• Title/Summary/Keyword: ammonium sulfate

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Cyclic process for the preparation of synthetic rutile and pure iron oxide from the domestic titaniferous magnetite ore (국내 부존의 함티탄자철광으로 부터 합성 rutile 및 고순도 철화산화물의 제조를 위한 순환 공정)

  • Lee, Chul-Tae;Ryoo, Young-Hong
    • Applied Chemistry for Engineering
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    • v.2 no.4
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    • pp.372-384
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    • 1991
  • The sulfation of the domestic titaniferous magnetite ore with ammonium sulfate was investigated to find a cyclic process for the production of synthetic rutile and high purity iron oxide and to test the feasibility of ammonium sulfate being an alternative sulfation agent. The proper sulfation conditions were determined to be a temperature of $425^{\circ}C$, 2.5 hours of reaction time, the weight ratio of ammonium sulfate to titaniferous magnetite : 11, and particle size or titaniferous magnetite : -250 mesh. 90.4 % of $TiO_2$ and 85.3 % of iron were extracted from the titaniferous magnetite sulfated under these conditions by the water leaching. From the leachate $TiO_2$ of 93.8 % purity as a mixture of rutile and anatase and ${\alpha}-Fe_2O_3$ of 97.6 % purity were obtained.

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Sequential Separation of Lysozyme and Ovalbumin from Chicken Egg White

  • Abeyrathne, Nalaka Sandun;Lee, Hyun Yong;Ahn, Dong Uk
    • Food Science of Animal Resources
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    • v.33 no.4
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    • pp.501-507
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    • 2013
  • Lysozyme was trapped from $2{\times}$ diluted egg white using Amberlite FPC 3500 ion exchange resin (1 g/10mL of egg white). The lysozyme bound to the resin was recovered using 0.1 N glycine-NaOH buffers, pH 9.0, containing 0.5 M NaCl. After separating lysozyme, the pH of the egg white solution was adjusted to 4.75 and centrifuged to remove interfering proteins. The supernatant was collected, added with 2.5% citric acid and 5.0% ammonium sulfate combination to precipitate egg white proteins, except for ovalbumin. After centrifugation, both supernatant (S1) and precipitant were collected. The precipitant was dissolved with 4 volumes of distilled water, and then 2.0% ammonium sulfate and 1.5% citric acid combinations added, stirred overnight in a cold room, and centrifuged. The resulting supernatant (S2) was pooled with the first supernatant (S1), desalted using an ultrafiltration unit, heat-treated at $70^{\circ}C$ for 15 min, and then centrifuged. The supernatant was collected as an ovalbumin fraction and lyophilized. The separated proteins were confirmed using Western blotting. The yield of lysozyme and ovalbumin was > 88.9% and > 97.7%, respectively, and the purity of lysozyme and ovalbumin was > 97% and 87%, respectively. The results indicated that the protocol was simple, and separated lysozyme and ovalbumin effectively.

Sulfating Reaction of Coal Fly Ash and Microwave Extraction of Aluminum Ions (석탄회의 황산화반응과 알루미늄이온의 마이크로파 추출)

  • 박영증;박영민;양태영;윤석영;박홍채
    • Journal of the Korean Ceramic Society
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    • v.40 no.9
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    • pp.897-901
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    • 2003
  • The sulfating reaction of coal fly ash with ammonium sulfate and the microwave extraction of aluminum ions from the resultant materials using sulfuric acid have been investigated. The (NH$_4$)$_3$Al(SO$_4$)$_3$ formed by the reaction of coal fly ash and ammonium sulfate decomposed to NH$_4$Al(SO$_4$)$_2$ at $\geq$ 350$^{\circ}C$. The maximum efficiency of aluminum ions extracted from the sulfating reaction product (400$^{\circ}C$, 120 min) by microwave heating (90$^{\circ}C$, 240 min) using 1 M H$_2$SO$_4$ was 84% (based on Al content in coal fly ash) but 77% by conventional heating at same condition.

