• Title/Summary/Keyword: analytical verification

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Evaluation of Homogeneity and Stability of Korean Mussel (Mytilus coruscus) Standards for Cadmium Analysis (카드뮴 분석용 홍합(Mytilus coruscus) 표준물질의 균질성 및 안정성 시험평가)

  • Lee, Ha-Eun;Lee, Jangho;Chung, David;Lee, Soo Yong;Park, Ki-Wan;Shim, Kyu-Young
    • Journal of Environmental Science International
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    • v.28 no.11
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    • pp.1041-1045
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    • 2019
  • In this study, the KS A ISO Guide 35 was applied to develop analytical standards for heavy metal cadmium using the Korean mussel (Mytilus coruscus) and to evaluate the homogeneity and stability of the sample. Some of the crucial characteristics that reference materials must consist include homogeneity and stability of both intra- and inter-bottles. We tested homogeneity using ANOVA analysis and short-term stability using regression analysis. The variations of cadmium concentrations did not significantly differ between intra- and inter-bottles (F=0.41, p=0.90). For short-term stability verification, cadmium analysis results were not statistically significant as a result of the regression analysis (significance F=0.51, p=0.53). This suggests that we can not dismiss the null hypothesis that there is no significant variation in concentrations of cadmium over time. These results indicated that the cryogenic-milling process has statistically proven the short-term stability for materials from mussels in the chemical analysis of cadmium. Therefore, we propose that the Korean mussel's reference material developed for the proficiency test could be used as a tool to evaluate reliability and consistency in laboratories.

Research Survey of the Containment Case for Damage Protection from Blade Fragments (블레이드 파편 봉쇄를 위한 컨테인먼트 케이스 연구 동향)

  • Chae, Seungho;Ahn, Sanghyeon;Lee, Soo-Yong;Roh, Jin-Ho
    • Journal of Aerospace System Engineering
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    • v.14 no.3
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    • pp.60-68
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    • 2020
  • If a broken blade in the aircraft engine penetrates the casing and ejects outside the aircraft, it will impact the fuselage, threatening the safety of the passengers. Thus, the development of a engine case should be certified for stability evaluation by the Aviation Administration. In this paper, we investigated the requirements and development technology for the containment certification of the engine casing necessary for the independent engine development in the country. An experimental/analytical method has been identified to summarize the contact safety requirements presented by the U.S. and European aviation agencies to verify the containment of debris in the casing corresponding to this certification. Also, we analyzed recent research on the containment casing and verification methods in casing development.

Verification of Analytical Method of Azaspiracid Toxins in Shellfish and Tunicates by Liquid Chromatography-Tandem Mass Spectrometry (LC-MS/MS (Liquid Chromatography-Tandem Mass Spectrometry)를 이용한 패류 및 피낭류 중 아자스필산 분석법의 유효성 검증)

  • Cho, Sung Rae;Jeong, Sang Hyeon;Park, Kunbawui;Yoon, Minchul;Kim, Dong Wook;Son, Kwang Tae;Ha, Kwang Soo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.54 no.4
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    • pp.404-410
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    • 2021
  • Although, mouse bioassay for the monitoring of azaspiracids (AZAs) toxins in shellfish has been used previously, the reported method has low sensitivity and it is time-consuming. Recently, there is an interest in the quantitative analysis of AZAs using liquid chromatography-tandem mass spectrometry (LC-MS/MS). The purpose of this study is to verify the simultaneous analysis of AZAs in shellfish and tunicate in Korea using LC-MS/MS. To validate the method, linearity, limit of detection (LOD), limit of quantification (LOQ), precision, accuracy, and repeatability were determined. All standard compounds were analyzed within 7 min. The correlation coefficients (R2) of the standard solution was higher than 0.9995 (within the range of 0.8-10.0 ㎍/L). The LODs and LOQs of AZAs in shellfish were 0.08-0.16 ㎍/kg and 0.23-0.50 ㎍/kg, respectively. The accuracy and precision of the method for determining AZAs in shellfish were 87.1-93.0% and 1.23-4.91%, respectively. Consequently, the verified LC-MS/MS method is suitable to analyze AZAs in shellfish and tunicates in Korea.

