• 제목/요약/키워드: ammonium sulfate

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방사성핵종 오염 토양 특성 분석 및 핵종제거 방법 연구

  • 김계남;원휘준;오원진
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2002년도 총회 및 춘계학술발표회
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    • pp.209-212
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    • 2002
  • Main radionuclides of the soil waste stored in Korea Atomic Energy Research Institute are Co-60 and Cs-137. Moisture content of soil is 12%, pH of soil is 5.8, and content of organic matter is 2.2 %. Radioactive concentrations of the soil particle size of which is less than 0.063mm and soil in the drum surface of which is more than radiation dose rate 0.05mR/hr are higher. Meanwhile, radioactive concentration of soil in the drum surface of which is less than radiation dose rate 0.02 mR/hr are mostly lower. On using the mixing solution of ammonium sulfate and citric acid, 62% Co was removed from soil and 41% Cs was removed. Also, on using the mixing solution of ammonium nitrate and citric acid, 61% Co was removed from soil and 39% Cs was removed, and on using the mixing solution of ammonium potassium oxalate, 36% Co was removed and only 3% Cs was removed. And on using only water, removal efficiency is less than 5%.

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프탈레이트 에스터 분해세균의 분리 및 분해효소의 최적 생성조건 (Isolation and Identificatioh~ of a Phthalate Ester Degrading Bacterium and the Optimal Culture Conditions for Production of One Degrading Enzyme)

  • 김병오;김란숙;진익렬;박완
    • 한국미생물·생명공학회지
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    • 제18권6호
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    • pp.553-559
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    • 1990
  • 많은 관심이 집중되고 있는 환경오염의 대처방안의 일환으로, plastic 및 wrap 제조시 가소제로 가장 널리 사용되고 폐수 중에 대량 유출되어 인체에 유독한 난분해성 고분자 유기합성 물질로서 문제가 되고 있는 phthalate ester의 일종인 dibutyl phthalate(DBP)를 분해 자화할 수 있는 미생물을 분리하고자 했다. 저자들은 대구 근교의 토양 및 sludge에서 DBP 분해 관련 효소인 protocatechuate dioxygenase을 생성하는 새로운 균주를 분리하여 동정하였다.

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3상 생물막유동층반응기를 이용한 황화수소와 암모니아의 동시제거

  • 박진수;문종혜;김종우;김동욱;오광중
    • 한국생물공학회:학술대회논문집
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    • 한국생물공학회 2000년도 춘계학술발표대회
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    • pp.339-342
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    • 2000
  • 황화수소와 암모니아 함유악취의 동시처리를 위해 Thiobacillus sp.IW가 함유된 3상 생물막유동층반응기를 사용하였다. 본 연구에서 황화수소는 미생물에 의해 산으로 전환되었으며 이어서 유입된 암모니아와 반응하여 황산암모늄이 생성됨으로서 양성분은 제거되었다. 황화수소의 경우 45 mg/l h의 유입량에서도 거의 완전한 처리 효율을 보여주었으나, 암모니아의 경우 유입량이 10 mg/l h에서 증가함에 따라 처리효율은 점차 감소하였다.

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국산 명반석과 황산염으로부터 고순도의 미세한 알루미나의 제조 및 특성에 관한 연구 (Fabrication and Characterization of High Purity of Fine Alumina from Korean Alunite and Sulfate Salts)

  • 변수일;이수영;김종희
    • 한국세라믹학회지
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    • 제16권1호
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    • pp.13-20
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    • 1979
  • High purity alumina has been extracted form low grade Korean alunite. Alunite ore was treated by 15% $NH_4OH$ solution, followed by 10% $H_2SO_4$ leaching and metallic impurities such as Fe and Ti were removed by solvent extraction method. Alumina prepared by the extraction process was 99.9% in purity. Hot Petroleum Drying Method has been employed for the preparation of uniformly fine alumina powder, using chemical reagent aluminum sulfate and ammonium aluminum sulfate extrated from Korea alunite. The sinterability of alumina powder prepared by Hot Petroleum Drying Method was shown to be improved in comparison with the one treated by other methods such as ball milling method, but dry pressing was difficult due to the agglomeration of calcined powder. The best slip of alumina powder prepared by Hot Petroleum Drying Method contained a lower soild content than the one treated by other methods. The alumina body formed by soild and drain casting with the former alumina powder showed a higher sintered density.

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Manufacture of Vanadium pentoxide and nickel sulfate from heavy oil fly ash

  • Park, Gyeong-Ho
    • 자원리싸이클링
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    • 제2권4호
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    • pp.23-26
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    • 1993
  • This work is carried out to develop the recovery process of vanadium as vanadium pentoxide and nickel as nickel sulphate from the leaching solution of heavy oil fly ash. First, sodium chlorate solution was added to the leaching solution to oxidize vanadium ions. With adjusting pH of the solution and heating, vanadium ions(V) is hydrated and precipitated as red cake of $V_2O_5$ from the solution. After recovering vanadium, nickel is recovered as ammonium nickel sulfate with crystallization process. From this nickel salt, nickel sulfate which meets the specifications for the electroplating industry can be produced economically. More than 85% of vana-dium and nickel in the fly ash are recovered in this process.

