• Title/Summary/Keyword: archaeological woods

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Application of Infrared Spectroscopical Techniques for Investigation of Archaeological Woods (적외선(赤外線)(IR) 분광법(分光法)에 의한 고목재(古木材) 성상(性狀)의 심지(深知))

  • Kim, Yoon-Soo
    • Journal of the Korean Wood Science and Technology
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    • v.16 no.4
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    • pp.3-9
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    • 1988
  • Infrared (IR) spectroscopic techniques for the analysis of wood samples and the absorbance spectra of solid woods were presented. KBr pellets were prepared by throughly mixing approximately 300 mg of dried KBr and 1 mg of finely milled wood powder extracted with ethanol-cyclohexane previously. This mixture was made into a transparent disc by means of a pellet-making die (10 ton/$cm^2$ for 10 min). This IR techniques were applied for the analysis of archaeological wood samples. The most notable difference in the IR spectra between the recent and the archaeological waterlogged woods is that the absorption band centered at $1,730cm^{-1}$ was significantly diminished in the waterlogged ones. Total loss of absorption in $1,730cm^{-1}$ might be mainly due to the result of hemicellulose degradation. Another feature indicated by IR spectral comparision are that the degraded waterlogged wood samples showed 1) the increased intensity of the 1,600, 1,500 and $1,270cm^{-1}$ due to the residual lignin and the increased intensity at 1,470 and $1,425cm^{-1}$ due to the degradation of hemicellulose and 2) to the emergence of single band around $1,050cm^{-1}$ instead of three bands at 1,110, 1,060 and $1,040cm^{-1}$ in recent wood due to the degradation of cellulose crystalline. It was revealed from the IR examinations that the first change of wood in the waterlogged situation was the lysis of hemicellulose and the second the lysis of cellulose. It was also suggested that IR spectroscopy could serve a fast method for the investigation on the chemical characteristics of archaeological wood samples.

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Chemical Composition of Archaeological Woods Submerged in the Seawater (수침고목재(水浸古木材)의 화학조성(化學組成))

  • Kim, Yoon-Soo;Bang, Joo-Wan;Kim, Ik-Joo;Choi, Kwang-Nam
    • Journal of the Korean Wood Science and Technology
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    • v.18 no.2
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    • pp.3-7
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    • 1990
  • The chemical Composition of Chinese red pine (Pinus massoniana) submerged in the Yellow Sea for more than 700 years has been examined. When compared to the recent wood, the marked chemical changes in the waterlogged wood is the higher amount of lignin with lesser amount of holocellulose and abnormally high ash content. In the heavily degraded samples, the degradation of cellulose is more severe than that of hemicellulose. However, hemicellulose is much more attacked than the cellulose at the initial stage of deterioration in the sea water. Chemical analysis suggests that the cellulolytic marine microorganisms, whether they are fungi or bacteria. can be regarded as the primary agents for the destruction of the archaeological woods submerged in the sea water.

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Chemical and micromorphological changes of archaeological waterlogged wood degraded in marine situations. (해양에서 열화된 완도선 수침고목재의 화학적.미시형태적 변화)

  • Kim, Ik-Joo
    • 보존과학연구
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    • s.11
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    • pp.87-105
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    • 1990
  • Chemical and micro morphological changes of archaeological waterlogged woods from shipwrecked materials in marine situations were investigated which were submerged in seabed for over 900 years. Tested Wood species were Pinusdensiflora, Zelkova serrata, Quercus acutissima and Camellia japonica. The obtained results were summarized as follows; Chemical analysis showed that lignin content was increased, whereas the amout of holocellulose was heavily decreased in the degraded archaeological lwoods(DAW), when compared to the recent woods. The amount of alkalineextractives in the DAW was extremley high. IR spectra showed that disappearance of absortion band at $1,730㎝^-1$ intensity increase at 1,600, 1,500 and $1,270㎝^-1$ and the emergence of single band around $1,050㎝^-1$.Microscopic investigation showed that cell wall of latewood tracheids and fiber in the DAW were severely degraded while, early wood tracheids less degraded. Degradation in the cell wall was mainley occurred in $S_2$layer, while the middle lamella was the least degraded. The micro morphological characteristics of DAW were separation of secondary wall from middle lamella, cavities aligned with micro fibril angle in $S_2$layer and granular appearance of secondary wall by the bacterial attack.

