Fabrication and Characterization of High Purity of Fine Alumina from Korean Alunite and Sulfate Salts

국산 명반석과 황산염으로부터 고순도의 미세한 알루미나의 제조 및 특성에 관한 연구

  • 변수일 (한국과학원 재료공학과) ;
  • 이수영 (한국과학원 재료공학과) ;
  • 김종희 (한국과학원 재료공학과)
  • Published : 1979.01.01

Abstract

High purity alumina has been extracted form low grade Korean alunite. Alunite ore was treated by 15% $NH_4OH$ solution, followed by 10% $H_2SO_4$ leaching and metallic impurities such as Fe and Ti were removed by solvent extraction method. Alumina prepared by the extraction process was 99.9% in purity. Hot Petroleum Drying Method has been employed for the preparation of uniformly fine alumina powder, using chemical reagent aluminum sulfate and ammonium aluminum sulfate extrated from Korea alunite. The sinterability of alumina powder prepared by Hot Petroleum Drying Method was shown to be improved in comparison with the one treated by other methods such as ball milling method, but dry pressing was difficult due to the agglomeration of calcined powder. The best slip of alumina powder prepared by Hot Petroleum Drying Method contained a lower soild content than the one treated by other methods. The alumina body formed by soild and drain casting with the former alumina powder showed a higher sintered density.

Keywords

References

  1. Ber. Dtsch. Keram. Ges. v.54 no.3 Nasschemische Methode zur Erzeugung von Synthetischen Rohstoffen und von Homogenen Pulvern fuer Physikalisch-Chemische Untersuchungen P. Reynen;H. Bastius;M. Faizullah;H.V. Kamptz
  2. 한국세라믹학회지 v.14 no.3 다성분계 산화물의 요업재료 제조를 위한 석유증발 건조방법 변수일
  3. Bull. Amer. Ceram. Soc. v.50 no.6 Theoretically Dense(99.9%), Polycrystalline Alumina Prepared from Cryochemically Processed Powders Y.S. Kim;F.R. Monforte
  4. Azerbajdzhanskij Khim. Zh. v.1 Extraction of Alkali Metal Sulfates from Alunite by Ammonia Leaching G.B. Shakhtakhtiskij;Sh. P. Banamov
  5. 단국대 논문집 v.2 국산 Alunite로 부터 Alum과 Aluminum Sulfate 추출에 관한 연구 손선관
  6. Science of Ceramics v.4 A Cryochemical Method for Preparing Ceramic Materials F.J. Schnettler;F.R. Monforte;W.W. Rhodes
  7. 한국세라믹학회지 v.16 no.2 석유증발 건조방법에 의한 Mn-Zn Ferrite의 제조에 관한 연구 변수일
  8. J. Amer. Ceram. Soc. v.39 no.10 Sintering and Grain Growth of α-Al₂O₃ H.P. Cahoon;C.J. Christensen
  9. Bull. Amer. Ceram. Soc. v.41 no.12 Sintering Kinetics for the High Density Alumina Process C.A. Bruch
  10. Bull. Amer. Ceram. Soc. v.51 no.11 High Purity Reactive Alumina Powders :Ⅰ Chemical and Powder Density L. Berrin;D.W. Johnson;D.J. Nitti
  11. Bull. Amer. Ceram. Soc. v.51 no.12 High Purity Reactive Alumina Powders : Ⅱ Particle Size and Agglomeration Study D.W. Johnson;D.J. Nitti;L. Berrin
  12. J. Amer. Ceram. Soc. v.45 no.3 Sintering Alumina : Effect of Atmospheres R.L. Coble