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제주도 고산에서의 에어로솔 입경분포별 조성: 1998년 4월 측정 연구 (Aerosol Size Distribution and Composition at Kosan, Cheju Island : Measurements in April 1998)

  • 김용표;배귀남;지준호;진현철;문길주
    • 한국대기환경학회지
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    • 제15권5호
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    • pp.677-685
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    • 1999
  • Aerosol mass size distributions were measured at Kosan, Cheju Island in April 1998 and their compositions were analyzed. Microorifice Uniform Deposit Impactor(MOUDI) was used to collect aerosols. Sulfate and ammonium ions were predominatly present at fine mode of the aerosols while nitrate, chloride, and metal ions were mostly at coarse mode. Based on the size distribution of nitrate, it is suggested that most nitrate were from gas to particle conversion on coarse particles. Non-sea salt(nss) fraction of sulfate accounted for more than 90% of total sulfate mass concentration. In general, ion concentrations in this study are lower than those measured at the same site from the previous studies. Ion balance and chloride ion levels indicates that there had been anthropogenic chloride emission sources near to the site during the measurements.

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서울시 초미세먼지 질량농도 저감을 위한 입자 내 이온성분 최적감축방법 예측 (Estimation of Optimum PM2.5 Ionic Concentration Control Strategy for Reducing Fine Particle Mass Concentrations in Seoul)

  • 김정연;이지원;김용표
    • 한국입자에어로졸학회지
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    • 제6권4호
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    • pp.151-164
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    • 2010
  • Inorganic ions and water are major components of ambient fine particles. Water content in fine particles is mainly determined by ambient meteorological conditions and the concentrations of hygroscopic species such as inorganic ions. Thus, to reduce fine particle mass concentration, it is important to accurately estimate the relationship between water content and the concentration of ions in fine particles. Water content in fine particles in Seoul are estimated by using a gas/particle equilibrium model to understand the characteristics of fine particle mass concentration. In addition, sensitivity of fine particle mass concentration to the changes of particulate ionic species (sulfate, nitrate, and ammonium) is estimated. It was found that water content in Seoul is mostly determined by the concentrations of the hygroscopic ionic species, especially, sulfate and ammonium, and ambient relative humidity.

수산을 사용한 크롬도금의 광택성에 미치는 도금액의 조성과 도금조건의 영향 (Effect of Bath Compositions and Plating Conditions for Decorative Properties of Chromium Deposits using Oxalic Acid)

  • 오이식;박정덕
    • 동력기계공학회지
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    • 제5권3호
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    • pp.80-87
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    • 2001
  • Decorative properties of chromium depositions from oxalic acid bath containing chromium oxide and ammonium sulfate have been examined over a wide range of bath compositions and plating conditions. The obtained results from this experiment are summarized as follow: The followings were determined as a optimum conditions, bath compositions; $CrO_3\;200{\sim}250\;g/{\ell},\;H_2C_2O_4{\cdot}2H_2O\;500{\sim}700\;g/{\ell},\;(NH_4)_2SO_4\;40{\sim}120\;g/{\ell}$, and operation conditions; pH $2.0{\sim}2.5$, current density $15{\sim}250\;A/dm^2$ at bath temperature range of $30{\sim}80^{\circ}C$. Bright chromium deposits were obtained over a wide range of ammonium sulfate concentration and bath temperature. Decorative property for chromium deposition was adopted to apply stoichiometric ratio of $CrO_3$ concentration and $H_2C_2O_4{\cdot}2H_2O$.

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Biofilter를 이용한 폐가스중의 styrene 제거

  • 강염석;황재웅;장석진;박성훈
    • 한국생물공학회:학술대회논문집
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    • 한국생물공학회 2000년도 춘계학술발표대회
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    • pp.394-397
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    • 2000
  • Styrene을 제거하기 위한 biofilter가 연구되었다. 운전 초기에 활성슬러지를 접종함으로써 start-up 기간을 24시간으로 줄일 수 있었다. 운전중 질소원 고갈 현상이 발생하였고 첨가된 ammonium sulfate양에 따라 제거된 styrene의 양을 정량적으로 구하여 이것을 biofilter의 장기운전에 이용할 수 있었다. Styrene의 maximum elimination $capacity(EC_{max})$와 critical elimination $capacity(EC_{cr})$는 각각 4.8kg $C\;/m^3{cdot}day$, 1.248kg $C\;/m^3{cdot}day$이었으며 styrene 농도 400ppmv까지를 분해하는데 EBRT 1min으로 제거율 95% 이상을 달성할 수 있었다.

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