• Bulletin of the Korean Chemical Society
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• v.25 no.8
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• pp.1189-1194
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• 2004

The adsorption isotherms of N2 onto the metallic silver treated activated carbon fiber samples after acid treatment are Type I with a small amount of capillary condensation hysteresis. Increasing amount of acid treatment leads to a decrease in SBETs and external surface area. But, micropore volume and average pore diameter are presented in constant regular values with increasing amount of sulfuric acid treatment. SEM observes the surface morphology and crystal grown state of metal on the fiber surface. The results of EDX of Ag-activated carbon fiber pre-treated with acid show the spectra corresponding to almost all samples rich in silver with increasing the amount of acid treated. The FT-IR spectra of Ag-activated carbon fiber show that the acid pre-treatment is consequently associated with the homogeneous dispersion of metal with the increased surface acidity of the activated carbon fiber. The type and quality of oxygen groups are determined with Boehm titration method. From the those results, a positive influence of the acidic groups on the carbon fiber surface by acid treatment is also demonstrated by an increase in the contents of metallic silver with increasing of acidic groups.

• Proceedings of the Korean Environmental Health Society Conference
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• 2002.04a
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• pp.54-64
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• 2002

This study evaluated advanced water treatment (AWT) system in Korea. There are currently 16 plants operating with AWT. However, no attempt has been made to evaluate AWT system. This study selected one water treatment plant with AWT (pre-ozonation ＋ BAC). Using the operation data from 1995 to 2001 and pilot study results, the post-evaluation of the AWT system has been conducted. The study found that AWT improved water qualities of organic, ammonia, and turbidity, as expected. However, the extent of the improvement was generally short of the pilot study expectations. Pre-ozonation failed to decrease coagulant consumption. The dosage increased rather than decreased. AWT was, however, successful to decrease chlorine consumption. The chlorine reduction was related to the change in raw water characteristics and AWT introduction. Pre-ozonation failed to decrease coagulant consumption. The dosage increased rather than decreased. AWT was, however, successful to decrease chlorine consumption. The chlorine reduction was related to the change in raw water characteristics and AWT introduction, Both operation of pre-ozonation and reduced ammonia loading were responsible for the reduction. AWT increased the operation cost. Maintenance, raw water, and power cost increased, while labor and chemical cost decreased. Manpower reduction resulting form automation caused the decrease of labor cost. The reduction of chlorine consumption caused the decrease of chemical cost.

• Journal of Plant Biology
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• v.17 no.1
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• pp.15-21
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• 1974

The most commonly grown economical and flue-cured tobacco cultivar Yellow Special A was used in pot-culture tests in order to study Ethrel (2-chloroethyl phosponic acid) effects on accelerating maturity of tobacco leaves in relation to the most adequate level of the chemical useful for field growing, nitrogen level in soil for the most pronounced response, and the most suitable spray period during the growth stages of pre-, post- and topping periods. The following conclusions, thus, were obtained from the present studies; 1. 500ppm Ethrel spray was reconfirmed to be adequate in the practical applications, although the extent of yellow-ripening of tobacco leaves was increased as the Ethrel level increased. The highest leevel treated resulted in causing chemically damaged lesions on leaves and early defoliation. 2. Ethrel-treated leaves showed deeper yellowish tinge to them than those without treatment, while different levels of the chemcial had less influence on the tinge. 3. An adequate level of nitrogen supply to plants favored the Ethrel response, whereas either very low or high level of nitrogen in the soil lowered the chemical effect on accelerating the yellow-ripening. When carbohydrates versus total nitrogen ratio became relatively high, the condition brought out some outstanding Ethrel effects. 4. Chlorophyll level of leaves increased as soil applications of nitrogen level increased, and that also increased carotenoid level of the tobacco leaves. Ethrel-treated leaves showed deeper orange tinge than those without treatment, while the highest level of nitrogen application showed the deepest orange tinge to tobacco leaves. 5. Pre-topping treatment (12 days before topping and flowering) resulted in almost no Ethrel response, and that treatment right on the day of topping, showed response of yellow-leaf ripening at nearly bottom-half leaves of a tobacco plant. The post-topping treatment (12 days after topping) made plants showing full response of Ethrel from bottom to the top leaves of tobacco plant in accelerating the leaf maturity. 6. The extent of Ethrel responses on accelerating yellow-ripening of tobacco leaves was discussed for the modifying influences brought about by certain environmental factors. Discussions were also made about the possible practical applications (particularly for pre-rice planting) and quality difference that may be caused by such growth environments.

