• Title/Summary/Keyword: anhydride

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A Study on the Curing Behavior and Toughness of Amine Terminated Polyetherimide/Epoxy Resin System (Amine Terminated Polyetherimide/에폭시 수지 시스템의 경화공정연구와 파괴인성에 관한 연구)

  • 김민영;이광기;김원호;황병선;김대식;박종만
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2002.05a
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    • pp.147-150
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    • 2002
  • The cure kinetics of blends of epoxy (DGEBA:diglycidyl ether of bisphenol A)/anhydride (NMA:nadic methyl anhydride) resin with synthesized amino terminated polyetherimide (AT-PEI) were studied using differential scanning calorimetry (DSC) and Dynamic Mechanical Analysizer(DMA) under isothermal condition to determine the reaction parameters and gel-vitrification behavior. The fracture toughness of AT-PEI 20phr/epoxy resin system was improved over 224% and 42.5% more than neat epoxy resin and commercial PEI/Epoxy Resin System.

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Development of A Recycling Process for Waste FRP from Boats (선박용 폐 FRP 수지의 재활용 공정 개발)

  • 강세란;김영우;황덕기;김시영;이민규;주창식
    • Journal of Environmental Science International
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    • v.12 no.6
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    • pp.635-641
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    • 2003
  • A recycling process for the waste FRP from boats was developed. The recycling process is composed of decomposition of waste FRP with propylene glycol and synthesis of recycled unsaturated polyester resin from the decomposed liquid material. Prior to the decomposition, waste FRP was cut into 2cm x 5cm segments and mechanical impact was applied by press roller to give gaps between cumulated laminates. Propylene glycol effectively decomposed the waste FRP segments and glass fibers were easily separated from decomposed liquid material. Recycled unsaturated polyester resin could be made from the decomposed liquid material by reaction with maleic anhydride and phthalic anhydride.

A Study on the Synthesis of Dinitramide Salts (디니트라미드 염의 합성)

  • Chung, Kyoo-hyun;Sim, Hyun-ho
    • Applied Chemistry for Engineering
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    • v.9 no.1
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    • pp.155-157
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    • 1998
  • Dinitramide salts may be useful as effective solid oxidizers because of higher oxygen content than nitrate salts. 3-Nitramino-propanoate was given by base treatement in the retro-Michael reaction of N-nitro-4-azaheptanedioate, which was prepared by nitration of 4-azaheptanedioate using $HNO_3$-TFAA(trifiluoroacetic anhydride)-$Br_2$. The nitramino compound was treated wile $NO_2BF_4$ to give dinitramino compound which was subsequently reacted with bases to give dinitramide salts.

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Synthesis and Properties of Photocurable Pentaerythritol Modified Hyperbranched Acrylate (광경화형 Pentaerythritol 변성 초분지형 아크릴레이트의 합성과 물성)

  • Kim Dong Kook;Lim Jin Kyu;Kim Woo Geun;Heo Jung Lim
    • Polymer(Korea)
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    • v.29 no.3
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    • pp.237-241
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    • 2005
  • Photocurable pentaerythritol modified hyperbranched acrylates were prepared from trimellitic anhydride, glycidyl methacrylate and pentaerythritol derivatives. Thermal stability obtained by using TGA showed that HBMA-1 was superior to the others. Hardness, abrasion resistance and tensile strength of HBMA-1 showed that Hey were also superior to the others. Value of yellow index of HBMA-1 showed the lowest.

A Study on the Dispersion Effects and Slump for Elapsed Time of Cement Admixed with Naphthalene Sulfonated Condensate and Maleic Anhydride Copolymer (나프탈렌술폰산축합물과 무수말레인산계 공중합체를 첨가한 시멘트의 분산효과 및 경시변화에 관한 연구)

  • 김도수;김은영;홍성수;노재성
    • Proceedings of the Korea Concrete Institute Conference
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    • 1995.04a
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    • pp.94-99
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    • 1995
  • Naphthalene sulfonated condensatd(NSF) has been widely using for the superplasticizing of ement and concrete. But NSF has a very large mobility loss with elapsed tiom. To retain mobility of NSF during a certain time, maleic anhydride and acrylic acid copolymer(MA) was polymerized and mixed with NSF in order to perpare admixture holding mobility-retention property of cement. By applying this admixture for ement paste, we examined the fluidity and mobility retention property as a function to elapsed time and measured the compressive strength of mortar with curing time. As a result, NSF containing 20wt% of MA showed very excellent fluidity and mobility-retention property. These properties were affected by the added amount of admixture and the ratio of water to cement.

