• Title/Summary/Keyword: anisotropy, dipole moment

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Polarization Mode Coupling Constants in Solid-State Lasers

  • Park, Jong-Dae;Cho, Chang-Ho
    • The Journal of Natural Sciences
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    • v.17 no.1
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    • pp.31-37
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    • 2006
  • We have found that the polarization mode coupling between the orthogonally linearly polarized dual mode laser results from the anisotropy of dipole moments. Rate equation analysis demonstrated that high anisotropy in dipole moment components can give rise to law intrinsic mode coupling constants while isotropic dipole moment components give high intrinsic mode coupling constant. The populations at active ion sites are shown to self-organize the populations such that laser mode gain is constant adove threshold while the gain contributions from the each site adjust themselves with pump power.

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Experimentally Measured Rotational Reorientation Time of Coumarin 6 Laser Dye in Ethanol and Acetonitrile Solvents

  • Renuka, C.G.;Raikar, U.S.
    • Journal of Photoscience
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    • v.12 no.3
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    • pp.119-122
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    • 2005
  • The photophysical properties of coumarin 6 laser dye have been studied in two solvents; ethanol and acetonitrile using steady-state fluorescence depolarization technique. The experimentally measured reorientation time of coumarin 6 is more or less the same in given solvents at particular temperature. It is found that coumarin 6 rotates slower in acetonitrile than in ethanol especially at higher values of viscosity over temperature. We also measure the ground and excited state dipole moments of coumarin 6 by solvent perturbation method. The results found that excited state dipole moment is greater than ground state dipole moment, which indicates that excited state is more polar than the ground state.

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Dipole Moment Derivatives and Infrared Intensities of SiH$_4$ and SiD$_4$

  • Kim, Kwan;Lee, Hwi-Geon
    • Bulletin of the Korean Chemical Society
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    • v.6 no.2
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    • pp.79-86
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    • 1985
  • The complete neglect of differential overlap (CNDO/2) approximate wavefunctions have been applied to select the preferred signs for the dipole moment derivatives of SiH$_{4}$ and SiD$_{4}$ in conjunction with the experimental alternatives. The apparent sign discrepancy from earlier report has been identified. The effective atomic charge for hydrogen was found to be X$_{H}$/e = 0.229, more than two times larger in comparison with the values of typical hydrocarbons like CH$_{4}$. The anomalously large effective hydrogen charge was interpreted based on a quantum mechanical model as well as the value of atom anisotropy relative to effective atomic charge.

Polarization Properties of J-aggregates by Mutual Mixing Effect in the LB Films of Merocyanine Dyes (메로시아닌 색소 LB막의 상호혼합효과에 의한 J-aggregates 편광특성)

  • Yang, Chang-Heon;Kim, Gyong-Chol;Kwon, Young-Soo;Shin, Hoon-Kyu
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.59 no.12
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    • pp.2245-2249
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    • 2010
  • The physical properties of the LB films with merocyanine dyes have been published and attract attention due to the possibility of molecular structure control. The evaluation of the thin films was focused for the purpose of molecular structure control. The molecular structure in the case of the thin films with dyes can be examine by optical absorption spectra measurements. In the result measured by optical absorption spectra, the $[DX]_{1-x}[DO]_x$ LB films shows a large in-plane anisotropy and the transition dipole moment of red-shifted band is preferentially oriented perpendicular to the dipping direction of the film, while that of the blue-shifted band prefers the dipping direction. The spectrum for $0_{\circ}$, $90_{\circ}$-polarized light coincides with the spectrum for non-polarized light and also with the spectrum was observed in the LB film deposited using a fresh solution. These results show that the aging process does not cause a structural change in chromophore but a change in the degree of molecular orientation. In the results, study of the merocyanine dyes LB films using optical absorption spectra would an interesting problem of absorbance peak shifts and mixed components.

Nuclear Structure Studies with Low Temperature Technique (I)

  • Young Koh;Park, Won-Seok;Park, Chang-Kyu;Shin, Hee-Sung;Song, Tae-Yung
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.11b
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    • pp.669-674
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    • 1996
  • The theory of quantum mechanics states that for any system there are a set of discrete physical states, quantum states, which corresponds a particular energy level of the system. The lowest energy the system can have, corresponding to its ground state, is not necessarily zero, but depends only on the precise microscopic nature of the system under consideration. At the absolute zero of temperature all systems will be in their lowest energy state (zero point energy) and as the system is warmed from OK, the higher energy states become occupied. The probability of occupancy of the excited states relative to that of the ground state is proportional to the absolute temperature. Therefore we can obtain nuclear dipole and quadrupole moment very accurately at ultra low temperature (<15mk) by NMR and from the destruction of anisotropy. The former is called LTNO/NMR and the latter is called LTNO (Low Temperature Nuclear Orientation). In this paper we discuss and introduce only an experimental apparatus with results of cooling power test, a helium dilution refrigerator, which can reache 8mK, and an actual technique for the experiment, a theory and results will be presented in another papers.

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Anisotropy Effect of Exchange Bias Coupling by Unidirectional Deposition Field of NiFe/FeMn Bilayer (NiFe/FeMn 이중박막의 증착시 자기장에 의한 교환결합력 이방성 효과)

  • Park, Young-Seok;Hwang, Do-Guwn;Lee, Sang-Suk
    • Journal of the Korean Magnetics Society
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    • v.18 no.5
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    • pp.180-184
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    • 2008
  • The relation of ferromagnet anisotropic magnetization and the antiferromagnet atomic spin configuration has been investigated for variously angles of unidirectional deposition magnetic field of FeMn layer in Corning glas/Ta(5 nm)/NiFe(7 nm)/FeMn(25 nm)/ Ta(5 nm) multilayer prepared by ion beam deposition. Three unidirectional deposition angles of FeMn layer are $0^{\circ},\;45^{\circ}$, and $90^{\circ}$, respectively. The exchange bias field ($H_{ex}$) obtained from the measuring easy axis MR loop was decreased to 40 Oe in deposition angle of $45^{\circ}$, and to 0 Oe in the angle of $90^{\circ}$. One other side hand, $H_{ex}$ obtained from the measuring hard axis MR loop was increased to 35 Oe in deposition angle of $45^{\circ}$, and to 79 Oe in the angle of $90^{\circ}$. Although the difference of uniderectional axis between ferromagnet NiFe and antiferromagnet FeMn was 90o, the strong antiferromagnetic dipole moment of FeMn caused to rotate the weak ferromagnetic dipole moment of NiFe in the interface. This result implies that one of origins for exchange coupling mechanism depends on the effect of magnetic field angle during deposition of antiferromgnet FeMn layer.