• Journal of Microbiology and Biotechnology
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• v.29 no.11
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• pp.1760-1768
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• 2019

The use of lignocellulosic biomass such as rice straw can help subsidize the cost of producing value-added chemicals. However, inhibitory compounds, such as phenolics, produced during the pre-treatment of biomass, hamper the saccharification process. Laccase and electrochemical stimuli are both well known to reduce phenolic compounds. Therefore, in this study, we implemented a bioelectrochemical detoxification system (BEDS), a consolidated electrochemical and enzymatic process involving laccase, to enhance the detoxification of phenolics, and thus achieve a higher saccharification efficiency. Saccharification of pretreated rice straw using BEDS at 1.5 V showed 90% phenolic reduction (Ph_r), thereby resulting in a maximum saccharification yield of 85%. In addition, the specific power consumption when using BEDS (2.2 W/Kg Ph_r) was noted to be 24% lower than by the electrochemical process alone (2.89 W/kg Ph_r). To the best of our knowledge, this is the first study to implement BEDS for reduction of phenolic compounds in pretreated biomass.

• Journal of Fashion Business
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• v.12 no.6
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• pp.1-10
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• 2008

Public interest in healthy hairs gets growing as damaged hairs are seen more frequently with the generalization of heat permanent waves. For this study, experiments have been conducted to understand the influences on the changes in physical and morphological features of wave forms and damaged hairs, by collecting virgin hairs from the women in their mid-20's, who had not experienced chemical applications, and by dividing the applications of heat perm hair treatments, PPT(for pre-treatment) and LPP(for post-treatment), into the pre-treatment, the post-treatment, the pre & post-treatment, and the non-treatment. For the wave formations, curl waves were investigated by the bare eyes using the pictures taken by a digital camera. For the comparison of physical features, the experiments of tensile strength and elongation were done and their mean values were found. For the observations of morphological features, the pictures were taken by SEM for comparison. As for the findings, regarding the curl wave shapes of hairs, the most even and elastic S curl was formed in the case of non-treatment. In the physical features, both of the tensile strength and elongation showed a decreasing tendency in line with the hair damage levels, and the case of the pre & post-treatment indicated the tendency most similar to the control group. In the morphological features of the cuticle, observed with an SEM, the pre-treatment showed the higher possibility of reducing the cuticle damages than the post-treatment did. LPP was found to play the role of protective membrane for the post-treatment, and the pre & post-treatment turned out to reduce most effectively the cuticle damages.

• Journal of Korean Society for Atmospheric Environment
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• v.22 no.4
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• pp.431-439
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• 2006

Catalytic oxidation of benzene, toluene and xylene (BTX) using regenerated metal oxide catalysts (ZnO-CuO, NiO, $Fe_2O_3$, ZnO, CrO) were investigated in a fixed bed flow reactor to evaluate their feasibility for the purpose of removing volatile organic compounds (VOCs). Four kinds of pre-treatment methods such as gas (air and hydrogen), acid aqueous solution, alkali aqueous solution and cleaning agent were used to find out the optimal regeneration conditions. The physico-chemical properties of the used and regenerated catalysts were characterized by BET and TPR (Temperature Programmed Reduction). The used catalysts showed high conversion ratio and the catalytic ability of toluene oxidation was in the order of ZnO-CuO>$Fe_2O_3$>NiO>ZnO>CrO. We found that the acid aqueous pre-treatment (0.1 N HNO$_3$) was the best way to enhance the catalytic activity of $Fe_2O_3$. In addition, air and hydrogen gas treatment were optimal for NiO and ZnO-CuO catalysts, respectively. Furthermore, the decomposition of BTX depends on the type of a catalyst and a gas molecule.

