• Title/Summary/Keyword: apparatus

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Analysis of Amine Absorbents Volatility Based on the Chemical Structure (아민 흡수제의 화학구조에 따른 휘발 특성)

  • Lee, Kyung Ja;Lee, Ji Hyun;Kwak, No Sang;Lee, In Young;Kim, Jun Han;Eom, Yong Seok;Jang, Kyung Ryoung;Shim, Jae Goo;Lee, Yongtaek
    • Korean Chemical Engineering Research
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    • v.50 no.2
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    • pp.348-352
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    • 2012
  • Amine volatility occurring on the $CO_2$ capture process may result in significant economic losses and environmental impact. In this study, using an volatility measurement apparatus, we measured a amine volatility of various amines including MEA(Monoethanolamine), MDEA(N-Methyldiethanolamine), Pz(Piperazine), AMP(2-Amino-2-methyl-1-propanol), 2-MP(2-Methylpiperazine), DGA(Diglycolamine). For the quantitative analysis of volatility, we analyzed the effects of temperature and $CO_2$ loading using an gas chromatography analysis. The result shows that the amine volatility was increased by increasing Henry's constant(MDEA$-CH_3$)(for AMP).

The Measurement and Prediction of the Combustible Properties of of Benzyl-Alcohol for MSDS (Material Safety Data Sheet) (MSDS (Material Safety Data Sheet)를 위한 벤질알코올 연소특성치의 측정 및 예측)

  • Ha, Dong-Myeong
    • Korean Chemical Engineering Research
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    • v.55 no.2
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    • pp.190-194
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    • 2017
  • The combustion properties for the prevention of the fire and explosion in the work place are flash point, explosion limit, autoignition temperature (AIT) etc.. The using of the corrective combustion properties of the MSDS (Material Safety Data Sheet) of the handling substance for the chemical process safety is very important. For the safe handling of benzyl alcohol which is widely used in the chemical industry, the flash point and the AIT were measured. And, the lower explosion limit (LEL) of benzyl alcohol was calculated by using the lower flash point which obtained in the experiment. The flash points of benzyl alcohol by using the Setaflash and Pensky-Martens closed-cup testers measured $90^{\circ}C$ and $93^{\circ}C$, respectively. The flash points of benzyl alcohol by using the Tag and Cleveland open cup testers are measured $97^{\circ}C$ and $100^{\circ}C$. The experimental AIT of benzyl alcohol by ASTM 659E tester was measured as $408^{\circ}C$. The LEL of benzyl alcohol measured by Setaflash closed-cup apparatus was calculated as 1.17 vol% at $90^{\circ}C$. In this study, it was to possible predict the LEL by using the lower flash point of benzyl alcohol which measured by Setaflash closed-cup tester.

Changes of Volatile Odor Components in Onion by Freeze-drying (동결건조에 의한 양파의 휘발성 향기성분의 변화)

  • Kim, Jun-Hyoung;Seo, Hye-Young;No, Ki-Mi;Han, Byung-Jae;Lee, Seong-Jin;Seo, Yu-Seog;Kim, Kyong-Su
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.34 no.2
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    • pp.230-235
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    • 2005
  • Volatile organic components from fresh and freeze-dried onions were extracted by SDE apparatus and analyzed by GC/MS. Components of 40 and 31 were identified in fresh and freeze-dried onions respectively. These components included esters, aldehydes, ketones, alcohols and S-containing compounds. Major compounds of S-containing compounds such as 1-propanethiol, dipropyl trisulfide, and methyl propyl trisulfide in fresh onions were clearly decreased in freeze-dried onions. Then, S-containing compounds such as methyl allyl sulfide, propyl ally sulfide, dially disulfide and 3,5-diethyl-l,2,4-trithiolane and alcohols such as pentanol, hexanol and propanol were disappeared by freeze-drying. Exceptionally, ethyl acetate, dimethyl disulfide and 2-methyl-2-pentenal were increased as different trend with major S-containing compounds. (Z)-Propenyl methyl disulfide and (E)-propenyl methyl disulfide were also changed by freeze-drying in the similar pattern as mentioned above compounds.

