• Title/Summary/Keyword: anthraquinone

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Preconcentration and Determination of Copper(II) Using Octadecyl Silica Membrane Disks Modified by 2-Propylpiperidine-1-carbodithioate and Flame Atomic Absorption Spectrometry (2-Propylpiperidine-1-carbodithioate로 수식화한 Octadecyl 실리카 막으로 구리(II)의 예비농축 및 불꽃 원자흡수분광법으로의 정량)

  • Moghimi, Ali;Mossalayi, Haydar
    • Journal of the Korean Chemical Society
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    • v.52 no.2
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    • pp.148-154
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    • 2008
  • A simple and fast method for extraction and determination of trace amounts of copper(II) ions using octadecyl-bonded silica membrane disks modified with 2-propylpiperidine-1-carbodithioate (PPCD)I and atomic absorption spectrometry (AAS) is introduced. Extraction efficiency and the influence of flow rates, pH, and type and smallest amount of stripping acid were investigated. Maximum capacity of the membrane disks modified with 2 mg of the anthraquinone derivative used was found to be 425μg Cu2+. The limit of detection of the proposed method is 7 ng/ml. The method is applied to the recovery of Cu2+ from different synthetic samples and a spring water sample.

Quantitative Analysis of Anthraquinones from the Roots of Korean Natural Rumex species Plants (국내 자생 Rumex속 식물의 Anthraquinone 함량분석)

  • Lim, Jong-Pil;Park, Young-Seo;Hong, Min-Wook;Kim, Dae-Keun
    • Korean Journal of Pharmacognosy
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    • v.42 no.4
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    • pp.297-301
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    • 2011
  • Rumex species (Polygonaceae) is widely distributed in Korea and its little sprout has been used as wild greens. The roots of Rumex sp. are used as a substitute for Rhei Rhizoma in Korea for its antipyretic and laxative properties. For the purpose of researching the value of Rumex sp. plants as natural resources, pattern recognition for the analysis of those plants was conducted using HPLC method. Two anthraquinone compounds, chrysophanol and emodin, were isolated from Rumex crispus to use standards. Chrysophanol and emodin from R. crispus were detected at retention time of 14.96 and 12.21 min, respectively. These compounds were detected from Rhei Rhizoma and all Rumex sp. plants. The content of chrysophanol of R. conglomeratus was higher than any other Rumex sp. plants. The amount of emodin was much higher from R. crispus than any other Rumex sp. The HPLC patterns of Rumex sp. are similar to that of Rhei Rhizoma, so they have something valuable as natural resources.

Elucidating soda and soda-anthraquinone pulping characteristics of Korean bamboo species (국내산 주요 죽종의 소다 및 소다-안트라퀴논 펄핑 특성 비교)

  • Lee, Kyu-Seong;Song, Woo-Yong;Shin, Soo-Jeong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.48 no.3
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    • pp.44-50
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    • 2016
  • As a raw material for pulp and paper industry, Moso bamboo, Timber bamboo and Henon bamboo pulps were prepared by soda or soda-anthraquinone(Soda-AQ) pulping process. Soda-AQ pulp yields was higher in Henon bamboo (43.2%) than in Moso bamboo or Timber bamboo (32.7-39.2%), but quite lower than hardwood species. In Kappa number comparison, Henon bamboo pulp showed lower (16.6) with 50 min cooking to $170^{\circ}C$ than that of Moso bamboo (22.8) and Timber bamboo (18.9) with 90 min cooking to $170^{\circ}C$. Fiber length of Timber bamboo soda pulp had higher (1.46 mm) than that of Moso bamboo or Henon bamboo (1.18-1.36 mm). All three bamboo pulps showed longer average fiber length than commercial hardwood pulp. With higher pulp yield and lower Kappa number, Henon bamboo is better raw material for pulp than Moso bamboo and Timber bamboo.

Chemical and Mechanical Properties of Yellow Poplar Pulp Produced by Formic Acid- Hydrogen Peroxide Pulping (개미산-과산화수소 펄핑에 의하여 생산된 백합나무 펄프의 화학적 및 역학적 특성 분석)

  • Sim, Jaehoon;Kim, Jeong-Ho;Park, Jong-Moon;Shin, Soo-Jeong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.45 no.1
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    • pp.6-12
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    • 2013
  • TFormic acid-hydrogen peroxide (or performic acid) pulping process needs milder reaction condition than other chemical pulping process. Two-step formic acid-hydrogen peroxide pulping process can produce the chemical pulp with similar pulp yield and lignin content compared with soda-anthraquinone process. Formic acid-hydrogen peroxide pulp can be produced less xylan content than other alkaline pulps, which favor for dissolving pulp production. Formic acid-hydrogen peroxide pulp showed better response beating than soda-anthraquinone(AQ) pulps with reaching target freeness with less beating. Also, formic acid-hydrogen peroxide pulp had better tensile index at similar freeness level compared with soda-AQ pulps.