• Journal of the Korea Organic Resources Recycling Association
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• v.17 no.1
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• pp.96-102
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• 2009

The effect of ultrasonic and alkaline pre-treatments on waste activated sludge (WAS) disintegration was investigated for improved anaerobic digestion. As WAS was treated by either methods, longer capillary suction time (CST) was required due to the break-up of cell walls, and its supernatant demonstrated increase in soluble chemical oxygen demand (SCOD), protein content and turbidity. Ultrasonic process combined with alkaline pre-treatment demonstrated higher SCOD and protein content in the supernatant as compared with ultrasonic pre-treatment only. However, the degree of disintegration (DDCOD) of WAS decreased with increasing solid concentration as both WAS disintegration methods employed simultaneously.

• Journal of environmental and Sanitary engineering
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• v.23 no.3
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• pp.1-8
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• 2008

Currently, medical waste stoker incinerator is widely used in the emission control technology of health-care risk waste and miscellaneous contaminated waste. In the past, wet type control technology was used to remove the major harmful gaseous contaminants of medical waste such as HCl, $NO_x,\;SO_2$, CO, DUST, Dioxin. However, the treatment cost for wastewater was high and it has a disadvantage for frozen system during winter season. Therefore, in order to obtain effective treatment, the dry type control technology was developed and widely used to remove the gaseous contaminants. In this study, pre-coated bag filter using hydrated lime, ($Ca(OH)_2$), was applied to the dry type control system and the optimum dose of hydrated lime was investigated. The treatment results showed that the dust collection rate was approximately 26.7%. Moreover, the HCl removal rate using pre-coated bag filter ($50mg/sm^3\;Ca(OH)_2$) was 13.52%, which was significantly higher than 3.26% obtained from conventional bag filter.

• Journal of the Korean institute of surface engineering
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• v.49 no.3
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• pp.265-273
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• 2016

The effects of surface modification by nitric acid on the pre-treatment of electroless copper plating were investigated. Copper was electroless-plated on the nitric acid treated graphite activated by a two-step pre-treatment process (sensitization + activation). The chemical state and relative quantities of the various surface species were determined by X-ray photoelectron spectroscopy (XPS) after nitric acid modification or pre-treatment. The acid treatment increased the surface roughness of the graphite due to deep and fine pores and introduced the oxygen-containing functional groups (-COOH and O-C=O) on the surface of graphite. In the pre-treatment step, the high roughness and many functional groups on the nitric acid treated graphite promoted the adsorption of Sn and Pd ions, leading to the uniform adsorption of catalyst ($Pd^0$) for Cu deposition. In the early stage of electroless plating, a lot of tiny copper particles were formed on the whole surface of acid treated graphite and then homogeneous copper film with low variation in thickness was formed after 30 min.

• Journal of the Korea Fashion and Costume Design Association
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• v.11 no.1
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• pp.43-51
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• 2009

The cotton, wool, cotton/wool blended(80:20) and tencel fabrics were treated with low temperature oxygen or argon plasma, enzymes(cellulase or protease), or oxygen plasma-enzyme and examined for their weight loss and conditions for treatment for the environment friendly finishing. In the plasma treatment argon gas had better effect on the weight loss than oxygen gas did and the weight loss of all the fabrics was increased as increasing discharge power and discharge time. The weight loss of cotton, wool, cotton/wool blended(80:20) fabrics decreased in a large measure after 1 hr but that of tencel didn't decrease after 1 hr. In case of cellulose fibers oxygen gas plasma induced chemical functional groups on the surface of substrate more than argon gas plasma did so the weight loss of wool was larger than that of cotton, tencel fabrics in oxygen plasma-enzyme treatment. The weight loss of cotton and tencel fabrics decreased the initial stage because oxygen plasma pre-treatment caused cross linking as well as etching effect but argon plasma pre-treatment didn't. The plasma pre-treatment cleared the way for enzyme treatment on the whole but oxygen plasma pre-treatment bear in hand the increase of weight loss more or less because of the cross linking on the surface of cellulose fibers. The appropriate conditions for plasma treatment was 10-1Torr, 40W for 30minutes and for cellulase treatment were enzyme concentration of $3g/{\ell}$, pH 5, $60^{\circ}C$ for 1hr and for protease treatment were enzyme concentration of $4g/{\ell}$ pH 8, $60^{\circ}C$ for 1hr.