• 한국자기학회지
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• 제7권1호
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• pp.7-12
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• 1997

회전형 볼밀을 이용하여 Ar 분위기에서 기계적 합금화 방법으로 Fe$_{50}$Zr$_{50}$ 비정질을 제조하고 이들의 구조 및 자기적 성질을 투과전자현미경과 SQUID 자력계를 이용하여 조사하였다. 기계적합금화법으로 제조된 분말로 부터 얻은 제한시야 회절도형은 두개의 인접한 halo ring 도형을 나타내며, 이것은 비정질이 Fe rich 한 비정질과 Zr rich 한 두 비정질로이 공존하기 때문이다. 기계적 합금화한 Fe$_{50}$Zr$_{50}$ 비정질 분말에서 비정질상의 큐리온도로 부터 추정된 강자성 Fe-Zr계 비정지상의 Fe 조성은 100시간 합금화한 경우 65 at% 로서, 이것은 비정질의 상분리가 일어났기 때문이며, 이 결과는 회절도형의 분석결과와 일치한다. 기계적 합금화한 Fe$_{50}$Zr$_{50}$ 분말의 스핀파 탄성계수는 100시간 합금화한 경우에는 52.2 meV .angs. 이고, 200시간 합금화 한 경우에는 63.8 meV .angs. 으로 합금화시간이 증가함에 따라 증가하였다. 이것으 200시간 합금화한 경우 부분 결정화에 의하여 .alpha. -Fe가 일부 석출하였기 때문이다.

• 한국재료학회지
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• 제5권8호
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• pp.913-920
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• 1995

RFe$_2$(R=rare earth) Laves상 금속간 화할물은 $10^{-3}$ 정도의 큰 포화 자왜 정수를 나타내고 있어, 자왜 재료의 응용 분야에서 많은 주목을 받고 있다. 그러나, 이 금속간 화합물은 결정 자기 이방성 에너지가 크기 때문에, 큰 포화 자왜 정수를 얻기 위해서는 높은 외부 자장이 요구되어진다. 이에 따라 저자장에서 보다 높은 자왜 정수를 얻고자 하는 연구들이 행하여 지고 있는데, 이를 위한 방법은 RFe$_2$Laves상 금속간 화합물중 결정 자기 이방성 부호가 각기 다른 회토류 금속의 치환 혹은 RFe$_2$금속간 화합물의 비정질화이다. 본 연구에서는 RFe$_2$금속간 화합물의 자기 이방성 에너지를 최소화하여 저자장에서 높은 자왜 정수를 얻기 위해, 결정 자기 이방성 정수 및 자왜 정수의 부호가 각각 반대인 SmFe$_2$와 PrFe$_2$을 합금화 한후, 비정질화하여 자왜 정수의 변화를 포함한 자성을 조사하였다.

• Journal of Periodontal and Implant Science
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• 제41권6호
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• pp.263-272
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• 2011

A number of surface modification techniques using immobilization of biofunctional molecules of Titanium (Ti) for dental implants as well as surface properties of Ti and Ti alloys have been developed. The method using passive surface oxide film on titanium takes advantage of the fact that the surface film on Ti consists mainly of amorphous or low-crystalline and nonstoichiometric $TiO_2$. In another method, the reconstruction of passive films, calcium phosphate naturally forms on Ti and its alloys, which is characteristic of Ti. A third method uses the surface active hydroxyl group. The oxide surface immediately reacts with water molecules and hydroxyl groups are formed. The hydroxyl groups dissociate in aqueous solutions and show acidic and basic properties. Several additional methods are also possible, including surface modification techniques, immobilization of poly(ethylene glycol), and immobilization of biomolecules such as bone morphogenetic protein, peptide, collagen, hydrogel, and gelatin.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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• pp.364-365
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• 2006

Nanostructured or partially amorphous Al-and Zr-based alloys are attractive candidates for advanced high-strength lightweight materials. Such alloys can be prepared by quenching from the melt or by powder metallurgy using mechanical attrition techniques. This work focuses on mechanically attrited powders and their consolidation into bulk specimens. Selected examples of mechanical deformation behavior are presented, revealing that the properties can be tuned within a wide range of strength and ductility as a function of size and volume fraction of the different phases.