Condensation Heat Transfer Characteristics of R-410A as an Alternative R-22 in the Condenser with Small Diameter Tubes (세관을 사용한 응축기에서 R-22의 대체냉매인 R-410A의 응축 열전달 특성)

  • Son, Chang-Hyo
    • Clean Technology
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    • v.13 no.2
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    • pp.151-158
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    • 2007
  • An experimental study to investigate the condensing heat transfer characteristics of small diameter horizontal double pipe heat exchangers with R-22 and R-410A was performed. Experimental facility was constructed to calculate and observe HTC(heat transfer coefficients), flow patterns and pressure drop. The main components include a liquid pump, an evaporator, a condenser(test section), a sight-glass, pressure taps and measurement apparatus. Two pipes of different diameters are tested; One 5.35 mm ID 0.5 mm thick, the other 3.36 mm ID 0.7 mm thick. The mass flow rate ranged from 200 to $500\;ks/m^2{\cdot}s$ and heating capacity were form 1.0 to 2.4 kW. The flow patterns of R-22 and R-410A were observed with a high speed camera through the sight-glass. The tests revealed that HTC of R-410A was higher than that of R-22 by maximum 5%. Annular pattern was observed for the most cases but stratified flow was also detected when x<0.2. The pressure drop in 3.36 mm ID pipe was higher than that of 5.35 mm by $30{\sim}50%$. Comparing with previous correlations such as Shah, Fujii and Soliman's, Fujii' showed the best good agreement with my data with a maximum deviation of 40%.

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A Study on the Effects of Magnetic Field and BEP on Hyperlipidemia and Enzymatic Activities in Rats (자기장(磁氣場) 및 BEP 조사(照射)가 식이성(食餌性) 고지혈증(高脂血症)이 유발(誘發)된 흰쥐에 미치는 영향(影響)에 대(對)한 연구(硏究))

  • Koh, Kwang-chan;Lee, Cheol-wan
    • Journal of Haehwa Medicine
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    • v.8 no.1
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    • pp.559-592
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    • 1999
  • It has been known that Ki(氣) energy is very effective on many adult diseases. Oriental Medicine has acknowledged Ki as an existing reality and investigated its effects on the body. However, the existence of Ki has not been fully explained. In order to find a conclusive evidence on the existence of Ki, this experiment was done to study the mutual relationship of Ki with a magnetic field and BEP (biological energy projector). The BEP apparatus was irradiated under the magnetic field on rats in the hyperlipidemic induced state. Following criterias were measured in this experiment: weight change, weight of the visceral organs, serum, hepatic lipid peroxide, bleeding time, tissue factor, and etc. The following results were obtained in this study: 1. The weight of rat significantly decreased in the magnetic field treated group and radically reduced in the group treated with both magnetic field and BEP. 2. The weight of liver, heart, and kidney increased in both the magnetic field treated group and magnetic field+BEP group compared to the normal group, but decreased in comparison to the control group. No changes were witnessed in the weight of spleen. 3. Serum and hepatic total cholesterol, total lipid, and lipid peroxide level significantly decreased in both magnetic field treated group and magnetic field+BEP treated group, while lipase activity has increased noticeably. 4. Serum HDL showed a significant increase in both magnetic field treated group and magnetic field+BEP treated group compared to the control group, while LDL and VLDL level decreased significantly. 5. A bleeding time significantly increased in both magnetic field treated group and magnetic field+BEP treated group compared to the control group. A tissue factor value of the lung decreased in the magnetic field treated group and magnetic field+BEP treated groups while increased in the control group. 6. Serum and hepatic lipid peroxide and glutathione level were significantly decreased in the magnetic field treated group and magnetic field+BEP treated group, while hepatic glutathione level was significantly increased compared to the control group. 7. A significant increase was found in the serum hydroxyl radical and SOD activity in the dietary hyperlipidemic rats, and significant decrease was found in the serum lipid peroxide content and superoxidase activity. 8. Hepatic cytosolic enzyme xanthine oxidase and aldehyde oxidase showed a significant decrease in the magnetic field treated group and magnetic field+BEP treated group. Through the above experimental results, one can suggest that the magnetic field with BEP can suppress hyperlipidemia and boost lipid metabolism and restructuring a lipid in liver, which increases the function of liver. To conclude, BEP is considered to show more potent effects under the exposure of magnetic field because magnetic field seems to increase the flow of Ki in the body.

