • pp.53-57
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    • 2004
  • 홍경천(Rhodiola sachalinensis)의 성분을 분석하여 식품학적 특성을 검토하고 식품소재로서의 기초자료로 활용할수 있도록 건조된 홍경천을 분쇄, 분말화한 후 일반성분 및 무기성분, 유리당, 구성아미노산, 유리지방산, 그리고 향기성분을 분석하였다. 홍경천 건조분말의 수분은 10.14%, 조단백 3.90%, 조지방 1.33%, 총당 41.17%, 환원당 11.40% 회분은 3.05%로 분석되었고, 무기성분은 Ca, K, Kg이 높은 함량으로 나타났다. 유리당으로는 glucose, fructose, sucrose 등으로 특히 glucose와 fructose가 높게 함유되어있었다. 주된 구성아미노산은 glutmic acid, cystine arginine, proline, aspartic acid, isoleucine, histidine 등의 함량 순으로 나타났으며, 특히 glutamic acid, cystine, arginine 함량이 각각 176.24, 168.60, 159.90 mg%로 높은 함량 수준을 보였다. 유리지방산은 linoleic acid가 32.46%로 함량이 가장 높았으며 그 다음으로 palmitic acid가 21.42%, lignoceric acid 14.83%, oleic acid 13.09% behenic acid가 5.80% 순으로 나타났다. 향기성분은 GC-MS로 분석한 결과 2-cinnamic aldehyde 함량이 가장 높았으며 geraniol, myrtenol, octanol 등의 함량이 높게 나타났다. 이러한 결과로 볼 때 홍경천 뿌리는 다양한 일반성분 조성과, 필수아미노산, 불포화지방산, 필수 무기질 등이 균형있게 함유된 식품학적 성분 가치가 충분한 소재임이 확인되었다. 따라서 향후 홍경천 뿌리에서 유효성분을 추출하여 생리활성 및 동물실험을 통해 이들 식품학적 성분들의 유용성을 탐색하는 작업이 필요하리라 사료된다.

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볶음처리에 따른 치커리의 유리당과 아미노산의 변화 (Changes in the Free Sugars and Amino Acids Components of Chicory Roots by Different Roasting Processes)

  • 박채규;전병선;김나미;권오근;심기환
    • 식품산업과 영양
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    • 제9권3호
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    • pp.45-52
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    • 2004
  • 볶음조건에 따라 치커리의 유리당 함량은 무처리구에서는 sucrose 4.78%, fructose 0.81% 및 glucose 0.53%이었는데 볶음온도가 증가하고 볶음시간이 길어질수록 감소하여 16$0^{\circ}C$ 40분 볶음처리구에서는 sucrose 2.21%, fructose 0.35% 및 glucose 0.20%로 전체 유리당 함량으로는 약 45.10% 잔존하였다 아미노산은 18종이 분리되었고, 그 중 유리아미노산 함량은 arginine이 504.49 mg%, asparagine이 500.78 mg%, glutamic acid가 97.82 mg%이었고, 충아미노산 함량은 arginine이 676.7 mg%, glutamic acid가 583.9 mg%, aspartic acid가 319.2 mg%, prolineol 297.4 mg%로 다른 것에 비하여 높게 나타났다 볶음온도가 증가하고 볶음시간이 길어질수록 아미노산의 함량은 감소하였고, 그 정도도 다르게 나타났다. 전체함량으로 보면 유리 아미노산의 경우 무처리구에서는 1728.6 mg%이었던 것이 16$0^{\circ}C$ 40분 처리구에서 4.37 mg%로 약 0.25%만 잔존하였고, 총아미노산의 경우 무처리구에서 3159.4 mg%이었던 것이 16$0^{\circ}C$ 40분 볶음처리구에서는 1732.5 mg%이었다.

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