• Proceedings of the KIEE Conference
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• 2007.11a
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• pp.144-145
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• 2007

본 논문은 LabVIEW를 이용하여 온도측정과 amperometry 측정을 동시에 하며, amperometry 측정오차와 구동전압의 세팅 시간을 줄일 수 있는 시스템을 설계한 내용을 담고 있다. Amperometry는 구동전압을 인가하여, 전류를 측정하는 방법인데, 정확한 측정을 위해서는 구동전압을 균일하게 인가해야 한다. 또한 바이오 분야에서의 amperometry 측정은 온도에 따라 측정 결과가 다르게 나타날 수 있기 때문에 온도의 측정과 amperometry 측정이 동시에 이루어져야 측정오차를 줄일 수 있다. 본 논문에서는 이상(異常) 구동전압의 배제 알고리즘을 통하여 전류측정의 오차를 ${\pm}$70pA에서 ${\pm}$50pA이내로 줄였으며, proportional control을 응용한 알고리즘을 사용하여 307초의 측정시간을 105초로 단축하였다. 또한 amperometry 측정 과정에서 온도를 실시간으로 측정함으로써 측정상태를 보다 정확히 파악하는 시스템을 구성하였다.

• Journal of the Korean Chemical Society
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• v.48 no.6
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• pp.654-658
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• 2004

• Journal of the Korean Electrochemical Society
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• v.11 no.3
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• pp.147-153
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• 2008

Improvement of the selectivity of nonenzymatic glucose based on mesoporous platinum ($H_1$-ePt) by using A.C. impedance is reported. The idea of the present work is based on the novel effect of the mesoporous electrode that the apparent exchange current due to glucose oxidation remarkably grows although the reaction kinetics on the surface is still sluggish. It is expected that the enlarged apparent exchange current on the mesoporous electrode can raise the sensitivity of admittance in A.C. impedance to glucose concentration. At a low frequency, A.C. impedance could become more powerful. The admittance at 0.01 Hz is even more sensitive to glucose than to ascorbic acid while amperometry exhibits the inverse order of sensitivity. This is the unique behavior that is neither observed by A.C. impedance on flat platinum electrode nor obtained by amperometry. The study shows how the combination of A.C. impedance and nano-structured surface can be applied to the detection of sluggish reaction such as electrochemical oxidation of glucose.

• Journal of the Korean Chemical Society
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• v.67 no.5
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• pp.339-347
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• 2023

In this study, a nanocomposite of multi-walled carbon nanotubes@poly(p-phenylenediamine)-Prussian blue (MWCNTs@PpPD-PB) was synthesized and employed for the electrochemical detection of hydrogen peroxide (H₂O₂). A straightforward approach was utilized to prepare an electrochemical H₂O₂ sensor using a MWCNTs@PpPD-PB modified glassy carbon electrode, and its electrochemical behavior was investigated through techniques such as electrochemical impedance spectroscopy, cyclic voltammetry, and amperometry. The modified electrode displayed a favorable electrocatalytic response towards the reduction of H₂O₂ in an acidic solution. The developed sensor exhibited linearity in the concentration range of 0.005 mM to 2.225 mM for H₂O₂, with high sensitivity (583.6 ㎂ mM^-1cm^-2) and a low detection limit (0.95 ㎛, S/N = 3) at an applied potential of +0.15 V (vs. Ag/AgCl). Additionally, the sensor demonstrated excellent selectivity, reproducibility, and stability. Moreover, successful detection of H₂O₂ was achieved in real samples.

• Archives of Pharmacal Research
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• v.11 no.1
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• pp.56-60
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• 1988

A thin layer flow cell with cell volume of $8\;{\mu}{\ell}$ was constructed. Diffusion currents of ascorbic acid was directly proportional to the 1/3 power of volume flow rates. A linear dynamic range was obtained at the concentration range between $10^{-7}\;M\;and\;10^{-4}\;M$ of ascorbic acid with a detection limit of $10^{-8}\;M$. Ascorbic acid in the multivitamin product was amperometrically determined at TLFC after simply dissolving mg range ground product in $100m{\ell}$ of pH 7.0 phosphate buffer.