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Effect of Surfactant Addition on Se Absorption and Growth of Pak-choi and Leaf Lettuce in Hydroponics (수경 재배 시 계면 활성제 첨가가 상추와 청경채의 생육과 Se 흡수에 미치는 영향)

  • Yuna, Hyung-Kwon;Seo, Tae-Cheol;Zhang, Cheong-Hao;Chun, Chang-Hoo
    • Journal of Bio-Environment Control
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    • v.18 no.2
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    • pp.124-131
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    • 2009
  • Surfactant polyvinyl alcohol (PVA-95) 1, 2, 4mg. $L^{-1}$ and calcium lignosulfonate (CLS) 5, 25, 50, 100mg. $L^{-1}$ were treated to the nutrient solution containing 1.0mg. $L^{-1}$ selenium (Se) to evaluate Se absorption effect using small DFT apparatus. The growth of leaf lettuce and pak-choi did not show unique significance by surfactant kinds and concentration in the tested range and physiological disorder. Vitamin C in leaves of two leafy vegetables was not significantly affected by surfactants also. Among major cations K content in pak-choi was highest in Se I+PVA-95 4mg. $L^{-1}$ treatment, and high in Se I+CLS 5 mg. $L^{-1}$ treatment. Ca content in two leafy vegetables showed increasing pattern by the two kinds of surfactants. Mg content was high in Se I+CLS 25mg. $L^{-1}$ treatment compared to control. Pak-choi absorbed Se about 10 times higher than leafy lettuce. Se content in leaves of two leafy vegetables increased by the treatment of two kinds of surfactants with the exception of CLS 100mg. $L^{-1}$ treatment.

Effect of $\gamma$-Irradiation of Volatile Organic Compounds of Houttuynia cordata Thunb. (방사선 조사에 의한 어성초의 휘발성 유기성분 변화)

  • Ryu, Keun-Young;Shim, Sung-Lye;Jung, Min-Seok;Jun, Sam-Nyeo;Jo, Cheor-Un;Song, Hyun-Pa;Kim, Kyong-Su;Kim, Youn-Soon
    • Food Science and Preservation
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    • v.15 no.3
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    • pp.411-420
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    • 2008
  • This study was performed to examine the effect of $\gamma$-irradiation on the volatile organic compounds in Houttuynia cordata Thunb.(H. cordata). 1be volatile compounds of non-irradiated and 10 kGy $\gamma$-irradiated H. cordata were isolated using SDE apparatus and analyzed by GC/MS. For each treatment the number of volatile compounds were detected at 83 and 85, respectively, 1be predominant functional groups of volatile organic compounds from H. cordata were identified as alcohols and ketones. H. cordata was mainly composed of hexahydrofarnesyl acetone (12.81 %), phytol, decanoic acid, dodecanoic acid, octadecanol, caryophyllene oxide, 2-undecanone and menthol. Houttuynum which is characteristic compound of H. cordata was found in all samples and there was no significant difference with irradiation doses. Consequently, $\gamma$-irradiation of H. cordata would be an effective process for sanitation and to increase extraction efficiency.

Study of Mechanical Characteristics of Electric Cupping Apparatus in Korea for Suggestion of its Assessment Guideline (국내 평가 가이드 라인 제시를 위한 전동식 부항기의 특성 조사에 관한 연구)

