• Membrane Journal
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• v.25 no.2
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• pp.85-98
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• 2015

A global trend of replacing metal or glass containers with polymer-based packaging materials has been prevalent in the food packaging industry due to their ease in processibility, excellent transparency, and good cost efficiency. Barrier polymers tend to show low permeabilities for atmospheric gases such as oxygen, carbon dioxide, and water vapor, which allow them to be utilized in the food and beverage packaging industry. With the current global trend, expansion of polymeric packaging materials to new markets such as oxygen sensitive juices, flavored water, and energy drinks requires improved $CO_2$ and $O_2$ barrier properties. The improvement of the existing polymer-based barrier platform will enable a rapid market impact. In this paper, the current barrier technologies such as (1) antiplasticization-induced barrier materials, (2) synergistic effect of antiplasticization and crystallization, (3) new barrier polymers, (4) nanocomposite materials, and (5) polymer blending are introduced with their characterization techniques for the development of advanced packaging materials.

• Polymer(Korea)
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• v.25 no.4
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• pp.521-527
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• 2001

The miscibility, molecular interaction and tensile properties of the blends of poly (${\varepsilon}$-caprolactone) (PCL) with poly(vinyl chloride) (PVC) have been studied. The measured glass transition temperature values of PCL/PVC blends were found to be well fitted by Fox equation. We found that PCL/PVC blends are amorphous up to 23% PCL content. The blends showed the highest Young's modulus and yield strength at 5% PCL content and the highest tensile strength at 11% PCL content. The blends with low contents of PCL(up to 13%) show increased tensile strength and decreased elongation of PCL/PVC blends. Consequently, the antiplasticization phenomenon is observed in the PCL/PVC blends.

• 한국생물공학회:학술대회논문집
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• 2002.04a
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• pp.379-380
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• 2002

Biodegradable polymers have been regarded as a good alternative to solve the plastic waste problems caused by nondegradable synthetic polymers such as polyethylene and polystyrene. In the soil environment, plastics are mainly being used as a mulching film for agricultural purposes. In this research, the miscibility, tensile properties and biodegradation effect of poly-${\varepsilon}$-caprolactone(PCL) with polyvinyl chloride(PVC) have been studied. After 8 weeks of biodegradation, PCL/PVC(9/91) blend surface showed newly formed many holes. Consequently, the antiplasticization phenomenon and biodegradation were observed in the PCL/PVC blends. It was confirmed that a test for general biodegradation condition can be applied to plastic biodegradation in soil.