Production of Ammonia Water and Sulfuric Acid from Ammonium Sulfate by Electrodialysis with a Bipolar Membrane (바이폴라막 전기투석을 이용한 황산암모늄으로부터 암모니아수와 황산의 제조)

  • Hwang, Ui-Son;Choi, Jae-Hwan
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.1
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    • pp.36-42
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    • 2005
  • This study examined the feasibility of producing sulfuric acid and ammonia water from ammonium sulfate solution using two-compartment electrodialysis with a bipolar membrane (EDBM). Electrodialysis experiments were carried out with 20 wt% ammonium sulfate at different current densities and sulfuric acid concentrations in a concentrate compartment. The current efficiency increased with the current density from 25 to $100\;mA/cm^2$. Nevertheless, the efficiency was relatively low compared with that of general desalting electrodialysis, owing to the diffusion of sulfuric acid from the concentrate compartment to the diluate. The diffusion rate through the anion exchange membrane increased with the sulfuric acid concentration in the concentrate compartment, which decreased the current efficiency. Conversely, the electrical resistance decreased with increasing current density owing to the Joulian heat generated during water dissociation in the transition region of the bipolar membrane under a high electric field. From the experimental results, we concluded that operating at a higher current density is effective from the perspective of current efficiency and electrical resistance when producing sulfuric acid and ammonia water from ammonium sulfate using a two-compartment EDBM process. Further studies on the effects of increasing the sulfuric acid concentration on current efficiency are required to apply the EDBM process practically.

Mechanism of Cadmium Accumulation in the Cell of Cadmium-Tolerant Bacterium, Pseudomonas putida (카드뮴내성균(耐性菌)(Pseudomonas putida)에 의한 균체내(菌體內) 카드뮴 축적(蓄積) 기작(機作))

  • Heo, Jong-Soo;Cho, Ju-Sik;Han, Mun-Gyu
    • Korean Journal of Environmental Agriculture
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    • v.11 no.1
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    • pp.67-76
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    • 1992
  • A mechanistic study by which Cadmium-tolerant P.Putida C1 accumulates high conc of Cd in its cell body was performed. Approximately 57% Cd accumulated was distributed on the cell wall and the other 43% portion was in cytoplasm. 84% Cd of the Cd in the cell wall fractions present in the polyphosphate-polysaccharide fractions, but most of Cd in the cytoplasm fraction was in protein and nucleic acid. Cadmium affected the protein synthesis in P. Putida. The intracellular protein content was decreased by cadmium addition, but the soluble protein precipitated by ammonium sulfate($30{\sim}75%$ satruation) was increased as compared to that from the cells grwon without cadmium. Furthermore, in the cells grown with of cadmium, high-molecular-weight soluble protein was increased, with of cadmium, high-molecular-weight soluble protein was increased, compared with the cells grown without cadmium, but low-molecular-weight soluble protein was decreased. These results indicate that Cd inhibited the intracellular protein biosynthesis but enhance biosynthesis of the high-molecular-weight soluble protein precipitate by ammonium sulfate($30{\sim}75%$ saturation).

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Optimization of Culture Conditions for the Production of Antibacterial Activities by Paenibacillus polymyxa DY1 Isolated from Soil (토양에서 분리한 Paenibacillus polymyxa DY1의 항균활성물질 생산을 위한 배양조건 최적화)

  • Shin, Eun-Seok;Kwon, Sun-Il;Yoo, Kwan-Hee
    • Korean Journal of Environmental Biology
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    • v.25 no.4
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    • pp.342-348
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    • 2007
  • In a previous study, a new antibacterial activity was found from Paenibacillus polymyxa DY1 isolated from Korean soil, which showed a good growth inhibition against various multidrug resistant enteric bacteria. Thus the effect of nutritional factors and physicochemical conditions on the growth of P. polymyxa DY1 cells and the production of antibacterial activity were evaluated in this study. For the growth of P. polymyxa DY1 cells the optimum condition reaches by incubating at $35^{\circ}C$ for 48 hours by shaking at 180 rpm in the basal medium containing 0.6% dextrose, 1.4% ammonium phosphate dibasic, 0.9% peptone, 2.4% glutamine, and 2 mM sodium molybdate with initial pH 8.0. A maximum level of antibacterial activity was obtained when P. polymyxa DY1 was incubated at $35^{\circ}C$ for 48 hours by shaking at 180 rpm in the basal medium with initial pH 8.0 containing 1% dextrose, 1.5% ammonium sulfate, 1.1% casamino acid, 1.9% aspartic acid, and 2 mM ferrous sulfate.

