• 제목/요약/키워드: anodic oxidation

검색결과 324건 처리시간 0.024초

Borate 완충용액에서 철의 산화 반응구조와 산화피막의 전기적 특성 (Electronic Properties of the Oxide Film and Anodic Oxidation Mechanism of Iron in Borate Buffer Solution)

  • 김현철;김연규
    • 대한화학회지
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    • 제56권5호
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    • pp.542-547
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    • 2012
  • Borate 완충용액에서 Fe의 산화 반응 경로와 생성된 산화피막의 전기적 특성을 조사하였다. Fe는 pH에 의존하는 두 가지의 반응 경로에 의하여 산화되었으며 산화된 피막은 Mott-Schottky 식이 적용되는 n-형 반도체 성질을 가지고 있음을 알 수 있었다.

양극산화법으로 제조한 산화 알루미늄 막의 감습특성 연구 (A study on humidity sensing properties of oxide aluminum films by Anodic oxidation)

  • 전범진;전용우;이월인;소대화
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1994년도 추계학술대회 논문집
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    • pp.113-117
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    • 1994
  • In this paper, an experiment about humidity sensing properties of oxide aluminum films by Anodic oxidation method was made. The humidity sensing properties of films were investigated in the relative humidity range of 10∼85(%RH) , changing the frequency from 1[kHz] to 100[kHz]. The impedance of humidity sensing films were decreased in accordance with the increase of relative humidity. The decreasing rate of impedance were larger at low measuring frequency. The decreasing difference changes from 17.7M$\Omega$ to 3.68M$\Omega$ at low measuring frequency.

수용액 중 탄소섬유/알루미늄 복합재의 전기화학적 거동에 관한 연구 (A Study on The Electrochemical Behavior of CF/Al Composite in Aqueous Solutions)

  • 남윤경;문성모;정용수;신승용
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2011년도 춘계학술대회 및 Fine pattern PCB 표면 처리 기술 워크샵
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    • pp.158-159
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    • 2011
  • In this work, The electrochemical behavior of CF/Al composite was investigated at constant current densities in aqueous solutions. The surface and cross section of PEO-treated CF/Al were observed using SEM, EDS and OM. The CF/Al composite contains carbon fibers of about 40 Vol.% with 5~7 um diameter and 100~150 um length. The carbon fibers appeared to b removed by anodic oxidation in sulfuric acid solution, leaving a carbon-fiber free zone in the surface region. Anodic oxide films were formed in the carbon-free region by plasma electrolytic oxidation(PEO) method in alkaline solutions.

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ANALYSIS OF THE ANODIC OXIDATION OF SINGLE CRYSTALLINE SILICON IN ETHYLEN GLYCOL SOLUTION

  • Yuga, Masamitsu;Takeuchi, Manabu
    • 한국표면공학회지
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    • 제32권3호
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    • pp.235-238
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    • 1999
  • Silicon dioxide films were prepared by anodizing silicon wafers in an ethylene $glycol+HNO_3(0.04{\;}N)$ at 20 to $70^{\circ}C$. The voltage between silicon anode and platinum cathode was measured during this process. Under the constant current electrolysis, the voltage increased with oxide film growth. The transition time at which the voltage reached the predetermined value depended on the temperature of the electrolyte. After the time of electrolysis reached the transition time, the anodization was changed the constant voltage mode. The depth profile of oxide film/Si substrate was confirmed by XPS analysis to study the influence of the electrolyte temperature on the anodization. Usually, the oxide-silicon peaks disappear in the silicon substrate, however, this peak was not small at $45^{\circ}C$ in this region.

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양극 산화법으로 제조된 Tantalum Oxide 박막의 전압-시간 특성과 미세구조와의 연관성 (Relationship Between Voltage-time Characteristics and Microstructures of Tantalum Oxide Thin Films Prepared by Anodic Oxidation)

  • 정형진;윤상옥;이동헌
    • 한국세라믹학회지
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    • 제28권6호
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    • pp.443-450
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    • 1991
  • Microstructures of tantalum oxide, anodic-oxidized in oxalic acid, are shown to be related to voltage-time characteristics during formation reaction. It is observed that a crystalline phase transformed from an amorphous phase is recrystallized in the presence of the high electric field within the film, and this recrystallized film has a very porous microstructure. From the results of the XRD, the nonlinearity observed after the first spark voltage is recognized to be due to the local crystallization.

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주조용 Al-Si-Cu 알루미늄 합금의 기계가공 및 주조된 표면에서의 양극산화피막 형성 (Formation of Anodic Oxide Films on As-Cast and Machined Surfaces of Al-Si-Cu Casting Alloy)

  • 문성모;남윤경;양철남;정용수
    • 한국표면공학회지
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    • 제42권6호
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    • pp.260-266
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    • 2009
  • The anodic oxidation behaviour of a cast component of AC2A Al alloy with machined surface and ascast surface was investigated in sulfuric acid solution. The anodized specimen showed relatively uniform and thick anodic oxide films on the as-cast surface, while non-uniform and very thin oxide films were formed on the machined surface. Non-anodized as-cast surface was observed to be covered with thick oxide scales and showed a number of second-phase particles containing Si, while non-anodized machined surface showed no oxide scales and relatively very small number of Si particles. Thus, the very limited growth of anodic oxide films on the as-cast surface was attributed to the presence of thick oxide scales and Si-containing second-phase particles on its surface.