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Ultrastructural Observation of Bacterial Attacks on the Waterlogged Archaeological Woods (세균에 의한 수침고목재 피해양태의 초미시구조적 관찰)

  • Kim, Y.S.;Choi, J.H.;Bae, H.J.;Nilsson, T.;Daniel, G.
    • Journal of Conservation Science
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    • v.1 no.1 s.1
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    • pp.3-11
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    • 1992
  • Micromorphological changes in waterlogged archaeological woods excavated from Sweden and Germany were investigated. Especially bacterial attacks on those wood samples under near anaerobic conditions were examined by transmission electron microscopy(TEM). The major feature of micromorphological alterations in those wood samples was the preferential destruction of secondary wood cell wall. In contrast, the middle lamella was not extensively degraded. Three distinct degradation patterns by bacteria were observed : erosion, cavitation and tunnelling bacteria. Erosion and cavitation bacteria attacked primarily $S_2$ layer, whereas tunnelling bacteria made the tunnel-like degradation along the $S_1$ layer. Tunnelling bacteria, in some samples, were able to degrade tunnel in the lignin-rich areas, such as middle lamella, suggesting that these bacteria had the capacity to degrade the lignin. IR spectra indicate that hemicellulose and cellulose in the waterlogged woods were preferentially decomposed. Breakdown of the lignin, on the other hand, was much slower.

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Alteration of Physical and chemical Characteristics of Waterlogged Archaeological Woods After Cleaning (세척 후 수침고목재의 물리.화학적 특성 변화)

  • Cha, Mi-Young;Lee, Kwang-Ho;Kim, Yoon-Soo
    • Journal of Conservation Science
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    • v.19
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    • pp.19-30
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    • 2006
  • Alteration of physical and chemical characteristics and the effect of removal of mineral substances in waterlogged archaeological woods by different cleaning processes were examined using oak wood(Quercus spp.) that was excavated from wetland near Gwangju, Korea. Cleaning methods employed in the present work were (1) tools, (2) deaeration, (3) EDTA and (4) ultrasonic cleaning, which are being currently applied in the field of preservation treatment. Cleaning process were performed independently or continuously. Composition of mineral substances in the waterlogged archaeological wood was almost same as the that of soil in which waterlogged archaeological woods were buried. In case of independent cleaning, tools cleaning efficiently removed the mineral substances on surface. Surface color become brighter after cleaning with EDTA. In contrast, deaeration and ultrasonic cleaning did not show any significant removal of mineral substances. In continuous cleaning process, tool cleaning as the first step treatment showed the same effect as shown in independent cleaning. Although deaeration as the second step cleaning did not remove the mineral substances, it could be assumed to contribute the infiltration of dimensional agents by homogenization of wood. EDTA treatment (the third step cleaning) removed the iron(Fe) and increased the whiteness of wood color. The ultrasonic treatment (the fourth step cleaning) removed the sodium(Na) remained after EDTA treatment and the fine mineral substances.

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A study on the Investigation and Removal the Cause of Blacken Effect of Waterlogged archaeological woods (수침고목재의 흑화 원인과 제거방법에 관하여)