Antidiabetic Stilbene and Anthraquinone Derivatives from Rheum undulatum

  • Choi Sang Zin;Lee Sung Ok;Jang Ki Uk;Chung Sung Hyun;Park Sang Hyun;Kang Hee Chol;Yang Eun Young;Cho Hi Jae;Lee Kang Ro
    • Archives of Pharmacal Research
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    • v.28 no.9
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    • pp.1027-1030
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    • 2005
  • The antidiabetic-activity-guided fractionation and isolation of the $80\%$ EtOH extracts obtained from cultivated Korean Rhubarb rhizomes (Rheum undulatum, Polygonaceae) led to the isolation and characterization of one stilbene, desoxyrhapontigenin(1) and two anthraquinones, emodin (2) and chrysophanol (3). Their structures were established by chemical and spectroscopic methods. Compounds 1, 2, and 3 inhibited postprandial hyperglycemia by 35.8, 29.5, $42.3\%$, respectively.

Inhibition of Lens Aldose Reductase by Medicinal Plants (수종 생약에 의한 Lens Aldose Reductase의 억제)

  • Jeong, Do-Rae;Park, Woong-Yang;Lee, Seung-Ho;Lee, Kyong-Soon;Ro, Jai-Seup
    • Korean Journal of Pharmacognosy
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    • v.24 no.1
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    • pp.58-62
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    • 1993
  • To search for inhibitory activities for lens aldose reductase, twenty two medicinal plants were tested by the method of bovine lens aldose reductase inhibition test. In this test Rubia akane(68%), Artemisia selengensis(61%), Lespedeza cuneata (58%), Ligustrum lucidum(58%), Viola patrinii(58%) extracts were shown to have aldose reductase inhibitory activity. From the radix of Rubia akane, $2-methyl-1,\;3,\;6-trihydroxy-9,\;10-anthraquinone-3-O-(6'-O-acetyl)-{\alpha}-rhamnosyl-(1{\rightarrow}2)-{\beta}-D-glucoside$ was isolated and the $IC_{50}$ of this compound in the aldose reductase inhibition test was about $1.2{\times}10^{-6}M$.

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Utilization of Pine Bark (Part 7) -Applicability of Spent Liquor Obtained from Alkaline Sulfite-Anthraquinone (AS-AQ) Cooking of Pine Bark as a Deinking Agent- (소나무 수피의 총합적 이용(제7보) -소나무 수피 AS-AQ 증해폐액의 탈묵제로서의 적용 가능성-)

  • 문성필;박성천
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.33 no.4
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    • pp.42-48
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    • 2001
  • The spent liquor (BSL) obtained from alkaline sulfite-anthraquinone (AS-AQ) cooking of pine bark was applied as a deinking agent. In the ONP deinking system, although BSL removed the small size of ink particles (${\geq}$$12.5{\mu}m$), it did not improve the brightness of pulp. The brightness of pulp slightly improved when treated with BSL at 150~$180^{\circ}C$. However, the brightness of the pulp was lower than that of a commercial deinking agent (oleic acid). It seems that BSL treated with a high temperature still had a high dispersing ability on the ink particles. Intensive oxidations were introduced, and remarkable deinking effects were observed at 13kgf/$cm^2$ oxygen pressure, $160^{\circ}C$ and 2h. When BSL treated at 13kgf/$cm^2$ oxygen pressure, $170^{\circ}C$ and a time period of 30~90 min is added to the pulp, at 0.1% or lower, the deinking effect became higher than that of oleic acid. On the other hand, additional alkali treatments during the oxidation possibility as a deinking agent when oxidized. However, since the oxidized BSL still has a high dispersing ability and lower molecular weight, several modifications need to be done in the near future in order to be applied as a high quality deinking agent.

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Synthesis and Properties of New Phthaloperinone Dyes (신규 Phthaloperinone 색소의 합성과 특성에 대한 연구)

  • Jun, Kun;Gwon, Seon Yeong;Kim, Sung Hoon
    • Textile Coloration and Finishing
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    • v.27 no.4
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    • pp.275-280
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    • 2015
  • New series of phthaloperinone dyes were synthesized by the condensation reaction between tetrachloro-phthalic anhydride, 2,3-naphthalene dicarboxylic anhydride and o-phenylenediamine, 1,8-diaminonaphthalene, 1,2-diaminoanthraquinone. These dyes absorb at around 370-490nm. It was found that introduction of naphthalene and anthraquinone moiety on the perinone system produces a large bathochromic shift of 100nm. The synthesized dye 7 containing anthraquinone moiety in perinone chromophoric system exhibited superior heat stability and bright color as yellow chromophore. New dye 7 have been investigated in terms of interacting with volatile organic compound(VOC) $EtNH_2$. The sensing behaviour of the dye 7 toward $EtNH_2$ was studied by UV-vis absorption spectroscopy. Sensing mechanism of dye 7 to $EtNH_2$ was supported by theoretical calculations based on DFT method.