• Title/Summary/Keyword: arc temperature

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Effect of Si on the High Temperature Oxidation of TiAl Alloys (Si 첨가가 TiAl 합금의 내산화성에 미치는 영향)

  • 김성훈;김승언;최송천;이동복
    • Journal of Surface Science and Engineering
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    • v.33 no.1
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    • pp.3-9
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    • 2000
  • Arc-melted alloys of TiAl-(o.25, 0.5, 1.0at%) Si were isothermally oxidized at 800, 900 and $1000^{\circ}C$ in air for 60hr. It was found that the oxidation resistance of the prepared TiAl-Si alloys was much better than that of pure TiAl, being progressively increasing with an increase in the Si content. This was attributed to the formation of $SiO_2$in addition to ($TiO_2$+$Al_2$$O_3$) oxides which formed in TiAl alloys with and without silicon additions. However, the silica formation within the oxide layer unfortunately accelerated the oxide scale spallations. During oxidation, all the elements in the base alloy diffused outward, whereas oxygen from the atmosphere diffused inward. The oxides were primarily composed of an outer thick $TiO_2$layer, an intermediate diffuse $Al_2$$O_3$layer and an inner $TiO_2$layer. A small amount of $SiO_2$was present all over the oxide scale and some voids were found around the intermediate layer.

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Hydrogen Permeation Properties of $(Ni_{60}-Nb_{40})_{95}-Pd_5$ Amorphous Metallic Membrane ($(Ni_{60}-Nb_{40})_{95}-Pd_5$ 비정질 금속막의 수소투과 특성)

  • Lee, Dock-Young;Kim, Yoon-Bae
    • Journal of Hydrogen and New Energy
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    • v.19 no.4
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    • pp.359-366
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    • 2008
  • Hydrogen as a high-quality and clean energy carrier has attracted renewed and ever-increasing attention around the world in recent years, mainly due to developments in fuel cells and environmental pressures including climate change issues. In this processes for hydrogen production from fossil fuels, separation and purification is a critical technology. $(Ni_{60}-Nb_{40})_{95}-Pd_5$ alloy ingots were prepared by arc-melting the mixture of pure metals in an Ar atmosphere. Melt-spun ribbons were produced by the single-roller melt-spinning technique in an Ar atmosphere. Amorphous structure and thermal behavior were characterized by XRD and DSC. The permeability of the $(Ni_{60}-Nb_{40})_{95}-Pd_5$ amorphous alloy membrane was characterized by hydrogen permeation experiments in the temperature range 623 to 773 K and pressure of 2 bars. The maximum hydrogen permeability was $3.54{\times}10^{-9}[mol{\cdot}m^{-1}s^{-1}{\cdot}pa^{-1/2}]$ at 773 K for the $(Ni_{60}-Nb_{40})_{95}-Pd_5$ amorphous alloy.

Evaluation Method I of the Small Current Breaking Performance for SF(sub)6-Blown High-Voltage Gas Circuit Breakers (초고압 $SF_6$ 가스차단기의 소전류 차단성능 해석기술 I)

  • 송기동;이병운;박경엽;박정후
    • The Transactions of the Korean Institute of Electrical Engineers B
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    • v.50 no.7
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    • pp.331-337
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    • 2001
  • With the increasing reliability of analysis schemes and the dramatically increased calculating speed, the computer simulation has become and indispensable process to predict the interruption capacity of circuit breakers. Generally, circuit breakers have to possess both the small current and large current interruption abilities and the circuit breaker designers need to evaluate its capacities to save the time and the expense. The analysis of small current and the large current interruption performances have been considered separately because the phenomena occurring in a interrupter are quite different. To analyze the dielectric recovery after large current interruption many physical phenomena such as heat transfer, convection and arc radiation, the nozzle ablation, the ionization of high temperature SF(sub)6 gas, the electric and themagnetic forces and so forth mush be considered. However, in the analysis of small current interruption performance only the cold gas flow analysis needs to be carried out because the capacitive current is to small that the influence from the current can be neglected. In this paper, an empirical equation which is obtained from a series of tests to estimate the dielectric recovery strength has been applied to a real circuit breaker. The results of analysis have been compared with the test results and the reliability has been investigated.