  • Yang, Seok-jin
    • Korean Journal of Heritage: History & Science
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    • v.40
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    • pp.413-430
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    • 2007
  • This study analyzed the foreign substances in waterlogged archaeological woods and compounds in soil where waterlogged archaeological wood was buried, in order to examine the relationship between burial environment and foreign substances in waterlogged archaeological wood. The XRF(X-ray Fluorescence Spectroscopy) and EDX(Energy Dispersive X-ray) analysis were conducted to examine the effect of iron(Fe) to blacken the waterlogged wood. The XRF results showed that investigated soil contained Si, Al, and Fe. Wood ash contained more sulfur and Fe than any other elements in the EDX analysis. Cellulose and hemicellulose were significantly reduced at the surface of wood, which is the blackened part of waterlogged wood. Foreign substances changed the surface color. These problems could be solved by removal of foreign substances in waterlogged archaeological wood using EDTA(Ethylene Diamine Tetra Acetic acid). The optimum condition to remove Fe from waterlogged wood by EDTA was investigated. To do this, the concentration of Fe removed was measured with various concentration of EDTA-2Na. The optimum pH of EDTA-2Na was figured to be 4.1 to 4.3. As the concentration of EDTA increased, the extracted concentration of Fe also increased. In the case of 0.4 wt% of EDTA-2Na, about 60ppm of Fe was eliminated and was stabilized after 48 hours. In the case of EDTA-3Na, the optimum pH was 7 to 8, and about 10 ppm of Fe was eliminated at 0.4 wt% of EDTA-3Na. In the case of EDTA-4Na, the optimum pH was 10 to 11, and about 20 ppm of Fe was eliminated at 0.4 wt% of EDTA-4Na. In conclusion, the iron(Fe) in waterlogged archaeological wood was removed by EDTA treatment and it increased the whiteness of the surface.

Reconstruction of Vegetation During $9^{th}$ Century in Southern Korea: Anatomical and Dendrochronological Analysis of Waterlogged Woods Excavated at Cheonghea-jin Fort

  • Han, Sang-Hyo;Park, Won-Kyu;Kim, Yo-Jung;Jung, Suk-Bae
    • The Korean Journal of Quaternary Research
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    • v.17 no.2
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    • pp.117-122
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    • 2003
  • This study is conducted to examine the woods that were excavated at Jangdo Island. The Jangdo site is located in a small island some 180 meters away from the main island of Wando, Jeollanam-do in southern Korea. This site is known as Cheong-Hea Jin fort for the marine King Jang Bogo during the early 9$^{th}$ century. Total of 101 specimens were collected in three groups; small-size piles, log fences (Mok-check) and logs from a well. The species of the group of piles consisted of Quercus spp. (43%), Pinus densiflora (29%), Pinus koraiensis (5%), Alnus japonica (3%), Fraxinus spp. (3%), Styrax obassia (3%), Juglans spp. (2%), Zelkova serrata (2%), Platycarya strobilacea (2%), Celtis spp. (2%), Torreya nucifera (2%), Quercus myrsinaefolia (2%), and Cinnamomum spp. (2%). The species of Mok-check and logs from the well were identified as all Pinus densiflora. The species composition indicated that the climate around A. D. 9th-10th century in southern Korea was similar to the present.. The wooden fences were also examined for tree-ring analysis. The ages of woods were 50∼60 years. We made two site chronologies. The chronologies indicated that southeastern and southwestern fences were repaired frequently. The results could not give the absolute dates due to lack of reference chronologies in this period.

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Studies on the Restoration of Ancient Bridge Setakarahashi -Conservation and Display for Large Size Waterlogged Wood- (고대 세다당교의 보존처리 - 대형출토목재의 보존과 전시 -)