• 한국자기학회지
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• 제5권5호
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• pp.483-486
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• 1995

Soft magnetic properties of Fe-based (Fe,Co)-B-Al-M (M=Nb, Mo or Ta) nanocrystalline alloy have been investigated. The alloy obtained directly form the rapid solidification process. Microstructure of the alloy is a mixtu re of ultrafine bcc Fe(Co) nanocrystallines and a small amount of retained amorphous phase. Heat treatment of as-prepared alloys improves soft magnetic properties in high frequency range. ${(Fe_{.85}Co_{.15})}_{70}B_{18}Al_{10}Ta_{6}$ alloy alloy annealed at $500^{\circ}C$ for 1 h shows the most improved soth magnetic properties among the alloy examined. Average grain size of the nanocystalline is about 10 nm.

• 소성∙가공
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• 제30권5호
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• pp.247-254
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• 2021

This study reviews dynamic deformation behavior of ultra-fine-grained Al alloys, ultra-fine-grained conventional low carbon steel and dual phase steel and Zr-based amorphous alloys. Dynamic tests were conducted using a Kolsky bar then the test data was analyzed in relation to resultant microstructures, mechanical properties and propensity of adiabatic shear band. In addition, deformed microstructures and fracture surfaces were used to investigate the behavior of both the dynamic deformation and fracture, and adiabatic shear banding. As a result, increasing microstructural homogeneity, strain hardenability and forming multiple shear bands could be a better way to increase the fracture resistance under dynamic loading as the formation of adiabatic shear bands was reduced or prevented.

• 한국자기학회지
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• 제2권3호
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• pp.211-215
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• 1992

The temperature-dependent saturation magnetization curves of amorphous $Fe_{80-x}Co_xB_{20}$ (8 ${\le}$ x ${\le}$ 40, the step of x is 8) alloys were measured using a vibrating sample magnetometer from 77 K up to 1000 K. Curie temperature and the Bloch coefficient were estimated from the saturation magnetization curves. The low temperature dependence of magnetization is in good agreement with Bloch relation, $M_s(T)$=$M_s(O)$ (1-$BT^{3/2}$ - ${\cdots}.$). The spin wave stiffness constant, tne range of the exchange interaction, and the probable atomic spin were calculated from the saturation magnetization values.

• 한국수소및신에너지학회논문집
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• 제8권4호
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• pp.173-180
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• 1997

The Mechanically Alloyed $Ti_{0.7}Mg_{0.3}Ni$ was investigated as a function of milling time by X-ray diffraction, SEM(scanning electron microscope), EDS(energy dispersive spectrometer), P-C-Isotherm curves. After 10hrs milling, mixed $Ti_{0.7}Mg_{0.3}Ni$ powders were changed to amorphous phase. And amorphous $Ti_{0.7}Mg_{0.3}Ni$ alloys became TiNi phase crystalline after heat treatment at 873K in a vacuum for 1 hour. The hydrogen absorption capacity of the annealed $Ti_{0.7}Mg_{0.3}Ni$ alloy increased as a function of mechanical alloying time.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2008년도 추계학술대회A
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• pp.1718-1722
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• 2008

This study explores the influence of volume fraction of nanocrystals of Cu-Zr amorphous alloys on shear band formation. As the number of crystals with very tiny size increases, the strain localization, i.e. shear band, decreases without large drop of flow stress. The DPRs also depict no sudden drop and relatively high values. The strain state during the deformation represents a few shear bands at low volume fraction while there are no distinguishable shear bands at high volume fraction of nanocrystals.

• 한국자기학회지
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• 제10권1호
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• pp.7-10
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• 2000

Co계 비정질합금을 400~46$0^{\circ}C$에서 열처리 한 후 냉각조건에 따른 자기특성의 변화를 조사하였다 42$0^{\circ}C$에서 30분 열처리 한 뒤 큐리점까지 노냉 후 수냉 시킨 경우 초투자율이 수냉 또는 노냉 했을 때보다 60-100% 정도 증가했다. 냉각속도에 따른 자기적 특성 변화를 내부음력 및 이온쌍의 규칙도(ordering) 관점에서 고찰하였다