Application of nonlocal elasticity theory on the wave propagation of flexoelectric functionally graded (FG) timoshenko nano-beams considering surface effects and residual surface stress

  • Arani, Ali Ghorbanpour;Pourjamshidian, Mahmoud;Arefi, Mohammad;Arani, M.R. Ghorbanpour
    • Smart Structures and Systems
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    • v.23 no.2
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    • pp.141-153
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    • 2019
  • This research deals with wave propagation of the functionally graded (FG) nano-beams based on the nonlocal elasticity theory considering surface and flexoelectric effects. The FG nano-beam is resting in Winkler-Pasternak foundation. It is assumed that the material properties of the nano-beam changes continuously along the thickness direction according to simple power-law form. In order to include coupling of strain gradients and electrical polarizations in governing equations of motion, the nonlocal non-classical nano-beam model containg flexoelectric effect is used. Also, the effects of surface elasticity, dielectricity and piezoelectricity as well as bulk flexoelectricity are all taken into consideration. The governing equations of motion are derived using Hamilton principle based on first shear deformation beam theory (FSDBT) and also considering residual surface stresses. The analytical method is used to calculate phase velocity of wave propagation in FG nano-beam as well as cut-off frequency. After verification with validated reference, comprehensive numerical results are presented to investigate the influence of important parameters such as flexoelectric coefficients of the surface, bulk and residual surface stresses, Winkler and shear coefficients of foundation, power gradient index of FG material, and geometric dimensions on the wave propagation characteristics of FG nano-beam. The numerical results indicate that considering surface effects/flexoelectric property caused phase velocity increases/decreases in low wave number range, respectively. The influences of aforementioned parameters on the occurrence cut-off frequency point are very small.

Numerical and experimental investigation on the global performance of a novel design of a Low Motion FPSO

  • Peng, Cheng;Mansour, Alaa M.;Wu, Chunfa;Zuccolo, Ricardo;Ji, Chunqun;Greiner, Bill;Sung, Hong Gun
    • Ocean Systems Engineering
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    • v.8 no.4
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    • pp.427-439
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    • 2018
  • Floating Production Storage and Offloading (FPSO) units have the advantages of their ability to provide storage and offloading capabilities which are not available in other types of floating production systems. In addition, FPSOs also provide a large deck area and substantial topsides payload capacity. They are in use in a variety of water depths and environments around the world. It is a good solution for offshore oil and gas development in fields where there is lack of an export pipeline system to shore. However due to their inherently high motions in waves, they are limited in the types of risers they can host. The Low Motion FPSO (LM-FPSO) is a novel design that is developed to maintain the advantages of the conventional FPSOs while offering significantly lower motion responses. The LM-FPSO design generally consists of a box-shape hull with large storage capacity, a free-hanging solid ballast tank (SBT) located certain distance below the hull keel, a few groups of tendons arranged to connect the SBT to the hull, a mooring system for station keeping, and a riser system. The addition of SBT to the floater results in a significant increase in heave, roll and pitch natural periods, mainly through the mass and added mass of the SBT, which significantly reduces motions in the wave frequency range. Model tests were performed at the Korea Research Institute of Ships & Ocean Engineering (KRISO) in the fall of 2016. An analytical model of the basin model (MOM) was created in Orcaflex and calibrated against the basin-model. Good agreement is achieved between global performance results from MOM's predictions and basin model measurements. The model test measurements have further verified the superior motion response of LM-FPSO. In this paper, numerical results are presented to demonstrate the comparison and correlation of the MOM results with model test measurements. The verification of the superior motion response through model test measurements is also presented in this paper.

Analytical Study on Software Static/Dynamic Verification Methods for Deriving Enhancement of the Software Reliability Test of Weapon System (무기체계 소프트웨어 신뢰성 시험 개선점 도출을 위한 소프트웨어 정적/동적 검증 분석 사례연구)

  • Park, Jihyun;Choi, Byoungju
    • KIPS Transactions on Software and Data Engineering
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    • v.8 no.7
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    • pp.265-274
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    • 2019
  • The reliability test performed when developing the weapon system software is classified into static test and dynamic test. In static test, checking the coding rules, vulnerabilities and source code metric are performed without executing the software. In dynamic test, its functions are verified by executing the actual software based on requirements and the code coverage is measured. The purpose of this static/dynamic test is to find out defects that exist in the software. However, there still exist defects that can't be detected only by the current reliability test on the weapon system software. In this paper, whether defects that may occur in the software can be detected by static test and dynamic test of the current reliability test on the weapon system is analyzed through experiments. As a result, we provide guidance on improving the reliability test of weapon system software, especially the dynamic test.