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Sticking Characteristics in Bi2Sr2CanCun+1Ox Thin Films Fabricated by using the Evaporation Method to Improve the Sticking Ratio (부착율 개선을 위해 증발 법으로 제작한 Bi2Sr2CanCun+1Ox 박막의 부착 특성)

  • 천민우;박용필
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.11
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    • pp.1029-1034
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    • 2003
  • The Bi$_2$Sr$_2$Ca$_{n}$Cu$_{n+1}$ O$_{x}$, superconducting thin films arc fabricated by using the sputtering and evaporation method. Because we confirmed the sticking ratio of Bi element in the Bi$_2$Sr$_2$Ca$_{n}$Cu$_{n+1}$ O$_{x}$ superconducting thin film fabricated by using the sputtering method was much lower than the expected value, to get the enough number of the flakes of Bi, faraday cup was used to evaporate Bi clement. As a result of the fabrication, Bi 2201 and Bi 2212 single phases could be made by the optima of deposition condition. And we confirmed the sticking coefficient of Bi element was clearly related to the temperature change of the substrate and the generation of Bi22l2 phase

Silicon Solar Cell Efficiency Improvement with surface Damage Removal Etching and Anti-reflection Coating Process (표면결함식각 및 반사방지막 열처리에 따른 태양전지의 효율 개선)

  • Cho, Chan Seob;Oh, Jeong Hwa;Lee, Byeungleul;Kim, Bong Hwan
    • Journal of the Semiconductor & Display Technology
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    • v.13 no.2
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    • pp.29-35
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    • 2014
  • In this study general solar cell production process was complemented, with research on improvement of solar cell efficiency through surface structure and thermal annealing process. Firstly, to form the pyramid structure, the saw damage removal (SDR) processed surface was undergone texturing process with reactive ion etching (RIE). Then, for the formation of smooth pyramid structure to facilitate uniform doping and electrode formation, the surface was etched with HND(HF : HNO3 : D.I. water=5 : 100 : 100) solution. Notably, due to uniform doping the leakage current decreased greatly. Also, for the enhancement and maintenance of minority carrier lifetime, antireflection coating thermal annealing was done. To maintain this increased lifetime, front electrode was formed through Au plating process without high temperature firing process. Through these changes in two processes, the leakage current effect could be decreased and furthermore, the conversion efficiency could be increased. Therefore, compared to the general solar cell with a conversion efficiency of 15.89%, production of high efficiency solar cell with a conversion efficiency of 17.24% was made possible.

High temperature air-oxidation of CrAlSiN thin films (CrAlSiN 박막의 대기중 고온산화)

  • Hwang, Yeon-Sang;Won, Seong-Bin;Chunyu, Xu;Kim, Seon-Gyu;Lee, Dong-Bok
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2013.05a
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    • pp.53-54
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    • 2013
  • Nano-multilayered CrAlSiN films consisting of crystalline CrN nanolayers and amorphous AlSiN nanolayers were deposited by cathodic arc plasma deposition. Their oxidation characteristics were studied between 600 and $1000^{\circ}C$ for up to 70 h in air. During their oxidation, the amorphous AlSiN nanolayers crystallized. The formed oxides consisted primarily of $Cr_2O_3$, ${\alpha}-Al_2O_3$, $SiO_2$. The outer $Al_2O_3$ layer formed by outward diffusion of Al ions. Simultaneously, an inner ($Al_2O_3$, $Cr_2O_3$)-mixed layer formed by the inward diffusion of oxygen ions. $SiO_2$ was present mainly in the lower part of the oxide layer due to its immobility. The CrAlSiN films displayed good oxidation resistance, owing to the formation of oxide crystallites of $Cr_2O_3$, ${\alpha}-Al_2O_3$, and amorphous $SiO_2$.

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Characteristics of GMA Weld Zone on TiO2 Different Component Flux Cored Wire for S500 Grade Steel (TiO2 성분 플럭스충진와이어에 따른 S500강의 GMA 용접부 특성)

  • Yoo, Cheol;Ko, Young-Bong;Park, Kyeung-Chae
    • Journal of Surface Science and Engineering
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    • v.48 no.6
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    • pp.335-342
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    • 2015
  • Recently, the production of oil and gas at the arctic ocean and offshore has been growing. Accordingly, S500 steel with the high tensile strength and excellent toughness has been used and flux cored wire that can be welded to the S500 has been required. In this study, we carried out observation of microstructures, mechanical properties and CTOD (crack tip openning displacement) in the weld zone that GMA (gas metal arc) welded with different component of $TiO_2$ flux core wire (the main components, rutile or Ti-slag) for S500 steel. Weld zone produced with Ti-slag flux cored wire has formed a enough acicular ferrite and shown excellent impact toughness at $-40^{\circ}C$, tensile strength at room temperature and CTOD at $-20^{\circ}C$. As a result, the developed flux cored wire was suitable for S500 steel.

