• 제목/요약/키워드: anode

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습식법에 의한 고체산화물 연료전지용 연료극 지지체관의 제조 및 특성 연구 (Fabrication and Characteristics of Anode-Supported Tube for Solid Oxide Fuel Cell)

  • 김응용;송락현;임영언
    • 한국재료학회지
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    • 제10권10호
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    • pp.659-664
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    • 2000
  • 연료극 지지체식 원통형 고체산화물 연료전지를 개방하기 위해 연료극 지지체와 전해질이 코팅된 연료극 원통관의 제조 및 그것의 특성에 대해 연구하였다- 연료극 지지체는 20-50vol.%의 탄소함량에 따라 만들어졌으며, 탄소량이 증가함에 따라 연 료극 지지체의 기공율도 점차 증가하였으며, 적절한 기공율을 가지기 위한 최적 탄소량은 30vol.%임을 확인하였다. 연료극 지지체 관은 압출법으로 제작하였으며, 전해질은 슬러리 코팅법으로 원통판의 바깥쪽에 코팅하였고, $1400^{\circ}C$에서 공소결을 성공적으로 실시하였다. 소결후 물리척특성과 미세구조를 조사하였으며, 연료극 지지체관의 기공율은 35%이었고 연료전지의 요구조건을 만족하였다. 기체투과율 시험을 통하여, 연료극 지지체관 자체는 충분히 다공성을 나타내었으나, 전해질층을 코팅한 경우에는 매우 낮은 기체부과율을 나타냄을 확인하였다. 이것은 코팅된 전해질층이 매우 치밀하다는 것을 의미하며, 본 연구를 통해서 연료극 지지체식 원통형 고체산화물 연료전지가 제조될 수 있음을 확인하였다.

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엔진피스톤링 홈의 크롬도금에 관한 연구 (A Study on Chromium Electroplating of Piston Ring Groove's Surface)

  • 문경만
    • Journal of Advanced Marine Engineering and Technology
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    • 제19권2호
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    • pp.47-55
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    • 1995
  • When the low heavy oil is using as fuel oil to the diesel engine, some problems such as corrosion resistance, wear resistance and heat resistance are happened in diesel engine's internal material, especially the adhesive wear of piston ring groove was occurred as a important problem. Therefore to prevent adhesive wear of its groove, the surface of its groove used to be electroplated with Chrominum and for its Chromium electroplating, Fe anode is being used until nowadays because of its Special shape. However in case of using Fe anode, there were some problems such as deterioation of solution, property of Chromium film, and condition of coation. In this paper Pb anode electroplated withPb to the steel plate was investigated for its Chromium electroplating for Pb's high corrosion resistance in acid solution, and Pb anode is not dissolved compared with Fe anode and deterioration degree of solution in case of Pb anode is smaller than that of Fe anode and also property of Chromium film was better than that of Fe anode. Moreover it was known that the optimum cathodic current density for Pb electroplating to steel plate as insoluable anode for Chromium coating of piston ring groove is 30mA/$cm^2$ by experimental results obtained.

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비정질 IZO 애노드를 이용한 형광 유기발광소자의 특성 (Characteristics of Fluorescent Organic Light Emitting Diodes using Amorphous IZO Anode Film)

  • 문종민;배정혁;정순욱;강재욱;김한기
    • 한국전기전자재료학회논문지
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    • 제19권11호
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    • pp.1044-1049
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    • 2006
  • We reported on characteristics of the fluorescent OLED fabricated on commercial ITO/glass and BCS grown IZO/glass substrate, respectively. The amorphous IZO anode film grown by box cathode sputtering(BCS) exhibited similar electrical and optical characteristics to commercial ITO anode even though it was deposited at room temperature. In addition, the amorphous IZO anode showed higher workfunction (5.2 eV) than that of the commercial ITO anode (5.0 eV) after ozone treatment for 10 min. Furthermore, fluorescent OLED fabricated on amorphous IZO anode film showed improved current-voltage-luminance characteristics, external quantum efficiency and power efficiency en contrast with fluorescent OLED fabricated on commercial ITO anode film. It was thought that smooth surface and high workfunction of amorphous IZO anode lead to more efficient hole injection by reduction of interface barrier height between anode and organic layers.

Analytical polarization curve of DMFC anode

  • Kulikovsky, A.A.
    • Advances in Energy Research
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    • 제1권1호
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    • pp.35-52
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    • 2013
  • A model for DMFC anode performance is developed. The model takes into account potential--independent methanol adsorption on the catalyst surface, finite rate of proton transport through the anode catalyst layer (ACL), and a potential loss due to methanol transport in the anode backing layer. An approximate analytical half--cell polarization curve is derived and equations for the anode limiting current density are obtained. The polarization curve is fitted to the curves measured by Nordlund and Lindbergh and parameters resulted from the fitting are discussed.

Shorted anode p-i-n 스위칭 소자의 전기적 특성 (Electrical Characteristics of Shorted Anode P-I-N Switchs)

  • 이성재;민남기
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1994년도 하계학술대회 논문집 C
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    • pp.1469-1471
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    • 1994
  • This paper describes the structure and electrical characteristics of a shorted anode p-i-n switch. The device showed a significant improvement in the threshold voltage-to-holding voltage ratio, which is due to the suppression of the hole injection from the anode and to the gold gettering at the anode side. The shorted anode devices with a $100{\mu}m$ channel length have a threshold voltage of 300 volts and a holding voltage of 5.5 volts.