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Interfacial phenomena of XLPE/EPDM laminates (XLPE/EPDM laminates의 계면현상)

  • 남진호;서광석;김지환;고광철
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.11a
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    • pp.211-214
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    • 1998
  • DC breakdown characteristics and formation of space charge at the interfaces of crosslinked polyethylene (XLPE) /ethylene propylene diene terpolymer (EPDM) laminates were studied. Effects of silicone grease and some chemicals such as crosslinking coagent on the interfacial charge were also studied. Interfacial charge develops at the interface of XLPE/EPDM laminates, which changes depending on heat treatment conditions and types of chemicals coated at the interface. Some chemicals such as maleic anhydride reduce the accumulation of interfacial charge in the XLPE/EPDM laminates. Breakdown strength of EPDM/XLPE laminate through the interface was highest when silicone oil was pasted in the interfaces. Interfacial breakdown strength decreased with the increase of MAH content.

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Studies on the Surface Treatment of Kaolin Filler(Part 2) -Morphological Studies by SEM- (Kaolin 충전제(充塡劑) 표면처리(表面處理)에 관(關)한 연구(硏究)(제(弟) 2 보(報)) -주사전자현미경(走査電子顯微鏡)에 의(依)한 morphology-)

  • Kwon, Dong-Yong;Hong, Sung-Il;Kim, Sun-Ho;Lee, Yong-Moo;Huh, Dong-Sub
    • Elastomers and Composites
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    • v.18 no.4
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    • pp.135-139
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    • 1983
  • Scanning electron microscopy studies were conducted to examine the surface treatment effects of treating agents the proposed in the previous studies on various vulcanizates. Fracture surfaces of the vulcanizates compounded with kaolin treated with sodium polyphosphate of poly(maleic anhydride) presented favorable results as expected from the results of the previous studies. In other words, treating agents such as sodium polyphosphate and poly(maleic anhydride) show considerable reinforcing effects on the vulcanizates.

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Preparation of photo-crosslinkable silk sericin hydrogel

  • Kim, Jung Eun;Kim, Eui Hwa;Lee, Ki Hoon
    • International Journal of Industrial Entomology and Biomaterials
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    • v.36 no.1
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    • pp.10-14
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    • 2018
  • A photo-crosslinkable sericin hydrogel has been prepared by introducing methacrylate groups on sericin. Lysine was the amino acid for methacrylation and the degree of methacrylation was increased with the amount of methacrylic anhydride added. When the concentration of methacrylic anhydride was 20% of sericin, 0.635 mmol/g of methacrylate group could be introduced. The storage modulus of sericin hydrogel was increased proportionally with the degree of methacrylation. However, the swelling ratio of sericin hydrogel decreased with the increase of methacrylation.

Reaction Processes of the Formation of Mg-Al Spinel by a Thermal Decomposition of a Mixed Sulfate Hydrate (복합 황산염 수화물의 열분해에 의한 Mg-Al 스피넬의 생성반응)

  • 박홍채;오기동
    • Journal of the Korean Ceramic Society
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    • v.23 no.6
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    • pp.71-75
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    • 1986
  • The forming reaction processes of magnesium aluminate spinel by a thermal decomposition of sulfate hydrate were studied with DTA, TG. SEM and X-ray powder diffraction methods. The hydrous salt composed of the mixture of the two compounds of $MgSO_4$ $6H_2O$ and ${AL_2}({SO_4})_17H_2O_3$ in which both sulfates were crystalline. On heating the hydrous slat the crystalline magnesium and aluminum sulfate anhydride to amorphous alumina magnesium sulfate anhydride decomposed to amorphous magnesia and these amorphous oxides reacted completely each other to form a spinel at $1000^{\circ}C$ The apparent activation energy of forming reaction of spinel was 36.5 kcal/mole($900^{\circ}C$~$1000^{\circ}C$) The crystallite size of spinel obtained at $1000^{\circ}C$ after 1 h was 380$\AA$.

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Development of epoxy resin with modified thermoplastic polymer and application to the carbon fiber composites (개질된 열가소성 고분자를 이용한 에폭시 수지 개발과 탄소섬유 복합재료에의 응용)

  • 이광기;김민영;김원호;안병현;황병선
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2002.10a
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    • pp.237-240
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    • 2002
  • Amino terminated polyetherimide(ATPEI) has been synthesized by bisphthalic anhydride arid m-phenylenediamine, after that characterized by differential scanning calorimetry(DSC), thermogravimetric analyzer(TGA). Fourier transform (FT-IR) spectroscopy and gel permeation chromatography(GPC). ATPEI was blend to improve the toughness of bisphenol-A type epoxy resin which was cured by nadic methyl anhydride(NMA). The fracture toughness and the molphology of the toughened epoxy resin was evaluated. The toughness of ATPEI modified epoxy resin was higher than that of the PEI modified epoxy resin. In addtion, carbon fiber/ATPEI modified epoxy resin composites were fabricated and the mechanical properties of the resulted composites were investigated.

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