• Korean Chemical Engineering Research
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• v.56 no.3
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• pp.416-420
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• 2018

A comprehensive kinetic study has been conducted on dimethyl carbonate synthesis by transesterification reaction of ethylene carbonate with methanol. An alkali base metal (KOH) was used as catalyst in the synthesis of DMC, and its catalytic ability was investigated in terms of kinetics. The experiment was performed in a batch reactor at atmospheric pressure. The reaction orders, the activation energy and the rate constants were determined for both forward and backward reactions. The reaction order for forward and backward reactions was 0.87 and 2.15, and the activation energy was 12.73 and 29.28 kJ/mol, respectively. Using the general factor analysis in the design of experiments, we analyzed the main effects and interactions according to the MeOH/EC, reaction temperature and KOH concentration. DMC yield with various reaction conditions was presented for all ranges using surface and contour plot. Furthermore, the optimal conditions for DMC yield were determined using response surface method.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.20 no.6
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• pp.562-567
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• 2010

A passenger vehicle has various and complicated transmission paths of sound and vibration. In order to identify the mechanism of transfer path, estimation of excitation force and exact modeling of transfer path are required. In this paper vector synthesis technique is employed to identify the characteristics of road noise and its transmission to vehicle compartment through noise and vibration analysis. Vibration reduction efficiency of each transfer path is evaluated by comparing individual vector components obtained virtual simulation. The degree of effect is used to estimate the contribution of vibration input components to total output. And in this paper presents a new technique based on simulation studies using vector synthesis diagram and design of experiments, by which the effects of magnitude and phase change of input paths can be predicted.

• Journal of the Korea Institute of Military Science and Technology
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• v.4 no.1
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• pp.93-103
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• 2001

A reflection signal in an active sonar using a high frequency is mainly formed of a specular reflection from the surface of an object along with several equivalent scatters inside, which are characterized by the spatial distribution of the highlight on the object. This study analyze the existing echo signal synthesis models eq, random distribution model, equivalent interval distribution model & MUTAHID(Modified Underwater TArget by HIlight Distribution) model for simulated target, and compare the characteristics of the reflected signal synthesis results for each model in various conditions. These highlight distribution models can be efficiently applied to the simulated target signals synthesis of various real systems requiring the echo signal synthesis on the underwater target.

• Bulletin of the Korean Chemical Society
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• v.33 no.8
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• pp.2609-2612
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• 2012

A simple green method was developed for rapid synthesis of silver and gold nanoparticles (AgNPs and AuNPs) has been reported using Lonicera japonica flower extract as a reducing and a capping agent. AgNPs and AuNPs were carried out at $70^{\circ}C$. The successful formation of AgNPs and AuNPs have been confirmed by UV-Vis spectro photometer, fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), energy dispersive X-ray Analysis (EDAX), scanning electron microscopy (SEM) and high-resolution transmission electron microscopy (HRTEM). To our knowledge, this is the first report where Lonicera japonica flower was found to be a suitable plant source for the green synthesis of AgNPs and AuNPs.

• ETRI Journal
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• v.34 no.5
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• pp.696-705
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• 2012

Accurate synthesis models based on artificial neural networks (ANNs) are proposed to directly obtain the physical dimensions of an asymmetric coplanar waveguide with conductor backing and substrate overlaying (ACPWCBSO). First, the ACPWCBSO is analyzed with the conformal mapping technique (CMT) to obtain the training data. Then, a modified genetic-algorithm-Levenberg-Marquardt (GA-LM) algorithm is adopted to train ANNs. In the algorithm, the maximal relative error (MRE) is used as the fitness function of the chromosomes to guarantee that the MRE is small, while the mean square error is used as the error function in LM training to ensure that the average relative error is small. The MRE of ANNs trained with the modified GA-LM algorithm is less than 8.1%, which is smaller than those trained with the existing GA-LM algorithm and the LM algorithm (greater than 15%). Lastly, the ANN synthesis models are validated by the CMT analysis, electromagnetic simulation, and measurements.

• The Transactions of the Korea Information Processing Society
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• v.7 no.4
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• pp.1299-1304
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• 2000

In a speed coding system using excitation source of voiced and unvoiced, it would be involved a distortion of speech quality in case coexist with a voiced and an unvoiced consonants in a frame. So, I propose TSIUVC(Transition Segment Including UnVoiced Consonant) searching, extraction ad approximation-synthesis method in order to uncoexistent with a voiced and unvoiced consonants in a frame. This method based on a zerocrossing rate and pitch detector using FIR-STREAK Digital Filter. As a result, the extraction rates of TSIUVC are 84.8% (plosive), 94.9%(fricative), 92.3%(affricative) in female voice, and 88%(plosive), 94.9%(fricative), 92.3%(affricative) in male voice respectively, Also, I obain a high quality approximation-synthesis waveforms within TSIUVC by using frequency information of 0.547kHz below and 2.813kHz above. This method has the capability of being applied to speech coding of low bit rate, speech analysis and speech synthesis.

• Korean Journal of Chemical Engineering
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• v.35 no.12
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• pp.2379-2383
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• 2018

We report a facile one-pot aqueous-phase synthesis of PdAu bimetallic nanoparticles with different Pd/Au ratio. The synthesis was conducted by co-reduction of Pd and Au precursor using ascorbic acid as a reducing agent and in the presence of polyallylamine hydrochloride (PAH). By high-angle annular dark field scanning transmission electron microscopy (HAADF-STEM) and energy-dispersive X-ray spectrometry (EDS) analyses, we found that the synthesized nanoparticles had an onion-like core/shell/shell/shell structure with Au-rich core, Pd-rich shell, Au-rich shell, and Pd shell, respectively. We also investigated the catalytic performance of the synthesized PdAu nanoparticles toward hydrogen peroxide generation reaction.

• Proceedings of the IEEK Conference
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• 1999.06a
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• pp.683-686
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• 1999

In this paper, we develop an active sonar signal synthesis model to analyze the detection performance of active sonar systems in a shallow water environment. Using this model, we synthesize the return signal of a bistatic sonar system at a typical operating frequency. This signal can be used to test proper active sonar signal processing techniques for real applications.

• Advances in nano research
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• v.1 no.4
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• pp.211-218
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• 2013

A low-cost, green and reproducible citric acid assisted synthesis of nanocrystalline $Al_{0.5}Ag_{0.5}TiO_3$ (n-AAT) powder is reported. X-ray, FTIR, energy dispersive X-ray, transmission electron microscopy and scanning electron microscopy analyses are performed to ascertain the formation of n-AAT. X-ray diffraction data analysis indicated the formation of monoclinic structure. Spherical shaped particles having the sizes of 3-15 nm are found. The mechanism of nano-transformation for the soft-chemical synthesis of n-AAT has been explained using simple organic chemistry rules and nucleation and growth theory. Dielectric study revealed that AAT ceramic might be a suitable candidate for capacitor applications.

• Proceedings of the Korean Society of Broadcast Engineers Conference
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• 1996.06b
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• pp.23-28
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• 1996

Model-based coding is one of several approaches to very low bit rate image coding and it can be used in many applications such as image creation and virtual reality. However, its analysis and synthesis processes remain difficult, especially in the sense that the resulting synthesized image reveals some degradation in detailed facial components such as furrows around eyes and mouth. To solve the problem, a large number of methods have been proposed and the texture update method is one of them. In this paper, we investigate texture synthesis for model-based coding. In the update process of the proposed texture synthesis algorithm, texture information is stored in a memory and the decoder reuses it. With this method, the transmission bit rate for texture data can be reduced compared with the conventional method updating texture periodically.