A Study on the Steady-State Characteristics of Symmetric Pintle Nozzle with Varying Position of Pintle and Change in Altitude (대칭형 핀틀 노즐의 핀틀 위치와 고도 변화에 대한 정상상태 특성 연구)

  • Jeong, Kiyeon;Kang, Dong-Gi;Jung, Eunhee;Lee, Daeyeon;Choi, JaeSung
    • Journal of the Korean Society of Propulsion Engineers
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    • v.23 no.1
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    • pp.33-45
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    • 2019
  • In this study, numerical simulations were performed to investigate the steady-state characteristics of a symmetric pintle nozzle by varying the position of the pintle and the altitude. The pintle nozzle shape was used in a linear pintle nozzle that had been analyzed prior to the study, and the boundary conditions of the chamber were considered to be according to the propellant burn-back characteristics. A software was used to perform a verification analysis of the square nozzle, pintle nozzle, and high-altitude conditions with an appropriate analytical technique. The pintle position had three different nozzle throat area conditions-: fully closed, half open, and fully open, and the altitude was set at 0, 5, and 20 km. The study compared the thrust, pintle drive load, and static stability at each condition.

Analytical Study of High Speed Railway Braking Disc-hub for Enhancement of Cooling Performance (냉각 성능 향상을 위한 고속철도 제동 디스크 허브의 해석 연구)

  • Lee, Yong-Woo;Kim, Jang-Hoon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.22 no.3
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    • pp.199-207
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    • 2021
  • This study aimed to improve the performance of the KTX (Korea Train Express) brake system. To develop a braking disc-hub for the high-speed rail, the model performance was analyzed by finite element analysis, and the analysis results were verified using the braking test results. In addition, heat transfer analysis, thermal stress analysis, natural frequency analysis, and static analysis were conducted to examine the mechanical performance of the braking system. By deriving the design factors and conducting parametric analyses according to the shape of the hub, this study derived the optimal specifications that could improve heat dissipation and reduce weight. The cooling efficiency and structural performance of the optimization model were improved during braking compared to the existing model. It is expected that the design verification will be carried out through analyses of the optimal specifications so that it can be used in the development of brakes in railway vehicles and motor vehicles.

Neural network based numerical model updating and verification for a short span concrete culvert bridge by incorporating Monte Carlo simulations

  • Lin, S.T.K.;Lu, Y.;Alamdari, M.M.;Khoa, N.L.D.
    • Structural Engineering and Mechanics
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    • v.81 no.3
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    • pp.293-303
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    • 2022
  • As infrastructure ages and traffic load increases, serious public concerns have arisen for the well-being of bridges. The current health monitoring practice focuses on large-scale bridges rather than short span bridges. However, it is critical that more attention should be given to these behind-the-scene bridges. The relevant information about the construction methods and as-built properties are most likely missing. Additionally, since the condition of a bridge has unavoidably changed during service, due to weathering and deterioration, the material properties and boundary conditions would also have changed since its construction. Therefore, it is not appropriate to continue using the design values of the bridge parameters when undertaking any analysis to evaluate bridge performance. It is imperative to update the model, using finite element (FE) analysis to reflect the current structural condition. In this study, a FE model is established to simulate a concrete culvert bridge in New South Wales, Australia. That model, however, contains a number of parameter uncertainties that would compromise the accuracy of analytical results. The model is therefore updated with a neural network (NN) optimisation algorithm incorporating Monte Carlo (MC) simulation to minimise the uncertainties in parameters. The modal frequency and strain responses produced by the updated FE model are compared with the frequency and strain values on-site measured by sensors. The outcome indicates that the NN model updating incorporating MC simulation is a feasible and robust optimisation method for updating numerical models so as to minimise the difference between numerical models and their real-world counterparts.

Analysis of Chloride Content in Aqueous Solution and Mortar using Laser Induced Breakdown Spectroscopy (LIBS를 활용한 수용액과 모르타르 내 염화물량 분석)

  • Ryu, Hwa-Sung;Park, Won-Jun
    • Journal of the Korea Institute of Building Construction
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    • v.21 no.3
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    • pp.189-194
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    • 2021
  • LIBS has been attracting attention as an analytical method capable of real-time measurement without sample preparation. In this study, a Lab. scale LIBS device was fabricated to examine the applicability and reproducibility of LIBS in the analysis of chloride contents in mortar. The existing analysis method and LIBS analysis were performed simultaneously on the mortar test specimen with the chloride content adjusted. Compared to the chloride content condition of the mortar, the XRF and Potentiometric Titration results also showed a similar trend. As a result of LIBS analysis, chlorine ions were detected at a wavelength of 837.59 nm according to the chloride content condition. In order to improve the precision in various concentration ranges, the LIBS signal amplification of about 50 times through the electric field enhancement was implemented. Through the verification of the aqueous solution-based reproducibility, a high correlation between the LIBS signal strength and the Cl concentration was confirmed, and the possibility of applying LIBS to the durability diagnosis of concrete damage by chloride was confirmed.