A Study of the Effects on the Structural Strength by Change of Spot Welding Pitch (점용접의 간격 변화에 의한 구조 강성 영향 평가 연구)

  • Hong, Min-Sung;Kim, Jong-Hyun
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.19 no.4
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    • pp.511-520
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    • 2010
  • In general, spot welding is used at no welding rod or flux for the process, low welding point temperature compared to arc welding, short heating time, less damage to the parent material, and low deformation and residual stress, relatively. Also, because of the pressurization effect, better mechanical qualities of the welding parts are obtained. Therefore, in various fields of industry its rapid operation speed can make mass production possible such as motor industry. In FEM analysis for the spot welding process, it is effective to use simple modeling rather than complicated one because of its numerous number of spots and reduction of analysis time. Therefore, this study provides with not only simplification of modeling analysis by using beam component composition of structure without re-compositing the spot welding point mesh but also modeling analysis of which property of fracture strength is reflected. In addition complete spot welding model is examined at rectangular post shape (hat shape) by impact test, compared the results, and verified its validity. As a result, it is possible to optimize the welding position and to recognize the strength of structure and the proposed equal distance model shows the effect of welding point reduction and improvement of stiffness.

A study on the application of the IEC61850 based eCMD convergence structure in Digital Substation (IEC61850 기반 디지털 변전시스템에서의 eCMD 융합화구조 적용에 관한 연구)

  • Lee, D.C.;Kim, H.S.;Bae, U.L.;Min, B.W.
    • Proceedings of the KIEE Conference
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    • 2006.07e
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    • pp.19-22
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    • 2006
  • The CMD(Condition Monitoring & Diagnosis) System is used to monitor and analyze the PD(Partial Discharge), Arc, Temperature, Pressure, Gas in Oil and so on for reliability and availability of the substation. Although this system comes into the spotlight as the forecast and management of the failure and fault, there are some problems. For example, the unified standard was not defined, and the effective management of the layed communication network does not performed, limitation of physical space, etc. To resolve above problems, this paper suggests the IEC61850 compatible eCMD system architecture for monitoring and analyzing the CMD factor in substations. The suggested eCMD system consists of CMD-LU(Condition Monitoring & Diagnosis-Local Unit), IED(Intelligent Electronic Device), and engineering centers. The IEC61850 is the international standard that defines communication networks and system in substation.

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Aging Behaviors of a Rapidly Solidified AI-Li-Cu Alloy (급냉응고된 Al-Li-Cu 합금의 시효거동)

  • Hong, Y.J.;Kim, S.H.;Kang, M.C.;Kim, I.B.
    • Journal of the Korean Society for Heat Treatment
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    • v.6 no.3
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    • pp.138-143
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    • 1993
  • Effects of aging treatment on the microstructural evolution of a rapidly solidified Al-Li-Cu alloy were investigated by differential scanning calorimetry (DSC) and transmission electron microscopy(TEM). It was found that the precipitation sequence was: supersaturated solid solution ${\alpha}^{\prime}$ ${\rightarrow}$ metastable ${\delta}^{\prime}$ + stable precipitate $T_1$ ${\rightarrow}$ stable precipitates ${\delta}+T_1$. Two exothermic and two endothermic peaks are detected by DSC analysis. The two exothermic and endothermic peaks corresponded to ${\delta}^{\prime}$ and ${\delta}+T_1$ precipitation and dissolution reactions respectively. The enthalpy of ${\delta}^{\prime}$ precipitation decreased with increasing of aging temperature and time until the finishing point of precipitation. The activation energy for precipitation of ${\delta}^{\prime}$ was measured as 80KJ/mol and the energy for dissolution was 93KJ/mol. These values arc higher than those of AI-Li binary alloy. Peak hardness value (Hv 170) was obtamed at $210^{\circ}C$ for 1hr aging treatment which coincided with finishing point of ${\delta}^{\prime}$ precipitation.

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