• Bulletin of the Korean Chemical Society
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• v.4 no.5
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• pp.217-219
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• 1983

A precise EDTA titrimetric method involving a weight titration of major portion with solid reagent followed by titration of the remainder with a very dilute standard solution has been developed for the determination of bismuth. When the end point is determined by means of amperometry with a rotating mercury electrode, the error in bismuth analysis is less than 0.01 % even when $Pb^{2+}$, $Zn^{2+}$, or $Cd^{2+}$ is present. However, copper interferes appreciably and masking with thiourea gives too low results.

• Journal of Sensor Science and Technology
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• v.23 no.4
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• pp.278-283
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• 2014

In this study, we propose an immunosensor using zinc oxide nanorods (NRs) inside PDMS channel for detecting the influenza A virus subtype H7N9. ZnO with high isoelectric point (IEP, ~9.5) makes it suitable for immobilizing proteins with low IEP. In this proposed H7N9 immunosensor structure ZnO NRs were grown on the PDMS channel inner surface to immobilize H7N9 capture antibody. A sandwich enzyme-linked immunosorbent assay (ELISA) method with was used 3,3',5,5' tetramethylbenzidine (TMB) for detecting H7N9 influenza virus. The immunosensor was evaluated by amperometry at various H7N9 influenza antigen concentrations (1 pg/ml - 1 ng/ml). The redox peak voltage and current were measured by amperometry with ZnO NWs and without ZnO NWs inside PDMS channel. The measurement results of the H7N9 immunosensor showed that oxidation peak current of TMB at 0.25 V logarithmically increased from 2.3 to 3.8 uA as the H7N9 influenza antigen concentration changed from 1 pg/ml to 1 ng/ml. And then we demonstrated that ZnO NRs inside PDMS channel can improve the sensitivity of immunosensor to compare non-ZnO NRs inside PDMS channel.

• Journal of the Korean Society of Food Science and Nutrition
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• v.41 no.9
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• pp.1301-1304
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• 2012

Mineral contents of various salts were determined by the ICP-OES method. Bamboo salt (baked 9 times) contained more potassium, calcium, magnesium, and manganese, compared to purified and solar salts. Bamboo salt had a pH of 11.04, higher than those of purified (6.29) and solar (9.13) salts. Contents of [$OH^-$] were measured by using the FT-IR spectra. Bamboo salt exhibited higher reduction potential and contained more OH groups than purified and solar salts. The reduction peak of bamboo salt was observed to be about three times broader than that of solar salt in terms of redox potential amperometry. At a salt concentration of 25%, bamboo salt showed higher radical scavenging activities (81.4%) than solar (5.0%) and purified (2.0%) salts, as evaluated by DPPH assay. Bamboo salt revealed alkaline property, more OH groups and antioxidative activity.

• Journal of Food Hygiene and Safety
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• v.32 no.6
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• pp.447-454
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• 2017

A new amperometric biosensor has been developed for the detection of hydrogen peroxide ($H_2O_2$). The sensor was fabricated through the one-step deposition of a biocomposite layer onto a glassy carbon electrode at neutral pH. The biocomposite, as a $H_2O_2$ sensing element, was prepared by the electrochemical deposition of a homogeneous mixture of graphene oxide, aniline, and horseradish peroxidase. The experimental results clearly demonstrated of that the sensor possessed high electrocatalytic activity and responded to $H_2O_2$ with a stable and rapid manners. Scanning electron microscopy, cyclic voltammetry, and amperometry were performed to optimize the characteristics of the sensor and to evaluate its sensing chemistry. The sensor exhibited a linear response to $H_2O_2$ in the range of 10 to $500{\mu}M$ concentrations, and its detection limit was calculated to be $1.3{\mu}M$. The proposed sensing-chemistry strategy and the sensor format were simple, cost-effective, and feasible for analysis of "food-grade $H_2O_2$" in food samples.

• Journal of Sensor Science and Technology
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• v.21 no.4
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• pp.311-317
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• 2012

Disposable amperometric screen-printed biosensor strips have been fabricated by a sol-gel encapsulation for the analysis of glucose. The glucose oxidase(GOx) is entrapped in the gel matrix through sol-gel transition of tetraethoxysliane(TEOS). The biosensor is fabricated by GOx containing thin film of TEOS gel on the surface of screen-printed carbon electrode(SPCE). The GOx-containing thin film of TEOS gel offers a one-step modification process on the surface of SPCE. The optimum conditions for glucose determination have been characterized with respect to the applied potential, enzyme loading ratio, and pH. The linear range and detection limit of glucose detection were from 2.0 mM to 16.0 mM and 0.25 mM, respectively.