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전계방출광원용 고효율 에노드 형광막 특성 연구(I) - 금속막 (Study on the High Efficiency of Anode Phosphor Electrode for Filed Emission Lamp (I) Metal Layer)

  • 이선희;김광복;김용원;유용찬
    • 한국조명전기설비학회:학술대회논문집
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    • 한국조명전기설비학회 2007년도 춘계학술대회 논문집
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    • pp.7-10
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    • 2007
  • The electron charging and degradation of anode phosphor layers are showed major problems in high electric field with anode electrode of field emission devices. An Al metal layer on the phosphor layer may get rid of these problems. This Al metal layer are formed with the roughness of phosphor surface layer without interlayer and cannot be given rise to enhance the luminance efficiency. In order to enhance the brightness, an anode layer need to be flated between phosphor layer and Al metal layer in anode electrode. After optimizing the anode phosphor layer, an anode layer with Al metal and inter layer increased the brightness and luminescence efficiency 1.5 times more than only phosphor layer in anode.

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고분자 연료전지 스택에서 질소 크로스오버 특성에 관한 연구 (Characterization of Nitrogen Gas Crossover in PEM Fuel Cell Stacks)

  • 백경돈;김민수
    • 대한기계학회논문집B
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    • 제33권3호
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    • pp.207-214
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    • 2009
  • Crossover of nitrogen from cathode to anode is inevitable in typical membranes used in PEM fuel cells. This crossovered nitrogen normally accumulates in the hydrogen recirculation system at anode side channels. Excessive buildup of nitrogen in the anode side lowers the relative hydrogen concentration and finally affects the performance of fuel cell stack. So it is very important to analysis the nitrogen gas crossover at various operating conditions. In this study, characterization of nitrogen gas crossover in PEM fuel cell stack was investigated. The mass spectroscopy (MS) has been applied to measure the amount of the crossovered nitrogen gas at the anode exit. Results show that nitrogen gas crossover rate was affected by current density, anode and cathode stoichiometric ratio and operating pressure. Current density, anode stoichiometric ratio and anode operating pressure do not affect nitrogen crossover rate but anode exit concentration of nitrogen. Cathode pressure and stoichiometric ratio largely affect the nitrogen crossover rate.

전계방출광원용 아노드 난반사 연구 (Reporting on the High Efficiency of Anode Phosphor Electrode for Filed Emission Lamp - Metal Layer)

  • 윤한나;김윤일;김대준;김광복
    • 한국조명전기설비학회:학술대회논문집
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    • 한국조명전기설비학회 2008년도 춘계학술대회 논문집
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    • pp.29-32
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    • 2008
  • The electron charging and degradation of anode phosphor layers are showed major problems in high electric field with anode electrode of field emission devices. An AI metal layer on the phosphor layer may get rid of these problems. This Hetero-metal-oxide phosphor layer are formed with the roughness of phosphor surface layer without interlayer and cannot be given rise to enhance the luminance efficiency. In order to enhance the brightness, an anode layer need to be flated between phosphor layer and AI metal layer in anode electrode. After optimizing the anode phosphor layer, an anode layer with AI metal and inter layer increased the brightness and luminescence efficiency 1.2 times more than only phosphor laver in anode.

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용융탄산염 연료전지의 양극 및 대체재료의 제작에 관한 연구 -Cu-base 전극에 대하여- (A study on the developmenet of Anode Material for Molten Carbonate Fuel Celt - Cu-base electrode-)

  • 박재우;김용덕;황응림;김선진;강성군
    • 한국표면공학회지
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    • 제28권4호
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    • pp.243-254
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    • 1995
  • The fabrication process of Cu-base anode for replacing Ni-base anode of molten carbonate fuel cell was investigated. Electrochemical performance and thermal stability of Cu-base anode were also investigated. Green sheet was prepared by mixing Cu and Ni powder with 1.5wt% methylcellulose and 100wt% water. The pore-size distribution of the Cu-base anode sintered at $800^{\circ}C$ for 30min showed almost uniform pore-size ranging from 4 to 20$\mu\textrm{m}$ and it was considered suitable for MCFC anode. Cu-Ni anode containing between 35 to 50wt% Ni exhibited current density of 111mA/$\textrm{cm}^2$ at 100mV overpotential and it was almost the some value for pure Ni anode. The sintering resistance of Cu-Ni increased with an increase of Ni addition. It was considered that the increase of sintering resistance was due to the decrease of diffusion rate of Cu and Ni with increasing the addition of Ni in Cu-Ni alloy.

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Experimental Observations for Anode Optimization of Oxide Reduction Equipment

  • David Horvath;James King;Robert Hoover;Steve Warmann;Ken Marsden;Dalsung Yoon;Steven Herrmann
    • 방사성폐기물학회지
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    • 제20권4호
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    • pp.383-398
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    • 2022
  • The electrochemical behavior was investigated during the electrolysis of nickel oxide in LiCl-Li2O salt mixture at 650℃ by changing several components. The focus of this work is to improve anode design and shroud design to increase current densities. The tested components were ceramic anode shroud porosity, porosity size, anode geometry, anode material, and metallic porous anode shroud. The goal of these experiments was to optimize and improve the reduction process. The highest contributors to higher current densities were anode shroud porosity and anode geometry.