  • Yi, Seung-Ho;Kim, Eun-Jung;Shin, Kyung-Hoon;Nam, Dong-Woo;Kang, Jung-Won;Lee, Seung-Deok;Lee, Hye-Jung;Lee, Jae-Dong;Kim, Kap-Sung
    • Journal of Acupuncture Research
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    • v.27 no.1
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    • pp.1-10
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    • 2010
  • Objectives : The mechanical properties of Korean electric cupping systems are studied via experimental measurements. The study aimed at establishing the fundamentals of industrialization and systemization of oriental medicine device industry, as well as improving the quality of life for many Koreans. Methods : We reviewed the studies on traditional cupping as well as modern one to fine necessary factors for electric cupping systems. To characterize the mechanical properties of Korean electric cupping systems, we measured the pressure characteristics of commercially available electric cupping system by using an automatic pressure acquisition system and a standard cup. The pumping capability was checked at 40 seconds, and the stability of the suction cup was checked at 600 seconds. We also acquired the noise level of each system in clinical setting. To check the portability of each system, we also measured its physical dimensions. We scrutinized system manuals provided by the system manufacturers. Results : It took less than 5 second to reach the pressure if the connection between the air hose and the vacuum valve of the cupping system was secure. Pressure diminished to no more than 10% for 600s for all systems. Noise levels were 55~70 dB. Increase in pressure was too fast to control for a designated vacuum level except for one product. Conclusions : The Pumping ability of the systems is impressive and reliable. Pressure retention ability of each cup is quite reliable and reproducible. Therefore, their mechanical performances were worthy of recommendation. Some of them had noise level higher than 60 dB and they were bothersome. It was also suggested that the control for low to middle pressure needed to be accomplished by the cupping system.

Analysis of Visitor's Satisfaction Factors and Determinants in Naejangsan National Park, Korea (내장산국립공원의 탐방객 만족요인 및 예측모형 분석)

  • Kim, Dong-Pil;Baek, Jae-Bong
    • Korean Journal of Environment and Ecology
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    • v.25 no.4
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    • pp.614-620
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    • 2011
  • The purpose of this study was to provide basic data for developing the practical park management. For this, satisfaction degree, satisfaction factors and estimated model by satisfaction variables of visitors analyzed through a questionnaire survey in Naejangsan National Park, Korea. In the evaluation of the satisfaction, variables of 'Lack of public facility'. 'Lack of use program', 'Lack of facility to stay' 'Charge of user fee, parking fee' and 'Exorbitant pay' at Naejangsan park office and 'Charge of user fee, parking fee', 'Lack of use program' and 'Lack of facility to stay' at Baekam park office was more unsatisfied than any other variable. Satisfaction factors by Factor Analysis were loaded with 'Facility management' at Naejangsan park office(34.3%) and 'user management' at Baekam park office(45.6%) by the highest contribution degree. In estimated model of satisfaction by Multiple Regression Analysis showed in order of 'damage of trail', 'Lack of commercial facility', and 'Littering problem' at Naejangsan park office and 'damage of cultural and historic resource', 'Lack of commercial facility', 'Touting' at Baekam park office. So, Naejangsan National Park needed intensive management policy and institutional apparatus for facility management and user education.

A Study of $C_9$-aldehyde Synthesis from n-Butene (노르말부텐으로부터 $C_9$-알데히드 합성에 관한 연구)

  • Jeon, Jong-Ki;Park, Seong-Ki;Park, Young-Kwon
    • Clean Technology
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    • v.14 no.3
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    • pp.176-183
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    • 2008
  • The purpose of this study is to upgrade the catalysts for synthesizing mixed octenes using normal butene and the catalysts for synthesizing $C_9$-aldehyde through hydroformylation of mixed octenes with syngas. The in-line activation method with circulating activating solution was effective for activation of the $NiO/A1_{2}O_3$ catalyst. The reason for catalyst deactivation may be ascribed to physi-sorbed materials or oligomers which block pore entrance and then prevent active sites from participating a reaction. Continuous distillation apparatus was used for separating mixed octenes from dimerization products. When reflux ratio was above 3 : 1, mixed octene fraction of which purity was above 99.57% was obtained. In $C_9$-aldehyde synthesis through hydroformylation of mixed octenes, we investigated a performance of ligand which increased catalyst stability as well as activity of Co catalyst. The results indicated that TPPO, NMP, NDMA, and succinonitrile were suitable ligand for increasing initial activity and reducing loss of Co during catalyst recovery.

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