  • NAKAGAWA, Masato
    • Journal of Conservation Science
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    • v.5 no.2 s.6
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    • pp.51-56
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    • 1996
  • This paper deals with the restoration of ancient wooden bridge foundation which excavated in Seta river Shiga Prefecture, Japan. Shiga Archeological Research started a marine archeological investigation of the bridge foundation in 1987. The bridge foundation stricture excavated and have since then recovered about a lots of woods and another materials. The bridge foundation structure constructed log, timbers and stones. The species of those waterlogged wood were identified as two types, hardwood and softwood. Hardwood(log : Cyclobalanopsis) was used for below foundation and softwood (timber' Chamaecyparis obtusa Endl. Cupreessaceae) was used for base structure. One of those timber sample dated by dendrochronology, we asked Dr. Misutani*. The softwood gave a felling date of 567 A.D. In result, the ancient Seta bridge foundation structure had constructed between Asuka and Nara period. We healed the news that ancient bridge foundation excavated at Woljyongyo site in Kyongju, Korea 1987. The bridge foundation Setakarahashi is similar in plane and structure to Woljyongyo structures. The Woljyongyo site report had be of value for reference. We had planning to restore those woods. Hardwood log was got serious damage. The water content varies from 400 to $600\%$. The other timbers water content varies about $200\%$. In the Shiga Center for Archaeological Operations and the Azuchi Castle Archaeological Museum, we set up the PEG impregnation tank. Those wooden objects treated by PEG method. PEG with a molecular weight of 4000. The treatment results may be considered satisfactory. The ancient wooden Seta bridge was reconstructed in Biwako Museum which established in Oct. 1996. We must take care of indoor exhibition environments. (*Nara National Cultual Properties Research Institute).

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Heritage of the Maritime Silk Route: Wrecks of Asian Traders and Ports

  • Jun KIMURA
    • Acta Via Serica
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    • v.9 no.1
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    • pp.1-32
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    • 2024
  • The archaeological remnants of coastal ports and shipwrecks serve as invaluable heritage sites that provide profound insights into historical maritime activities conducted by humans. Cross-regional voyages occurred as early as the beginning of the first millennium, aided by the increasing knowledge of the monsoons. Along with expanding intra- and inter-sailing routes, the improved seaworthiness of vessels facilitated the movement of people and seaborne commodities. The names of the Indic, Kunlun, and Persian ships appear in various historical accounts written in the latter half of the first millennium, and the structural details and characteristics can be physically examined by looking at shipwrecks. Southeast and East Asian shipwrecks from the eighth to the fourteenth century provide a perspective on the dynamism of types of seagoing ships involved in long-distance trade. By examining the remnants of cargo being transported by these ships, we begin to understand how the system of cross-regional shipment of heavy and bulky items, metal objects, fragrant woods, glass, and ceramics sustained and impacted the religions, societies, culture, and regional economies. Furthermore, it helps define the Maritime Silk Route heritage to be managed and protected. As such, this paper gives the archaeological evidence of port ruins and wrecks and also introduces, as an example, a case from Central Vietnam.

A Study on the Dimensional Stability of Archaeological Waterlogged Salix koreensis Andersson Treated with Recycled PEG (재활용 PEG를 이용한 수침 고버드나무의 치수안정화 연구)

  • Yang, Seok-Jin;Lee, Soo;Kim, Jong-Hwa
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.4
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    • pp.635-641
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    • 2014
  • Archaeological waterlogged woods require a process of dimensional stabilization for their conservation. PEG is the most widely used in the conservation of archaeological waterlogged wood. One of the easiest and commonly used methods is the impregnation of 40% polyethylene glycol followed by vacuum freeze drying. However, the waste fluid produced from the PEG treatment is black in color and has a severe odor due to the organic matter extracted from the wood. Thus It cannot be recycled and it was just thrown out. Color of waste fluid can be decolored with oxidation reaction by hydrogen peroxide. Properties of PEG before and after preservation treatment, and after oxidation with $H_2O_2$ were not changed. Dimensional stability of archaeological waterlogged Salix koreensis Andersson was studied with pure or recycled PEG. The ratio of impregnation solutions were 10:0, 7:3, 5:5, 3:7, 0:10 (pure PEG : recycled PEG). Impregnation process was carried out by putting the wood specimens 10% PEG solution for 5days, 20% for 5 days, 30% for 5 days finally 40% for 5 days. All of the specimens showed the weight change rate of 25%. SEM results provided that the dimensional change of were less than 4% PEG impregnated specimens. Comparing with pure PEG impregnation system, conservation precess mixed PEG also showed no significant changes. Conclusively, the recycled PEG can be used for archeological waterlogged wood conservation precess.