Effects of Nitrogen Fertilization on Physiological Characteristics and Growth of Populus sibirica Seedlings in a Semi-arid Area, Mongolia (몽골 반건조지에서의 질소 시비가 Populus sibirica 묘목의 생리 및 생장 특성에 미치는 영향)

  • Chang, Hanna;Han, Seung Hyun;Kang, Hoduck;Akhmadi, Khaulenbek;Son, Yowhan
    • Journal of Korean Society of Forest Science
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    • v.106 no.1
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    • pp.19-25
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    • 2017
  • This study was conducted to investigate the effects of nitrogen fertilization on physiological characteristics and growth of Populus sibirica seedlings in a semi-arid area, Mongolia. 2-year-old P. sibirica seedlings were planted in May, 2015 with applications of urea 5 g (N1), 15 g (N2), 30 g (N3) and ammonium sulfate 33 g (NS; same nitrogen amount with N2) to each seedling. Chlorophyll contents were significantly different among treatments in August, but not in June and July. The lower chlorophyll contents in August than those in June and July might be related to leaf senescence. In June and July, net photosynthetic rate was higher in NS and N2 than in the control. Unlike the tendency of photosynthesis, transpiration rate was highest in N2, but lower in NS than in any other nitrogen treatments. Relative growth rate of root collar diameter was significantly higher only in NS than in the control and it of height did not differ among treatments. Leaf area in nitrogen treatments was not significantly different from that in the control. Ammonium sulfate seemed to be more suitable fertilizer than urea for the early growth of P. sibirica seedlings in the study site. However, as the effects of urea and ammonium sulfate on soils and seedlings were different, further studies would be necessary to determine the optimal amount of ammonium sulfate.

Utilization of Porcine Blood and Liver in Yeast Culture for Animal Diets and Effects of Yeast Culture on the Growth of Broiler Chicks (돼지혈액 및 간을 이용한 사료용 효모배양과 효모배양물이 육계성장에 미치는 영향)

  • 마정숙;심관섭;박강희
    • Journal of Animal Environmental Science
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    • v.7 no.1
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    • pp.21-28
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    • 2001
  • Optimal conditions for utilizing the slaughtered porcine blood and liver for yeast culture and the effects of the yeast cultures on the growth of broiler chicks were investigated. The quantity of yeast cultured for 24hours in the BSG medium containing blood extracts containing 5% glucose and in the LSG medium containing liver extracts containing 5% glucose were higher by 4% and 10%, respectively, than that in the YEPD medium containing 1% yeast extracts, 2% bacto pepton and 2% glucose. Optimal concentrations of ammonium sulfate supplementation to the BSG medium to increase the quantity of yeast cultured for 24 and 48 hours were 100 mM(1.3%) and 50 mM(0.65%), respectively. The optimal pH for yeast culture in BSG medium ranged from 6 to 7. One percent supplementation of either ammonium sulfate or taurine to LSG medium increased the quantity of yeast by 18% and 9%, respectively, compared to no supplementation. The body weight of chicks fed with 2% and 4% yeast culture supplementations cultivated increased at the 4th week by 10%, with relative to no supplementation. The results from this study suggest that the slaughtered porcine blood and liver can be utilized for yeast culture which is used in animal diets.

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Preparation of Alumina and Amorphous Silica from Clay Minerals (점토광물로부터 알루미나 및 비정질 실리카 제조에 관한 연구)

  • 박희찬;조원제;강효경;손명모
    • Journal of the Korean Ceramic Society
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    • v.26 no.1
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    • pp.81-90
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    • 1989
  • High purity alumina and amorphous silica were prepared from Ha-dong kaolin by means of appliance of sulfuric acid. The effect of sulfuric acid concentration, reaction temperature and reaction time on the formation of aluminum sulfate was investigated. The precipitation conditions ofaluminum sulfate from the sulfuric acid solution with ethanol and ammonium hydroxide were deteremined. In the optimum condition, the conversion of aluminum oxide in kaolin to aluminum oxide powder was 85.0 percent. Alumina powder was prepared by calcination of the precipitates, and its purity was 99.0 percent.

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Major Factors Affecting PM2.5 Water Content in Seoul and Gosan (서울과 고산의 미세입자 수분함량에 영향을 미치는 주요 인자)

  • Choi E. K;Kim Y.P
    • Journal of Korean Society for Atmospheric Environment
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    • v.20 no.6
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    • pp.803-810
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    • 2004
  • Water contents in fine particles at Seoul and Gosan are estimated by using a gas/particle equilibrium model, SCAPE (Simulating Composition of Atmospheric Particles at Equilibrium). Also, sensitivity of particulate inorganic ionic concentrations on the total ionic species is estimated. Water content at Gosan is more sensitive to ambient relative humidity (RH) than Seoul. At both sites water content is most sensitive to sulfate concentration among sulfate, nitrate, and ammonium. Solid salts levels and compositions are also studied.